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Technical Paper

“Trapless” Trap – A Catalytic Combustion System of Diesel Particulates Using Ceramic Foam

1983-02-01
830082
“Trapless” Trap, which makes possible the effective collecting of particulates in diesel exhaust gas and their simultaneous combustion has been developed by use of a ceramic foam in combination with catalysts containing copper salt. From a TEM photograph, it was observed that the particulate was rapidly oxidized by mobile copper ion, showing worm-eaten like spots. Screening of various base metal salts by TGA presented CUCl2-KCl-NH4VO3 and CuCl2-KCl-(NH4)6Mo7O24 as very active catalysts for diesel particulate oxidation. They had thermal stability up to 900°C when they were supported on titania. The results obtained by measuring the back pressure using 1.8L diesel engine suggest the above trap to be a self-cleaning trapless trap.
Technical Paper

“Real-Time Estimation of Soot for a Wall Flow DPF Regeneration Management and an Efficient DOE for Model Calibration.”

2021-09-22
2021-26-0333
Estimation of soot deposited on a wall flow type DPF, is a vital information to ensure safe and efficient DPF management. Accuracy in determining mass of soot present inside the DPF ensures a correct regeneration management strategy in-terms of fuel efficiency and DPF safety considering soot overloading and too frequent regenerations. It also ensures an efficient detection of anomalies in the PM filtration mandated by the BSVI/EURO VI legislation as a part of On-board diagnostics. Classical approach of determining soot present inside DPF involves monitoring increase in pressure drop. Real time usage of such a model is limited by the inaccuracy of measuring pressure drop at low exhaust flows. Hence, contemporary engine controllers use pressure drop based models as a failsafe and estimate DPF soot loading by modelling soot release rate due to engine combustion and the rate at which it is oxidized.
Technical Paper

“OptiVent” - A New Approach for Controlling Mass Air Flow and Combustion in Direct Injection SI-Engines

2013-04-08
2013-01-0592
Combustion concepts for future SI engines try to meet CO2-emission commitments and legislation all over the world. Where the Diesel engine has an advantage by principle, the efficiency of the SI engine has to be improved significantly, while of course the exhaust emissions must not become worse. An approach is to reduce the gas exchange losses using fully variable valve trains on the intake side of the combustion engine. OptiVent is a patented new way of controlling the mass air flow in the cylinder of a combustion engine using opening valves during the compression phase of a four stroke engine. This technology regards a wider range of variability on the valvetrain components of the engine especially for opening the valves more than one time during a cycle. On the other hand it is necessary to combine this technology with direct injection to avoid fuel losses in the exhaust system and raising the exhaust hydrocarbon emission of the engine.
Technical Paper

“KATPROG” for the Determination of an Optimal Cost Effective Catalyst System

2001-01-10
2001-26-0016
An two-dimensional axial symmetrical finite volume model will be introduced for the calculation of catalytic converters. It is able to predict transient temperatures and conversion rates in different converter systems according to the driving conditions. Input data are the mass-flow rate, the converter inlet temperature and the raw emissions. The performance of this model is demonstrated on an Indian motorcycle application. Cold start behavior and peak temperatures are investigated. This model has proven to be an effective tool for the preselection of an optimal cost effective catalyst system.
Technical Paper

“Investigation of High Achievable Pollutant Reduction on a “State of the Art” Indian 2 Wheelers - Technology Road Map to a Cleaner Air”

2015-11-17
2015-32-0802
Affordable, efficient and durable catalytic converters for the two and three wheeler industry in developing countries are required to reduce vehicle emissions and to participate in a cleaner and healthier environment. As a contribution Continental Emitec started a comprehensive testing program with a state of the art 180 cc Bharat Stage (BS) III Indian motorcycle. The program consists of testing the state of the art of Metallic substrates with structured foils with various catalyst sizes and positions (original or close coupled). The publication presents a short literature survey and the results of the investigation with a big catalyst volume mounted in underfloor position as well as in close coupled position, gained over the World-wide harmonized Motorcycle Test Cycle, considering the two possible vehicle classifications of this motorcycle, Sub-Class 2.1 and Sub-Class 2.2.
Technical Paper

