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Low NOx and soot free premixed diesel combustion can be realized by increasing ignition delays in low oxygen atmospheres, as well as the combustion here also depends on fuel ignitability. In this report single intermittent spray combustion with primary reference fuels and a normal heptane-toluene blend fuel under several oxygen concentrations in a constant volume combustion vessel was analyzed with high-speed color video and pressure data. Temperature and KL factor distributions are displayed with a 2-D two-color method. The results show that premixing is promoted with a decrease in oxygen concentration, and the local high temperature regions, above 2200 K, as well as the duration of their appearance decreases with the oxygen concentration. With normal heptane, mild premixed diesel combustion can be realized at 15 vol% oxygen and there is little luminous flame.

Diesel-like combustion of an emulsified blend of water and diesel fuel in a constant volume chamber vessel was visualized with high speed color video, further analyzing with a 2-D two color method and shadowgraph images. When the temperature at the fuel injection is 900 K, here while the combustion with unblended diesel fuel in the vessel is similar to ordinary diesel combustion with diffusive combustion, combustion with the emulsified fuel is similar to premixed diesel combustion with a large premixed combustion and very little diffusive combustion. With the emulsified fuel the flame luminosity and temperature are lower, the luminous flame and high temperature regions are smaller, and the duration of the luminous flame is shorter than with diesel fuel. This is due to promotion of premixing with increases in the ignition delay and decreases in the combustion temperature with the water vaporization.

The volatile organic compounds (VOC) from diesel engines, including formaldehyde and benzene, are concerned and remain as unregulated harmful substances. The substances are positively correlated with THC emissions, but the VOC and aldehyde compounds at light load or idling conditions are more significant than THC. When coolant temperatures are low at light loads, there are notable increases in formaldehyde and acetaldehyde, and with lower coolant temperatures the increase in aldehydes is more significant than the increase in THC. When using ultra high EGR so that the intake oxygen content decreases below 10%, formaldehyde, acetaldehyde, benzene, and 1,3-butadiene increase significantly while smokeless and ultra low Nox combustion is possible.

Ultra low emissions and high performance combustion was achieved with a combination of high EGR, a three-way catalyst, and a highly oxygenated liquid fuel, neat dimethoxy methane (DMM), in an ordinary DI diesel engine. The smokeless nature of neat DMM effectively allowed stoichiometric diesel combustion by controlling BMEP with EGR. NOx, THC, and CO emissions were reduced with a three-way catalyst. At lower BMEP with excess air, the EGR effectively reduced NOx. High-speed video in a bottom view type engine revealed that luminous flame decreased with increased fuel oxygen content and almost disappeared with DMM.

Significant improvements in exhaust emissions and engine performance in an ordinary DI diesel engine were realized with highly oxygenated fuels. The smoke emissions decreased sharply and linearly with increases in oxygen content and entirely disappeared at an oxygen content of 38 wt-% even at stoichiometric conditions. The NOx, THC, and CO were almost all removed with a three-way catalyst under stoichiometric diesel combustion at both the higher and lower BMEP with the combination of EGR and a three-way catalyst. The engine output for the highly oxygenated fuels was significantly higher than that with the conventional diesel fuel due to the higher air utilization.

The authors have reported significant smoke reduction in twin shaped semi-premixed diesel combustion with a newly designed combustion chamber to distribute the first and the second sprays into upper and lower layers. However, the first stage premixed combustion tends to advance far from the TDC, resulting in lowering of thermal efficiencies. In this report, improvement of thermal efficiency by optimizing the combustion phase with lower ignitability fuels was identified with the divided combustion chamber. The experiment was conducted with four fuels with different cetane numbers. The first stage premixed combustion can be retarded to the optimum phase with the fuel with cetane number 38, establishing high efficiencies.

To improve the combustion characteristics in semi-premixed diesel combustion, consisting in the first-stage premixed combustion of the primary fuel injection and the second-stage spray combustion of the secondary injection, the effect of splitting the primary injection was investigated in a diesel engine and analyzed with a CFD. The indicated thermal efficiency improves due to reductions in heat transfer losses to the in-cylinder wall and the combustion noise is suppressed with the split primary injections. The CFD analysis showed that the reduction in heat transfer loss with the split primary injections is due to a decrease in the combustion quantity near the combustion chamber wall.

