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The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

Pilot injection (PI) during the negative-valve-overlap (NVO) period is one method to improve control of combustion in gasoline controlled auto-ignition engines. This is generally attributed to both chemical and thermal effects. However, there are little experimental data on active species formed by the combusting PI and their effect on main combustion in real engines. Thus, it is the objective of the current study to apply and assess optical in-cylinder diagnostics for these species. Firstly, the occurrence and nature of combustion during the NVO period is investigated by spectrally-resolved multi-species flame luminescence measurements. OH*, CH*, HCO*, CO-continuum chemiluminescence, and soot luminosity are recorded. Secondly, spectrally-, spatially-, and cycle-resolved laser-induced fluorescence measurements of formaldehyde are conducted. It is attempted to find a cycle-resolved measure of the chemical effect of PI.

As emission regulations are becoming increasingly stringent worldwide, multiple exhaust aftertreatment devices are considered in order to minimize diesel engine tailpipe emissions. For the typical diesel applications in developing markets like India, the fuel consumption is a very decisive selling argument for customers. The total cost of ownership needs to be as low as possible. To meet these competing requirements, the aftertreatment and engines must be optimized at the same time as the performance of the one system affects the other. In state-of-the-art calibration processes, the aftertreatment systems are considered separately from the calibration of the thermodynamics. This conventional approach makes it more challenging to achieve a simultaneous optimization of the fuel consumption and tailpipe emissions under transient operating conditions.

The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

Multiple-injection strategies are widely used in DI diesel engines. However, the interaction of the injection pulses is not yet fully understood. In this work, a split injection into a combustion vessel is studied by multiple optical imaging diagnostics. The vessel provides quiescent high-temperature, high-pressure ambient conditions. A common-rail injector which is equipped with a three-hole nozzle is used. The spray is visualized by Mie scattering. First and second stage of ignition are probed by formaldehyde laser-induced fluorescence (LIF) and OH* chemiluminescence imaging, respectively. In addition formation of soot is characterized by both laser-induced incandescence (LII) and natural luminosity imaging, showing that low-sooting conditions are established. These qualitative diagnostics yield ensemble-averaged, two-dimensional, time-resolved distributions of the corresponding quantities.

In order to reduce engine out CO2 emissions it is a main subject to find new alternative fuels out of renewable sources. For this reason in this paper a blend out of 1-octanol and di-n-butylether and pure di-n-butylether are investigated in comparison to n-heptane as diesel-like fuel. The alternative fuels have a different combustion behavior particularly concerning important combustion parameters like ignition delay and mixture formation. Especially the formation of pollutants like nitrogen oxides in the combustion of alternative fuels is of global interest. The knowledge of the combustion behavior is important to design new engine geometries or implement a new calibration of the engine. In previous measurements in a single cylinder engine it was found out that both alternative fuels form nearly no soot emissions. For this reason now NOx is investigated optically to avoid the traditional soot NOx trade-off in diesel combustion.

Maintaining low NOx emissions over the operating range of diesel engines continues to be a major issue. However, optical measurements of nitric oxide (NO) are lacking particularly in the core of diesel jets, i.e. in the region of premixed combustion close to the spray axis. This is basically caused by severe attenuation of both the laser light and fluorescent emission in laser-induced fluorescence (LIF) applications. Light extinction is reduced by keeping absorption path lengths relatively short in this work, by investigating diesel jets in a combustion vessel instead of an engine. Furthermore, the NO-detection threshold is improved by conducting 1-d line measurements instead of 2-d imaging. The NO-LIF data are corrected for light attenuation by combined LIF and spontaneous Raman scattering. The quantified maximum light attenuation is significantly lower than in comparable previous works, and its wavelength dependence is surprisingly weak.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

Improvements in the efficiency of internal combustion engines has led to a reduction in exhaust gas temperatures. The simultaneous tightening of exhaust emission limits requires ever more complex emission control methods, including aftertreatment whose efficiency is crucially dependent upon the exhaust gas temperature. Double-walled (also called air-gap) exhaust manifold and turbine housing modules made from sheet metal have been used in gasoline engines since 2009. They offer the potential in modern Diesel engines to reduce both the emissions of pollutants and fuel consumption. They also offer advantages in terms of component weight and surface temperatures in comparison to cast iron components. A detailed analysis was conducted to investigate the potential advantages of insulated exhaust systems for modern diesel engines equipped with DOC and SCR coated DPF (SDPF).

Within a project of the Research Association for Combustion Engines e.V., different measures for rising the temperature of exhaust gas aftertreatment components of both a passenger car and an industrial/commercial vehicle engine were investigated on a test bench as well as in simulation. With the passenger car diesel engine and different catalyst configurations, the potential of internal and external heating measures was evaluated. The configuration consisting of a NOx storage catalyst (NSC) and a diesel particulate filter (DPF) illustrates the potential of an electrically heated NSC. The exhaust aftertreatment system consisting of a diesel oxidation catalyst (DOC) and a DPF shows in simulation how variable valve timing in combination with electric heated DOC can be used to increase the exhaust gas temperature and thus fulfill the EU6 emission limits.