“Future” Diesel Fuel Compositions - Their Influence on Particulates

1988-08-01
881173
Five different diesel fuels, having been made available by the mineral oil industry within the framework of a research program of the Coordinating European Council (CEC/PF-26), were examined in addition to this program by the Klöckner-Humboldt-Deutz AG by means of the 13-mode test in accordance with the former US legislation and the ECE regulation No. 49 and by US Transient Tests. The results have been compared with results based on commercial European diesel fuel. There has been observed the emission behaviour of an 8-cylinder NA engine with a “state of the art” direct fuel injection system by particularly taking into consideration the particulate emission and the particulate components. The gaseous emissions, particularly CO and HC, are unfavourably influenced by low cetane numbers being associated with increased aromaticity in the diesel fuel.
Technical Paper

“EVO: New Metallic Substrate Development for Commercial Vehicle and Non-Road Applications”

2021-09-22
2021-26-0211
Affordable, efficient and durable catalytic converters for the Commercial Vehicle and Non-Road industry in all countries are required to reduce vehicle emissions under real world driving conditions and fulfill future legal requirements. Specially for India traffic conditions and payload to engine size conditions new cost-effective solutions are needed to participate in a cleaner and healthier environment. Metallic substrates with structured foils like the Transversal StructureTM (TS) or the Longitudinal StructureTM (LS) have been proved to be capable of improving conversion behavior, even with smaller catalyst size. Now Vitesco Technologies is developed a new Substrate for Heavy duty applications that specifically maintains the geometric surface area at a very high level and improves further the mass transport of the pollutants, which potentially leads together to very high pollutant conversion rates.
Technical Paper

“Catalytic Engine” NOx Reduction of Diesel Engines with New Concept Onboard Ammonia Synthesis System

1992-02-01
920469
Ammonia is one of the most useful compounds that react with NOx selectively on a catalyst, such as V2O5-TiO2, under oxygen containing exhaust gas. However ammonia cannot be stored because of its toxicity for the small power generator in populated areas or for the diesel vehicles. A new concept for NOx reduction in diesel engine using ammonia is introduced. This system is constructed from the hydrogen generator by fuel reformer, the ammonia synthesizer, SCR catalyst for NOx reduction and the gas injection system of reformed gas into the cylinder. Experimental results show that, the SCR catalyst provides a very high rate of NOx reduction, reformed gas injection into cylinder is very effective for particulate reduction. WHEN CONSIDERING INTERNAL COMBUSTION ENGINES of the 1990's the question of how to harmonize the engine with the natural environments is one of the greatest problems. The internal combustion engine changes a substance into energy via its explosive combustion.
Technical Paper

“Active Mass Absorber” at a 4×4 Transmition System

2003-11-18
2003-01-3682
The extensive use of rotative machines in the diverse branches of the modern world has made the rising undesirable mechanical and acoustic vibration levels to be a problem of special importance for the machines normal operation as for the communities that are each time more affected by the problem. It makes the study of vibration and acoustic phenomena also to be even more important and the applications of its concepts more sophisticated. Several are the concepts used for decreasing vibration levels, like common dampers, hydraulic dampers, active dampers, natural frequencies changes and others. The choice of use of one or another depends greatly on the engineering possibilities (weight, energy, physical space, other components functional interference, vibration levels, etc.) as well as the cost of implementation of each one.
Technical Paper

“A Flame Ionization Technique for Measuring Total Hydrocarbons in Diesel Exhaust”

