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“Trapless” Trap, which makes possible the effective collecting of particulates in diesel exhaust gas and their simultaneous combustion has been developed by use of a ceramic foam in combination with catalysts containing copper salt. From a TEM photograph, it was observed that the particulate was rapidly oxidized by mobile copper ion, showing worm-eaten like spots. Screening of various base metal salts by TGA presented CUCl2-KCl-NH4VO3 and CuCl2-KCl-(NH4)6Mo7O24 as very active catalysts for diesel particulate oxidation. They had thermal stability up to 900°C when they were supported on titania. The results obtained by measuring the back pressure using 1.8L diesel engine suggest the above trap to be a self-cleaning trapless trap.

An two-dimensional axial symmetrical finite volume model will be introduced for the calculation of catalytic converters. It is able to predict transient temperatures and conversion rates in different converter systems according to the driving conditions. Input data are the mass-flow rate, the converter inlet temperature and the raw emissions. The performance of this model is demonstrated on an Indian motorcycle application. Cold start behavior and peak temperatures are investigated. This model has proven to be an effective tool for the preselection of an optimal cost effective catalyst system.

Affordable, efficient and durable catalytic converters for the two and three wheeler industry in developing countries are required to reduce vehicle emissions and to participate in a cleaner and healthier environment. As a contribution Continental Emitec started a comprehensive testing program with a state of the art 180 cc Bharat Stage (BS) III Indian motorcycle. The program consists of testing the state of the art of Metallic substrates with structured foils with various catalyst sizes and positions (original or close coupled). The publication presents a short literature survey and the results of the investigation with a big catalyst volume mounted in underfloor position as well as in close coupled position, gained over the World-wide harmonized Motorcycle Test Cycle, considering the two possible vehicle classifications of this motorcycle, Sub-Class 2.1 and Sub-Class 2.2.

Automotive industry is a major contributor to global carbon dioxide (CO2) emissions and waste generation. Not only do vehicles produce emissions during usage, but they also generate emissions during production phase and end of life disposal. There is an urgent need to address sustainability and circularity issues in this sector. This paper explores how circularity and CO2 reduction principles can be applied to design and production of automotive parts, with the aim of reducing the environmental impact of these components throughout their life cycle. Also, this paper highlights the impact of design principles on End-of-Life Management of vehicles. As Design decisions of Component impacts up to 80% of emissions [1], it is important to focus on this phase for major contribution in reduction of emissions.

Ammonia is one of the most useful compounds that react with NOx selectively on a catalyst, such as V2O5-TiO2, under oxygen containing exhaust gas. However ammonia cannot be stored because of its toxicity for the small power generator in populated areas or for the diesel vehicles. A new concept for NOx reduction in diesel engine using ammonia is introduced. This system is constructed from the hydrogen generator by fuel reformer, the ammonia synthesizer, SCR catalyst for NOx reduction and the gas injection system of reformed gas into the cylinder. Experimental results show that, the SCR catalyst provides a very high rate of NOx reduction, reformed gas injection into cylinder is very effective for particulate reduction. WHEN CONSIDERING INTERNAL COMBUSTION ENGINES of the 1990's the question of how to harmonize the engine with the natural environments is one of the greatest problems. The internal combustion engine changes a substance into energy via its explosive combustion.

Abstract An investigation into the pre-ashing of new gasoline particulate filters (GPFs) has demonstrated that the filtration efficiency of such filters can be improved by up to 30% (absolute efficiency improvement) when preconditioned using ash derived from a fuel-borne catalyst (FBC) additive. The additive is typically used in diesel applications to enable diesel particulate filter (DPF) regeneration and can be added directly into the fuel tank of the vehicle. This novel result was compared with ash derived from lube oil componentry, which has previously been shown to improve filtration efficiency in GPFs. The lube oil-derived ash utilized in this work improved the filtration efficiency of the GPF by −30%, comparable to the ash derived from the FBC additive.

This paper presents a numerical study on the impact of washcoat diffusion on the overall conversion performance of catalytic converters. A comprehensive transient 1D pore diffusion reaction model is embedded in state-of-the-art 1D and 3D catalytic converter models. The pore diffusion model is discussed with its model equations and the applied diffusive transport approaches are summarized. The diffusion reaction model is validated with the help of two available analytical solutions. The impact of basic washcoat characteristics such as pore diameters or thickness on overall conversion performance is investigated by selected 1D+1D calculations. This model is also used to highlight the impact of boundary layer transfer, pore diffusion and reaction on the overall converter conversion performance. The interaction of pore diffusion and flow non-uniformities is demonstrated by 3D+1D CFD simulations.

