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Condensed soot coming out of vehicular exhaust is commonly classified as organic carbon (OC) and elemental carbon (EC). OC can be directly emitted to the atmosphere in the particulate form (primary carbon) from the tailpipe or can be produced by gas-to-particle conversion process (secondary organic carbon, SOC). Under typical atmospheric dilution conditions, most of the semi-volatile material is present in the form of soot. SOC holds wider implications in terms of their adverse health and climate impact. Diesel exhaust is environmentally reactive and it has long been understood that the ambient interaction of exhaust hydrocarbons and NOx results in the formation of ozone and other potentially toxic secondary organic carbon species. The current emission norms look at the primary emissions from the engine exhaust. Also, research efforts are geared towards controlling the emissions of primary carbon.

Considering the demand for sustainable transport, alternative fuels are a keen research topic for IC engine researchers. Among various alternative fuels being explored, Di-ethyl ether (DEE) is gaining popularity off-late for compression-ignition (CI) engines owing to its high cetane rating, oxygen presence in its molecular structure, and lower carbon content. This study explores the suitability of DEE blends in tractor engines. DEE blends [15% and 30% (v/v)] with diesel were compared with baseline diesel for combustion, and emission characterisation, keeping all parameters identical, including the fuel injection timings. Results were analysed for different engine loads at 1500 rpm. Delayed combustion was observed with DEE blends with diesel, possibly due to a higher cooling effect from DEE vaporisation and retarded dynamic fuel injection due to its higher compressibility. However, the DEE blend fuelled engine performance was comparable to baseline diesel.

This experimental study was undertaken to investigate the use of vegetable oil derivatives to substitute mineral diesel fuel. Straight vegetable oils pose some problems like injector coking, carbon deposits etc., when used as a fuel in an engine. These problems are due to high viscosity, low volatility and polyunsaturated character of vegetable oils. Transesterified vegetable oil derivative called “biodiesel” appear to be most convenient way of utilizing vegetable oil as a substitute fuel in diesel engines. In present investigation, rice bran oil (non-edible) was transesterified to methyl ester and reaction conditions for transeterifcation process for rice bran oil were optimized. Various properties like viscosity, density, flash point of the biodiesel thus prepared are comparable to diesel and found to be in acceptable range as per ASTM norms (ASTM D6751). Experimental investigations were carried out on a four stroke, four cylinders, transportation DI diesel engine.

Environmental concerns have increased significantly world over in the past decade. Regulatory agencies are becoming increasingly concerned with particulate emissions as the health and environmental effects are getting understood better due to rapid development in instrumentation. Biodiesel is one of the most promising alternative diesel fuels, which is getting global acceptability among the automotive/ engine manufactures as well as users due to numerous benefits it offers over the conventional diesel. While much of literature is available on particulate emitted by diesel fuelled engine, little is known by particulate emissions from biodiesel fuelled compression ignition (CI) engine. This study concentrates on the characterization of particulate emissions from mineral diesel vis-à-vis biodiesel (B100) and its optimum blend (20%, B20) with mineral diesel.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

Petroleum products are used to power internal combustion engines (ICEs). Emissions and depletion of petroleum reserves are important questions that need to be answered to ensure existence of ICEs. Indian Railways (IR) operates diesel locomotives, which emit large volume of pollutants into the environment. IR is looking for an alternative to diesel for powering the Locomotives. Methanol has emerged as a replacement for petroleum fuels because it can be produced from renewable resources as well as from non-renewable resources in large quantities on a commercially viable scale. It has similar/superior physico-chemical properties, which reduce tailpipe emissions significantly. It is therefore necessary to understand the in-cylinder phenomenon in methanol fueled engines before its implementation on a large-scale.

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

The interface between the piston rings and cylinder liner play an important role in total frictional losses and mechanical wear of internal combustion engine and is increasingly coming under scrutiny as legislated particulate emission standards are getting more and more stringent. The capacitance method is used for measurement of minimum oil film thickness between piston ring and liner interface. Measurement of capacitance formed between the piston ring and a probe mounted flush in the liner provides an accurate means of determining the oil film thickness provided that the region between the probe and liner is flooded with oil and dielectric constant of the oil is known. This paper presents detailed design and measurement of lubricating oil film thickness using capacitive micro sensor in a non-firing engine simulator. Lubricating oil film thickness was found to vary between 0.2μm to 8μm in the non firing engine simulator.