1968-02-01
680419
The method of flame ionization was used for measuring total hydrocarbons in both single-cylinder and multicylinder 4-cycle, direct injection diesel engine exhaust. Use of the emission parameters of hydrocarbon concentration, per cent unburned fuel, specific hydrocarbon rate, mass of hydrocarbons per million cycles, mass of hydrocarbons per mile, and mass of hydrocarbons per ton-mile are discussed. The basic approach used in the flame ionization detector is shown. The hydrocarbon sample was transferred from the exhaust system through a heated sample line and oven operating at 375 F. The sample line was aspirated to reduce the sample residence time to 2 sec. The effect various sampling locations have on hydrocarbon measurements from a single-cylinder engine is shown and discussed. The effects of load, speed, and injection timing on hydrocarbon emission data are shown for a single-cylinder engine.
Technical Paper

‘Regulated’ and ‘Non-regulated’ Emissions from Modern European Passenger Cars

2006-04-03
2006-01-1516
Regulated emissions from four current production European vehicles were measured over the Common Artemis Driving Cycles (CADC). Particulate Mass and Particle Number measurements were made in accordance with the newly-developed draft Particulate Measurement Programme (PMP) developed for the UN-ECE's expert group on pollution and energy (GRPE). During the test programme measurements were also made of currently non-regulated emissions including PAHs and speciation of the particulate material and key hydrocarbons. CADC results are presented for each of the four vehicles tested (one conventional gasoline vehicle, two different types of diesel without Diesel Particulate Filter (DPF) and one diesel with DPF) with results measured on the regulated New European Driving Cycle (NEDC) test for comparison. The emissions results on the Artemis cycles showed some significant differences from those on the regulated (NEDC) test cycle.
Technical Paper

‘Issues and Behaviors of Airborne Particulate Matters under Microgravity Environment’

2004-07-19
2004-01-2328
During several ISS missions, there were false alarms at both US and Russian smoke detectors. High local airborne particulate concentrations and interior deposits are considered the causes for such anomalies. Alternatives are proposed to replace or complement these faulty smoke detectors. The entrained zeolite particles may play a role in causing problems with check valves and air save pumps in CDRA and Vozdukh. Another incidence has been the dispersion of particulates out of Metox regeneration oven. Particulate matters with aerodynamic diameter of 15 microns and above, which normally settle down on earth, stay airborne under micro-gravity and thereby cause the above-mentioned nuisances. The motion of such a particle along a gas stream with an initial velocity can be expressed by theoretical equations. Stokes' Law leads to the descriptions of inertial precipitation of aerosols that are important in solving the issues.
Journal Article

μ-CT Investigation into the Impact of a Fuel-Borne Catalyst Additive on the Filtration Efficiency and Backpressure of Gasoline Particulate Filters

2022-01-18
Abstract An investigation into the pre-ashing of new gasoline particulate filters (GPFs) has demonstrated that the filtration efficiency of such filters can be improved by up to 30% (absolute efficiency improvement) when preconditioned using ash derived from a fuel-borne catalyst (FBC) additive. The additive is typically used in diesel applications to enable diesel particulate filter (DPF) regeneration and can be added directly into the fuel tank of the vehicle. This novel result was compared with ash derived from lube oil componentry, which has previously been shown to improve filtration efficiency in GPFs. The lube oil-derived ash utilized in this work improved the filtration efficiency of the GPF by −30%, comparable to the ash derived from the FBC additive.
Technical Paper

λDSF: Dynamic Skip Fire with Homogeneous Lean Burn for Improved Fuel Consumption, Emissions and Drivability

2018-04-03
2018-01-0891
Dynamic skip fire (DSF) has shown significant fuel economy improvement potential via reduction of pumping losses that generally affect throttled spark-ignition (SI) engines. In DSF operation, individual cylinders are fired on-demand near peak efficiency to satisfy driver torque demand. For vehicles with a downsized-boosted 4-cylinder engine, DSF can reduce fuel consumption by 8% in the WLTC (Class 3) drive cycle. The relatively low cost of cylinder deactivation hardware further improves the production value of DSF. Lean burn strategies in gasoline engines have also demonstrated significant fuel efficiency gains resulting from reduced pumping losses and improved thermodynamic characteristics, such as higher specific heat ratio and lower heat losses. Fuel-air mixture stratification is generally required to achieve stable combustion at low loads.
Technical Paper