The optimization study presented herein is aimed to minimize the fuel consumption and engine-out emissions using commercially available EN15940 compatible HVO (Hydrogenated Vegetable Oil) fuel. The investigations were carried out on FEV’s 3rd generation HECS (High Efficiency Combustion System) multi-cylinder engine (1.6L, 4 Cylinder, Euro 6). Using a global DOE approach, the effects of calibration parameters on efficiency and emissions were obtained and analyzed. This was followed by a global optimization procedure to obtain a dedicated calibration for HVO. The study was aiming for efficiency improvement and it was found that at lower loads, higher fractions of low pressure EGR in combination with lower fuel injection pressures were favorable. At higher loads, a combustion center advancement, increase of injection pressure and reduced pilot injection quantities were possible without exceeding the noise and NOx levels of the baseline Diesel.

Within this study a dual-fuel concept was experimentally investigated. The utilized fuels were conventional EN228 RON95E10 and EN590 Diesel B7 pump fuels. The engine was a single cylinder Diesel research engine for passenger car application. Except for the installation of the port fuel injection valve, the engine was not modified. The investigated engine load range covered low part load operation of IMEP = 4.3 bar up to IMEP = 14.8 bar at different engine speeds. Investigations with Diesel pilot injection showed that the dual-fuel approach can significantly reduce the soot/NOx-trade-off, but typically increases the HC- and CO-emissions. At high engine load and gasoline mass fraction, the premixed gasoline/air self-ignited before Diesel fuel was injected. Reactivity Controlled Compression Ignition (RCCI) was subsequently investigated in a medium load point at IMEP = 6.8 bar.

Fuel consumption and NOx emissions of gasoline engines at part load can be significantly reduced by Controlled Auto-Ignition combustion concepts. However, the range of Gasoline Controlled Auto-Ignition (GCAI) operation is still limited by lacking combustion stability at low load and by high pressure-rise rates toward higher loads. Previous investigations indicate that the auto-ignition process is particularly determined by the thermodynamic state of the charge and by stratification effects of residual gas, temperature, and air-fuel ratio. However, little experimental data exist on the direct influence of mixture stratification on local ignition and heat-release rate (HRR) in direct-injection (DI) GCAI engines, because it is challenging to measure all the relevant charge and combustion parameters quasi-simultaneously with sufficient spatial/temporal resolution and precision.

It is demonstrated that direct air injection leads to substantial improvement of the cold starting performance of an SI engine. Raw pollutant formation is considerably reduced and fuel conversion efficiency increased. Air is directly injected into the cylinder through a small orifice during the compression stroke. Optical measurement techniques, in particular Spontaneous Raman Scattering, are applied to elucidate the in-cylinder processes that lead to improved cold starting perfomance. It is demonstrated that air injection causes enhanced combustion via increased turbulence and this leads to rapid warm-up of the combustion chamber walls. Thus the quality of the combustion process after the first few cycles is comparable to warmed-up engine operating conditions. It turned out to be possible to avoid fuel-enrichment and start the engine with lean fuel/air mixture (at 20°C).

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Despite the trend in increased prosperity, the Indian automotive market, which is traditionally dominated by highly cost-oriented producion, is very sensitive to the price of fuels and vehicles. Due to these very specific market demands, the U-LCV (ultra-light commercial vehicle) segment with single cylinder natural aspirated Diesel engines (typical sub 650 cc displacement) is gaining immense popularity in the recent years. By moving to 2016, with the announcement of leapfrogging directly to Bharat Stage VI (BS VI) emission legislation in India, and in addition to the mandatory application of Diesel particle filters (DPF), there will be a need to implement effective NOx aftertreament systems. Due to the very low power-to-weight ratio of these particular applications, the engine operation takes place under full load conditions in a significant portion of the test cycle.

The influence of different fuels and injection pressures on the flame lift-off length (LOL), as well as the combustion structure under quiescent conditions in a heated high-pressure vessel were experimentally investigated using OH chemiluminescence measurements. This data was used to validate the newly developed G-equation coupled with MRIF (G-MRIF) model, which was designed to describe the lifted Diesel combustion process. The achieved results are very promising and could be used as a tool to apply this combustion mode into Diesel engines. Furthermore these measurements were used to validate the approach of a new combustion model, which was developed using former OH chemiluminescence measurements by the authors. Based on this approach the LOL is mainly determined by auto-ignition and therefore highly dependent on the cetane number. This model is presented in more detail within this work.

Due to experimental challenges, combustion of diesel-like jets has rarely been characterized by laser-based quantitative multiscalar measurements. In this work, recently developed laser diagnostics for combustion temperature and the concentrations of CO, O2, and NO are applied to a diesel-like jet, using a highly oxygenated fuel. The diagnostic is based on spontaneous Raman scattering (SRS) and laser-induced fluorescence (LIF) methods. Line imaging yields multiscalar profiles across the jet cross section. Measurements turn out to be particularly accurate, because near-stoichiometric combustion occurs in the central region of the jet. Thereby, experimental cross-influences by light attenuation and interfering emissions are greatly reduced compared to the combustion of conventional, sooting diesel fuel jets. This is achieved by fuel oxygenation and enhanced premixing.

Tailor-made multi-component fuels are currently being developed for advanced Diesel engines. Accordingly, there is renewed interest in the detailed evaporation characteristics of such multi-component fuels, in particular because soot formation in reacting Diesel sprays generally depends on the mixture formation upstream of the lift-off location. It is also well established that fuel components with different volatility are generally not coevaporative due to fractional distillation in the mixture formation process of spark-ignition engines, but it is not clear if this holds for Diesel-like sprays, in which evaporation and mixing are expected to be more rapid. Unfortunately, little work has been done in this field, and some of the previous results appear to be contradictory. This paper presents a new laser diagnostic approach, which yields the vapor-phase concentrations of two fuel components simultaneously in Diesel-like sprays.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.