Biodiesel is being explored as a sustainable renewable fuel for vehicles in India due to mounting foreign exchange expenditure to import crude petroleum. Significant amount of research and development work is being undertaken in India to investigate various aspects of biodiesel utilisation in different types of engines. This study is an effort to jointly investigate the use of biodiesel (B100) in an unmodified BS-III compliant sports utility vehicle (SUV) by a consortium of academia (IIT Kanpur) and Industry (M&M) to realistically assess whether biodiesel is compatible with modern engine technology vehicles. Two identical vehicles were operated in tandem using biodiesel (B100) and mineral diesel (B00) respectively for 30,000 kilometers in field conditions. The lubricating oil samples were collected and detailed analysis for assessing the comparative effect of new fuel (B100) vis-à-vis mineral diesel was carried out.

Biodiesel is mono alkyl ester derived from vegetable oils through transesterification reaction and can be used as an alternative to mineral diesel. In the present research, methyl ester of rice-bran oil (ROME) is produced through transesterification of rice-bran oil using methanol in presence of sodium hydroxide (NaOH) catalyst. Various properties like viscosity, density, flash point, calorific value of the biodiesel thus prepared are characterized and found comparable to diesel. On the basis of previous research for performance, emission and combustion characteristics, a 20% blend of ROME (B20) was selected as optimum biodiesel blend for endurance test. Endurance test of 100 hours was conducted on a medium duty direct injection transportation diesel engine. Tests were conducted under predetermined loading cycles in two phases: engine operating on mineral diesel and engine fuelled with 20% biodiesel blend.

IC engines are facing two major challenges in the 21st century namely threat of fossil fuel depletion and environmental concerns. HCCI engine is an attractive solution to meet stringent emission challenges due to its capability to simultaneously reduce NOx and PM. HCCI technology can be employed with different alternative fuels without significant modifications in the existing engines. In this study, HCCI combustion was investigated using B20 (20% v/v biodiesel with diesel). Investigations were carried out on a two cylinder engine, in which one cylinder was modified to operate in HCCI mode however the other cylinder operated in conventional CI combustion mode. A dedicated fuel vaporizer was used for homogeneous fuel-air mixture preparation. The experiments were performed at three different intake charge temperatures (160°C, 180°C and 200°C) and three different EGR ratios (0%, 10% and 20% EGR) at different engine loads.

This study was set out to characterize particulate emissions from diesel engines in terms of poly aromatic hydrocarbon emissions and Benzene Soluble Organic Fraction. The characteristics of DPM vary with engine operating conditions, quality of fuel and lubricants being used. Hence the diesel exhaust for the purpose of toxicity characterization needs to be studied for Organic Matter in terms of Poly Aromatic Hydrocarbon (PAH) and Benzene Soluble Fraction (BSF). Therefore, the objectives of the present research are to characterize the diesel exhaust particulate matter for the above parameters under varying engine operating conditions/loads. Six PAHs, namely Chrysene, Benzo (k) Flouranthene, Benzo (a) Pyrene, Dibenzo (a, h) Anthracene, Benzo (g,h,i) Perylene and Indenopyrene were analyzed on High Pressure Liquid Chromatography (HPLC). PAH concentrations in the particulates of Mahindra DI engine were affected by engine loads.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

Vegetable oils are produced from numerous oil seed crops. While all vegetable oils have high energy content, most require some processing to assure safe use in internal combustion engines. Some of these oils already have been evaluated as substitutes for diesel fuels. However, several operational and durability problems of using straight vegetable oils in diesel engines are reported in the literature, caused by of their higher viscosity and low volatility compared to mineral diesel. In the present research, experiments were designed to study the effect of reducing Jatropha oil's viscosity by blending it with mineral diesel and thereby eliminating the effect of high viscosity and poor volatility on combustion characteristics of the engine. Experimental investigations have been carried out to examine the combustion characteristics of an indirect injection transportation diesel engine running with diesel, and jatropha oil blends with diesel.

Homogeneous charge compression ignition (HCCI) is an advanced combustion concept that is developed as an alternative to diesel engines with higher thermal efficiency along with ultralow NOx and PM emissions. To study the performance of this novel technique, experiments were performed in a two cylinder engine, in which one cylinder is modified to operate in HCCI mode while other cylinder operates in conventional CI mode. The quality of homogeneous mixture of air and fuel is the key feature of HCCI combustion. Low volatility of diesel is a major hurdle in achieving HCCI combustion because it is difficult to make a homogeneous mixture of air and fuel. This problem is resolved by external mixture preparation technique in uses a dedicated diesel vaporizer with an electronic control system. All the injection parameters such as fuel quantity, fuel injection timing, injection delay etc., are controlled by the injection driver circuit.