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Pre-chamber combustion (PCC) has re-emerged in recent last years as a potential solution to help to decarbonize the transport sector with its improved engine efficiency as well as providing lower emissions. Research into the combustion process inside the pre-chamber is still a challenge due to the high pressure and temperatures, the geometrical restrictions, and the short combustion durations. Some fundamental studies in constant volume combustion chambers (CVCC) at low and medium working pressures have shown the complexity of the process and the influence of high pressures on the turbulence levels. In this study, the pre-chamber combustion process was investigated by combustion visualization in an optically-accessible pre-chamber under engine relevant conditions and linked with the jet emergence inside the main chamber. The pre-chamber geometry has a narrow-throat. The total nozzle area is distributed in two six-hole rows of nozzle holes.

Soot Volume Fraction (SVF) measurements were performed in an IFP Energies nouvelles optical single cylinder Diesel engine operated in Low Temperature Combustion (LTC) conditions. The engine was equipped with a sapphire liner, a dedicated flat bowl piston and a six-hole common-rail high pressure injector. The piston design included four quartz windows allowing optical access into the bowl. The aim of this work was to study soot formation and oxidation during the LTC Diesel combustion process and to build a database providing soot formation and oxidation data under a set of engine conditions to help developing and testing Computational Fluid Dynamics (CFD) models. Two complementary optical diagnostic techniques were combined: Planar Laser Induced Incandescence (PLII) and Laser Extinction Method (LEM).

The NO reduction in an ammonia SCR converter has been simulated by a 1D+1D model for a single representative channel to parametrically study the characteristics of the system under typical operating conditions. An appropriate model has been selected interpreting the chemical behavior of the system and the parameters are calibrated based on a comprehensive set of experiments with an Fe-Zeolite washcoated monolith for different feed concentrations, temperatures and flow rates. Physical and chemical properties are determined as well as kinetics and rate parameters and the model has been verified by experimental data at different operating conditions. Three different mechanisms for the surface kinetics to model NO reduction have been assessed and the results have been compared in the cases of steady DeNO performance and transient response of the system. Ammonia inhibition is considered in the model since it has a major effect specifically under transient operating conditions.

The fuel film thickness resulting from fuel spray impingement on a flat transparent window was characterized in a high pressure high temperature cell for various thermodynamic conditions, injection pressures, injection durations, fuel types and injector technologies by Refractive Index Matching technique. The ambient conditions at injection timing were similar to that of a direct injection spark ignition engine at Top Dead Center, with the distance between the injector tip and the impinging surface set to 10 mm. The spray axis was set normal to the rough transparent window surface at ambient temperatures of 453 K, 573 K and 673 K, and ambient densities of 5.0 kg/m₃, 6.0 kg/m₃ and 6.5 kg/m₃. Injection pressures of 100 and 200 bar were investigated. Three injector technologies were studied: piezo-electric, multi-holes and swirl types. Two fuels, iso-octane and model gasoline, were tested.

The current work utilizes computational fluid dynamics (CFD) simulations to assess the effects of different piston geometries in an active-type pre-chamber combustion engine fueled with methane. Previous works identified that the interaction of the jets with the main chamber flow and piston wall are key aspects for the local turbulent flame speed and overall burning duration. The combustion process is simulated with the G-equation model for flame propagation combined with the MZ-WSR model to determine the post-flame composition and to predict possible auto-ignition of the reactant mixture. Four setups were considered: two bowl-shaped and one flat piston, and one additional case of the flat piston with jets at wider jet angles to the cylinder axis. The results show that premature jet-wall interaction impacts the main chamber pressure build-up, turbulence, and burn rate.

Particle image velocimetry measurements of the in-cylinder flow in an optically accessible single-cylinder research engine were taken to better understand the effects of intake pressure variations on the flow field. At a speed of 1500 rpm, the engine was run at six different intake pressure loads from 0.4 to 0.95 bar under motored operation. The average velocity fields show that the tumble center position is located closer to the piston and velocity magnitudes decrease with increasing pressure load. A closer investigation of the intake flow near the valves reveals sharp temporal gradients and differences in maximum and minimum velocity with varying intake pressure load which are attributed to intake pressure oscillations. Despite measures to eliminate acoustic oscillations in the intake system, high-frequency pressure oscillations are shown to be caused by the backflow of air from the exhaust to the intake pipe when the valves open, exciting acoustic modes in the fluid volume.