µMist® - The next generation fuel injection system: Improved atomisation and combustion for port-fuel-injected engines

2011-08-30
2011-01-1890
The Swedish Biomimetics 3000's μMist® platform technology has been used to develop a radically new injection system. This prototype system, developed and characterized with support from Lotus, as part of Swedish Biomimetics 3000®'s V₂IO innovation accelerating model, delivers improved combustion efficiency through achieving exceptionally small droplets, at fuel rail pressures far less than conventional GDI systems and as low as PFI systems. The system gives the opportunity to prepare and deliver all of the fuel load for the engine while the intake valves are open and after the exhaust valves have closed, thereby offering the potential to use advanced charge scavenging techniques in PFI engines which have hitherto been restricted to direct-injection engines, and at a lower system cost than a GDI injection system.
Journal Article

xD+1D Catalyst Simulation-A Numerical Study on the Impact of Pore Diffusion

2012-04-16
2012-01-1296
This paper presents a numerical study on the impact of washcoat diffusion on the overall conversion performance of catalytic converters. A comprehensive transient 1D pore diffusion reaction model is embedded in state-of-the-art 1D and 3D catalytic converter models. The pore diffusion model is discussed with its model equations and the applied diffusive transport approaches are summarized. The diffusion reaction model is validated with the help of two available analytical solutions. The impact of basic washcoat characteristics such as pore diameters or thickness on overall conversion performance is investigated by selected 1D+1D calculations. This model is also used to highlight the impact of boundary layer transfer, pore diffusion and reaction on the overall converter conversion performance. The interaction of pore diffusion and flow non-uniformities is demonstrated by 3D+1D CFD simulations.
Technical Paper

mDSF: Improved Fuel Efficiency, Drivability and Vibrations via Dynamic Skip Fire and Miller Cycle Synergies

2019-04-02
2019-01-0227
mDSF is a novel cylinder deactivation technology developed at Tula Technology, which combines the torque control of Dynamic Skip Fire (DSF) with Miller cycle engines to optimize fuel efficiency at minimal cost. mDSF employs a valvetrain with variable valve lift plus deactivation and novel control algorithms founded on Tula’s proven DSF technology. This allows cylinders to dynamically alternate among 3 potential states: high-charge fire, low-charge fire, and skip (deactivation). The low-charge fire state is achieved through an aggressive Miller cycle with Early Intake Valve Closing (EIVC). The three operating states in mDSF can be used to simultaneously optimize engine efficiency and driveline vibrations. Acceleration performance is retained using the all-cylinder, high-charge firing mode.
Technical Paper

Zone Length Optimization to Improve PGM Utility

2014-04-01
2014-01-1508
“Zoning” a catalytic converter involves placing higher concentrations of platinum group metals (PGM) in the inlet portion of the substrate. This is done to optimize the cost-to-performance tradeoff by increasing the reaction rate at lower temperatures while minimizing PGM usage. A potentially useful application of catalyst zoning is to improve performance using a constant PGM mass. A study was performed to assess what the optimum ratio of front to rear palladium zone length is to achieve the highest performance in vehicle emission testing. Varying the zone ratio from 1:1 to 1:9 shows a clear hydrocarbon performance optimum at a 1:5.66 (15%/85%) split. This performance optimum shows as both a minimum in FTP75 non-methane organic gas (NMOG) emissions as well as a minimum in hydrocarbon, carbon monoxide, and nitrogen oxide light-off temperature. Overall, an improvement of 18%, or 11 mg/mi of combined NMOG+NOx emissions was obtained without using additional PGM.
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