Semi-premixed diesel combustion with a twin peak shaped heat release with the two-stage fuel injection (twin combustion) has the potential to establish efficient, low emission, and low noise operation. However, with twin combustion at low loads the indicated thermal efficiencies are poorer than at medium loads due to the lower combustion efficiencies. In this report, to increase the combustion efficiencies at low loads, the thermal efficiency related parameters were investigated in a 0.55 L single cylinder diesel engine. The results show that the indicated thermal efficiency improves with increases in the intake gas temperatures at low loads. However, at the higher loads where the combustion efficiencies are somewhat higher the indicated thermal efficiencies decrease with increases in the intake gas temperatures due to increases in the cooling losses.

To evaluate the relation between the intake air temperature (Tair-in), low temperature heat release (LTHR) and high temperature heat release (HTHR), a supercharged 4-cylinder engine with intake air heating, high compression pistons and a pressure transducer in each cylinder was introduced Eleven pure hydrocarbon components were blended into 23 different model fuels, labeled BASE MC01-MC11, and K01-K11. BASE is a mixture of equal proportion of each of the 11 pure hydrocarbons. The difference between MC series and K series fuels is in the amount of pure hydrocarbon added to the BASE: 6.5vol% for MC series fuels and 17.5vol% for K series fuels. Engine tests were performed with BASE and MC01-MC11 fuels at Tair-in=50°C (IMEP 530kPa), 80°C (IMEP 420kPa), and 100°C (IMEP 380kPa).

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

A study was performed in which the effects on the regulated emissions from a commercial small DI diesel engine were measured for different refinery-derived fuel blends. Seven different fuel blends were tested, of which two were deemed to merit more detailed evaluation. To investigate the effects of fuel properties on the combustion processes with these fuel blends, two-color pyrometry was used via optically accessible cylinderheads. Additional data were obtained with one of the fuel blends with a heavy-duty DI diesel engine. California diesel fuel was used as a baseline. The fuel blends were made by mixing the components typically found in gasoline, such as methyl tertiary-butyl ether (MTBE) and whole fluid catalytic cracking gasoline (WH-FCC). The mixing was performed on a volume basis. Cetane improver (CI) was added to maintain the same cetane number (CN) of the fuel blends as that of the baseline fuel.

A supercharged 4-cylinder engine was introduced to evaluate how fuel properties affect engine combustion and performance in homogeneous charge compression ignition (HCCI) operation. In this study, choosing from 12 hydrocarbon constituents, model fuels were mixed to have the same distillation but different octane numbers (RON=70, 80, 92). For each fuel, RON distribution against distillation is same to keep the same octane number in cylinder vapor during the air-fuel compression process. To confirm the appropriateness of model fuels and test procedures, regular gasoline (RON=90) was also included. From the combustion analysis it was clear that the low temperature heat release depends on fuel characteristics. RON92 fuel has a small low temperature heat release, and a high temperature heat release combusts slowly.

To reduce engine exhaust emissions, we have had to deal with this global environmental problem from the fuel side by introducing oxygenated fuels, reducing the RVP and using low aromatics. But when we change the fuel components and distillation, we must take note about how these affect the engine driveability. We have used T50, T90, RVP and so on as the fuel index up to the present. It is possible to characterize the fuel from one aspect, but these indexes don't always represent the real feature of the fuel. In this paper we propose a New Driveability Index (here in after referred to as NDI) that is more realistic and accurate than the other fuel indexes. We used a 1600cc DOHC L4 MPI type engine. We used Model Gasolines and Market Gasolines, see Appendix(1), (2) and (3), and tested them according to the Excess Air Ratio Response Test Method (here in after referred to as λ-R Test) that was suggested in SAE paper #930375, and we calculated the NDI statistically.

Synthetic fuels (e-fuels) synthesized from H2 and CO by renewable electricity are expected as the next- generation diesel fuels and two types of e-fuels have received extensive attention: Fischer-Tropsch (FT) fuel and Oxymethylene dimethyl ether (OME). In this study the effects of OME blending ratios with 0 to 50 vol.% in FT fuels on combustion, emissions and spray characteristics in diesel engines are investigated. The results suggest that the OME blends to FT fuels suppressed the deterioration in combustion efficiency under low intake oxygen concentration conditions. The smoke emissions of FT fuels and OME blended fuels were both lower than those of diesel fuel and decreased with the increase in the OME blend ratio, and the soot-NOx trade-off relation in diesel engines can be improved.