This work investigates the impact of injector temperature on the characteristics of high-pressure n-dodecane sprays under conditions relevant to heavy-duty diesel engines. Sprays are injected from a pair of single-hole diesel injectors belonging to the family of “Spray C” and “Spray D” Engine Combustion Network (ECN) injectors. Low and high injector temperature conditions are achieved by activating or deactivating a cooling jacket. We quantify spray spreading angle and penetration using high-speed shadowgraphy and long-distance microscopy imaging. We evaluate differences in fuel/air mixture formation at key timings through one-dimensional modeling. Injections from a cooled injector penetrate faster than those from a higher temperature injector, especially for an injector already prone to cavitation (Spray C).

Cycle-to-cycle variations in internal combustion engines are known to lead to limitations in engine load and efficiency, as well as increases in emissions. Recent research has led to the identification of the source of cyclic variations of pressure, soot and NO emissions in direct injection common rail diesel engines, when employing a single block injection and operating under long ignition delay conditions. The variations in peak pressure arise from changes in the diffusion combustion rate, caused by randomly occurring in-cylinder pressure fluctuations. These fluctuations result from the excitation of the first radial mode of vibration of the cylinder gases which arises from the rapid premixed combustion after the long ignition delay period. Cycles with high-intensity fluctuations present faster diffusion combustion, resulting in higher cycle peak pressure, as well as higher measured exhaust NO concentrations.

Past research has shown that post injections have the potential to reduce Diesel engine exhaust PM concentration without any significant influence in NOx emissions. However, an accurate, widely applicable rule of how to parameterize a post injection such that it provides a maximum reduction of PM emissions does not exist. Moreover, the underlying mechanisms are not thoroughly understood. In past research, the underlying mechanisms have been investigated in engine experiments, in constant volume chambers and also using detailed 3D CFD-CMC simulations. It has been observed that soot reduction due to a post injection is mainly due to two reasons: increased turbulence from the post injection during soot oxidation and lower soot formation due to lower amount of fuel in the main combustion at similar load conditions. Those studies do not show a significant temperature rise caused by the post injection.

Pre-chamber combustion (PCC) enables leaner air-fuel ratio operation by improving its ignitability and extending flammability limit, and consequently, offers better thermal efficiency than conventional spark ignition operation. The geometry and fuel concentration of the pre-chamber (PC) is one of the major parameters that affect overall performance. To understand the dynamics of the PCC in practical engine conditions, this study focused on (i) correlation of the events in the main chamber (MC) with the measured in-cylinder pressure traces and, (ii) the effect of fuel concentration on the MC combustion characteristics using laser diagnostics. We performed simultaneous acetone planar laser-induced fluorescence (PLIF) from the side, and OH* chemiluminescence imaging from the bottom in a heavy-duty optical engine. Two different PC Fueling Ratios (PCFR, the ratio of PC fuel to the total fuel), 7%, and 13%, were investigated.

The mixing and combustion processes of short double Diesel injections are investigated by optical diagnostics. A single hole Common Rail Diesel injector allowing high injection pressure up to 120MPa is used. The spray is observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a Diesel engine during injection. Three configurations are studied: a single short injection serving as a reference case and two double short injections with short and long dwell time (time between the injections). Several optical diagnostics were performed successively. The mixing process is studied by normalized Laser Induced Exciplex Fluorescence giving access to the vapor fuel concentration fields. In addition, the flow fields both inside and outside the jets are characterized by Particle Imaging Velocimetry.

A tracer laser-induced fluorescence (LIF) technique for the visualisation of fuel distribution in the presence of oxygen was developed and then used sequentially with high speed chemiluminescence imaging to study the correlation between the mixing and auto-ignition processes of high pressure Diesel jets. A single hole common rail Diesel injector allowing high injection pressures up to 150MPa was used. The reacting fuel spray was observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a Diesel engine during injection. Both free jet and flat wall impinging jet configurations were studied. Several tracers were first considered with the objective of developing a tracer-LIF technique in the presence of oxygen. 5-nonanone was selected for its higher fluorescence efficiency.

Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.

The Engine Combustion Network (ECN) has become a leading group concerning the experimental and computational analysis of engine combustion phenomena. In order to establish a coherent database for model validation, all the institutions participating in the experimental effort carry out tests at well-defined boundary conditions and using wellcharacterized hardware. In this framework, the reference Spray A injectors have produced different results even when tested in the same facility, highlighting that the nozzle employed and its fouling are important parameters to be accounted for. On the other hand, the number of the available Spray A injectors became an issue, due to the increasing number of research centers and simultaneous experiments taking place in the ECN community. The present work has a double aim: on the one hand, to seek for an appropriate methodology to “validate” new injectors for ECN experiments and to provide new hardware for the ECN community.