“Zoning” a catalytic converter involves placing higher concentrations of platinum group metals (PGM) in the inlet portion of the substrate. This is done to optimize the cost-to-performance tradeoff by increasing the reaction rate at lower temperatures while minimizing PGM usage. A potentially useful application of catalyst zoning is to improve performance using a constant PGM mass. A study was performed to assess what the optimum ratio of front to rear palladium zone length is to achieve the highest performance in vehicle emission testing. Varying the zone ratio from 1:1 to 1:9 shows a clear hydrocarbon performance optimum at a 1:5.66 (15%/85%) split. This performance optimum shows as both a minimum in FTP75 non-methane organic gas (NMOG) emissions as well as a minimum in hydrocarbon, carbon monoxide, and nitrogen oxide light-off temperature. Overall, an improvement of 18%, or 11 mg/mi of combined NMOG+NOx emissions was obtained without using additional PGM.

In spite of environmental issues related to cadmium and its electroplating process, electroplated cadmium is still extensively used in the aerospace and defense sectors. This trend is likely to continue especially for high strength steels because cadmium provides the best known corrosion and embrittlement protection for this application. Consequently, the environmental concerns related to the cadmium electroplating have been addressed using an alternative Zero-waste Physical Vapor Deposition (Z-PVD). This method does not use liquids, it recycles cadmium in situ, and is free of hydrogen embrittlement. The Z-PVD process is now in commercial production for the aerospace fasteners. The quality of the coatings has been at least equal to that of the electroplated cadmium.

This study aims at a new concept for a fast catalyst light-off in combining a latent heat storage with a catalyst. The arrangement of a latent heat storage device into the exhaust system offers significant benefits for the catalyst light-off. Different arrangements have been examined. The first arrangement, called the sequential arrangement, comprises a latent heat storage device and a subsequent catalyst. This offers a significantly faster heat up of the catalyst compared to the standard arrangement. By that emissions during the cold start phase can be significantly reduced. The setup of the latent heat storage device is designed for a high heat transfer between storage material and the exhaust gas. A second integrated arrangement of a latent heat storage and a catalyst into one common substrate has also been set up and investigated. The main advantage of this arrangement is that the catalyst itself is kept on its operation temperature during the engine off time.

OBD system requirements were first developed by the California Air Resources Board, the U.S. Environmental Protection Agency, and the European Commission. New OBD requirements should be as consistent as possible with existing requirements to maximize reliability and to minimize system complexity, proliferation of configurations, and consumer cost. New OBD requirements from around the world are briefly reviewed and most are consistent with the original U.S. and European requirements. Worldwide OBD requirements are being further harmonized under the United Nations, Economic Commission for Europe, World Forum for Harmonization of Vehicle Regulations (WP29). Presenter David H. Ferris, General Motors Company

To investigate the feasibility of various test procedures to determine aerodynamic performance for the Phase 2 Greenhouse Gas (GHG) Regulations for Heavy-Duty Vehicles in the United States, the US Environmental Protection Agency commissioned, through Southwest Research Institute, constant-speed torque tests of several heavy-duty tractors matched to a conventional 53-foot dry-van trailer. Torque was measured at the transmission output shaft and, for most tests, also on each of the drive wheels. Air speed was measured onboard the vehicle, and wind conditions were measured using a weather station placed along the road side. Tests were performed on a rural road in Texas. Measuring wind-averaged drag from on-road tests has historically been a challenge. By collecting data in various wind conditions at multiple speeds over multiple days, a regression-based method was developed to estimate wind-averaged drag with a low precision error for multiple tractor-trailer combinations.

This paper discusses the several reasons why vehicles do not achieve the EPA MPG values in service, and makes a numerical estimate of the magnitude of the individual effects. In addition, methods for adjusting EPA MPG values to estimate road fuel economy performance are presented and discussed.

The new American Petroleum Institute (API) categories for passenger car motor oils have focused on improving fuel economy and reducing emissions. This has resulted in more fuel efficient oils being developed by lowering the viscometrics and by adding friction modifiers. The emissions reductions have resulted from lowering the percent phosphorus (%P) in the engine oils because phosphorus has been found to poison the catalyst in the catalytic converter. When friction modifiers were introduced, researchers from four Japanese motorcycle manufacturers published the results of their studies (SAE 961217) which indicated that low friction oil can cause too much slippage in starter motor clutches, one-way limited slip clutches, and wet multi-plate clutches. In that same study they reported that engine manufacturers use 10W-30 grade oil to develop new engine technology, and gear pitting was observed with oils of viscosity grades lower than 10W-30 in all four manufacturers' motorcycle engines.

Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

PF&L is priority event for mobility professionals that specialize in powertrain, fuels, lubricants technology, including OEM and Tier 1 component suppliers Light medium and heavy-duty vehicle system and product design engineers.

September 17-19, 2019 │ Garden Grove, CA, USA

For an open exchange about the most promising new propulsion/powertrain-related technologies for light-, medium-, and heavy-duty vehicles, the SAE 2023 Powertrains, Fuels & Lubricants Conference & Exhibition (PF&L) is where you need to be.

For an open exchange about the most promising new propulsion/powertrain-related technologies for light-, medium-, and heavy-duty vehicles, the SAE 2023 Powertrains, Fuels & Lubricants Conference & Exhibition (PF&L) is where you need to be.