An HCCI combustion has a low temperature heat release (LTHR) and a high temperature heat release (HTHR). During the LTHR period, fuel chemicals break down into radicals and small hydrocarbons, and they assist an initial reaction of HTHR. This is an important role of LTHR. On the contrary, LTHR has a negative aspect. In general, a heating value of LTHR changes depending on HCCI engine load due to the difference of the injected fuel quantity. The heating value of LTHR is low under low load condition, and the heating value of LTHR is high under high load condition. This leads to the changes of the starting crank angle of HTHR against engine load and it is a nuisance problem for the control of HCCI engine operation. Therefore, a fuel which exhibits the constant LTHR phasing against engine load would be preferable.

Diesel combustion and emissions with four kinds of oxygenated agents as main fuels were investigated. Significant improvements in smoke, particulate matter, NOx, THC, and thermal efficiency were simultaneously realized with the oxygenates, and engine noise was also remarkably reduced for the oxygenates with higher ignitability. The improvements in the exhaust emissions and the thermal efficiency depended almost entirely on the oxygen content in the fuels regardless of the oxygenate to diesel fuel blend ratios and type of oxygenate. The unburned THC emission and odor intensity under starting condition with an oxygenate were also much lower than with conventional diesel fuel.

Characteristics of semi-premixed diesel combustion with a twin peak shaped heat release (twin combustion) were investigated under several in-cylinder gas conditions in a 0.55 L single cylinder diesel engine with common-rail fuel injection, super-charged, and with low pressure loop cooled EGR. The first-stage combustion fraction, the second injection timing, the intake oxygen concentration, and the intake gas pressure influence on thermal efficiency related parameters, the engine noise, and the exhaust gas emissions was systematically examined at a middle engine speed and load condition (2000 rpm, 0.7 MPa IMEP). The twin peak shaped heat release was realized with the first-stage premixed combustion with a sufficient premixing duration from the first fuel injection and with the second fuel injection taking place just after the end of the first-stage combustion.

It was reported that n-heptane and toluene blended fuels (NTL series fuels) showed the dual phase high temperature heat release (DP-HTHR) combustion in a previous SAE paper [1]. DP-HTHR has the potential to enlarge the engine operational range to high load conditions and lower the engine combustion noise. Further research has been reported in this paper. Initial interests were in the combustion characteristics of a second “bump” in the high temperature heat release (2nd HTHR) in DP-HTHR, since this kind of two-stage combustion appears, when CO oxidation radically occurs over the 1450K temperature range.

The engine performance and the exhaust gas emissions in a dual fuel compression ignition engine with natural gas as the main fuel and a small quantity of pilot injection of diesel fuel with the ultra-high injection pressure of 250 MPa as an ignition source were investigated at 0.3 MPa and 0.8 MPa IMEP. With increasing injection pressure the unburned loss decreases and the thermal efficiency improves at both IMEP conditions. At the 0.3 MPa IMEP the THC and CO emissions are significantly reduced when maintaining the equivalence ratio of natural gas with decreasing the volumetric efficiency by intake gas throttling, but the NOx emissions increase and excessive intake gas throttling results in a decrease in the indicated thermal efficiency. Under the 250 MPa pilot injection condition simultaneous reductions in the NOx, THC, and CO emissions can be established with maintaining the equivalence ratio of natural gas by intake gas throttling.

Premixed diesel combustion offers the potential of high thermal efficiency and low emissions, however, because the rapid rate of pressure rise and short combustion durations are often associated with low temperature combustion processes, noise is also an issue. The reduction of combustion noise is a technical matter that needs separate attention. Engine noise research has been conducted experimentally with a premixed diesel engine and techniques for engine noise simulation have been developed. The engine employed in the research here is a supercharged, single cylinder DI diesel research engine with a high pressure common rail fuel injection system. In the experiments, the engine was operated at 1600 rpm and 2000 rpm, the engine noise was sampled by two microphones, and the sampled engine noise was averaged and analyzed by an FFT sound analyzer.