The air entrainment of multi-hole diesel injection is investigated by high speed Particle Image Velocimetry (PIV) using a multi-hole common rail injector with an injection pressure of 100 MPa. The sprays are observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a diesel engine during injection. Typical ambient temperature of 800K and ambient density of 25 kg/m3 are chosen. The air entrainment is studied with the PIV technique, giving access to the velocity fields in the surrounding air and/or in the interior of two neighboring jets. High acquisition rate of 5000 Hz, corresponding to 200 μs between two consecutive image pairs is obtained by a high-speed camera coupled with a high-speed Nd:YLF laser. The effect of neighboring jets interaction is studied by comparing four injectors with different numbers of holes (4, 6, 8 and 12) with similar static mass flow rate per hole.

In this study we classify established and possible future engine combustion systems according to two main criteria, i.e. charge preparation (homogeneous or stratified) and type of combustion initiation (external, typically spark ignition and internal, typically due to compression). We discuss the relevant pros and cons of the four resulting energy conversion processes with emphasis on combustion stability, thermal efficiency and pollutant emissions. We show thereby that these output parameters are dominated by specific thermochemical and fluiddynamic processes as well as their complex interaction within the time scales of a thermodynamically optimal energy conversion at a given engine speed and load. For unsteady operation in mobile applications, the complexity of new combustion concepts may, nevertheless, prevent a breakthrough, despite their in-principle attractivity.

Soot formation in high-pressure n-dodecane sprays is investigated under conditions relevant to heavy-duty diesel engines. Sprays are injected from a single-hole diesel injector belonging to the family of engine combustion network (ECN) Spray D injectors. Soot is quantified using a high-speed extinction imaging diagnostic with incident light wavelengths of 623 nm and 850 nm. Previously, soot measurements in a high-pressure spray using 406-nm and 520-nm incident light demonstrated a minimal wavelength dependence in the complex refractive index of soot (m), as demonstrated by a near unity ratio of the non-dimensional extinction coefficients (ke,406 nm/ke,520 nm). The present work, however, demonstrates a significant difference in m for measurements with infrared incident light. During the quasi-steady period of the spray combustion event, the experimentally determined ke ratio (ke,623 nm/ke,850 nm) is 1.42 ± 0.27.

The operation of dual fuel engines, operated with natural gas as main fuel, offers the potential of substantial savings in CO2. Nevertheless, the operating map area where low pollutant emissions are produced is very narrow. Especially at low load, the raw exhaust gas contains high concentrations of unburned methane and, with high pilot fuel portions due to ignition limitations, also soot. The analysis of the combustion in those conditions in particular is not trivial, since multiple combustion modes are present concurrently. The present work focuses on the evaluation of the individual combustion modes of a dual fuel engine, operated with natural gas as main and diesel as pilot fuel, using a combustion model. The combustion has been split in two partwise concurrent combustion phases: the auto-ignition phase and the premixed flame propagation phase.

In order to study the soot formation and oxidation phenomena during the combustion process of Gasoline Direct Injection (GDI) engines, soot volume fraction measurements were performed in an optical GDI engine by combined Laser-Induced Incandescence (LII) and Laser Extinction Method (LEM). The coupling of these two diagnostics takes advantages of their complementary characteristics. LII provides a two-dimensional image of the soot distribution while LEM is used to calibrate the LII image in order to obtain soot volume fraction fields. The LII diagnostic was performed through a quartz cylinder liner in order to obtain a vertical plane of soot concentration distribution. LEM was simultaneously performed along a line of sight that was coplanar with the LII plane, in order to carry out quantitative measurements of path-length-averaged soot volume fraction. The LII images were calibrated along the same path as that of the LEM measurement.

Measurements of the soot emissions and engine operating parameters from a diesel engine during transient operation were used to investigate the influence of transient operation on the soot emissions, as well as to validate a realtime mean value soot model (MVSM, [1]) for transient operation. To maximize the temporal resolution of the soot emission and engine parameter measurements (in particular EGR), fast instruments were used and their dynamic responses characterized and corrected. During tip-in transients, an increase in the soot emissions was observed due to a short term oxygen deficit compared to steady-state operation. No significant difference was seen between steady-state and transient operation for acceleration transients. When the MVSM was provided with inputs of sufficient temporal resolution, it was capable of reproducing the qualitative and, in part, quantitative soot emission trends.