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The time of, and location where ignition first occurs in a diesel fuel spray were investigated in a rapid compression machine (RCM) using the two–dimensional techniques of silicone oil particle scattering imaging (SSI), and the planar laser induced fluorescence (LIF) of formaldehyde. Formaldehyde has been hypothesized to be one of the stable intermediate species marking the start of oxidation reactions in a transient spray under compression ignition conditions. In this study, the LIF images of the formaldehyde formed in a diesel fuel spray during ignition process have been successfully obtained for the first time by exciting formaldehyde with the 3rd harmonic of the Nd:YAG laser. SSI images of the vaporizing spray, and the LIF images of formaldehyde were obtained together with the corresponding time record of combustion chamber pressures at initial ambient temperatures ranging from 580 K to 790 K.

In order to clarify the reason why NOx emissions factor becomes higher at vehicle acceleration at intersections etc, two freight vehicles, that have EGR system for the reduction of NOx, were tested by an on-board NOx measurement system. Higher NOx emissions factor was observed in operations in lower-gear operation for each vehicle. Since the engine speed change was higher in the operation of lower gears, NOx emissions characteristics were analyzed in view of engine torque, NOx mass emissions and EGR rate, considering engine speed change. It was found that lower-gear operations made the engine speed change higher and the EGR rate lower. This seems to be one of the factors to engender the intensive NOx pollution at roadsides.

The HCCI engine is a next generation engine, with high efficiency and low emissions. However a rate of pressure rise is a major limitation for high load range. Recently, we are able to reduce the rate of pressure rise using thermal stratification. Nevertheless, this was insufficient to produce high power. Without the higher equivalent ratio, one way to improve the power is to increase the intake boost pressure. It is suggested that the rate of pressure rise is reduced by thermal stratification and the power is increased by boost pressure at the same time. The objective of this work is to understand the characteristics of combustion, knock and emissions for using both thermal stratification and the boost pressure. The calculations are performed by CHEMKIN and modified SENKIN. As a result of increasing the boost pressure, a higher IMEP was attained while the rate of pressure rise increased only slightly in the HCCI with thermal stratification.

CNG/diesel dual-fuel engine is using CNG as a main fuel, and injects diesel only a little as an ignition priming. In this study, remodeling an existing diesel engine into dual-fuel engine that can inject diesel with high pressure by CRDI (Common Rail Direct Injection), and injecting CNG at intake port for premixing. The results show that CNG/diesel dual-fuel engine satisfied coordinate torque and power with conventional diesel engine. And CNG alternation rate is over 89% in all operating ranges of CNG/diesel dual-fuel engine. PM emission is lower 94% than diesel engine, but NOx emission is higher than diesel engine. The output of dual fuel mode is 95% by the diesel mode. At this time, amount of CO₂ and PM are decreased while CO, NOx, and THC are increased. In NEDC mode, exhaust gases except NOx are decreased.

Super lean burn technology is conceived as one of methods for improving the thermal efficiency of SI engines[1][2]. For lean burn, reduction of heat loss and the due to decrease in flame temperature can be expected. However, as the premixed gas dilutes, the combustion speed decreases, so the combustion fluctuation between cycles increases. Also, to improve the thermal efficiency, the ignition timing is advanced to advance the combustion phase. However, when the combustion phase is excessively advanced, knocking occurs, which hinders the improvement of thermal efficiency. Knocking is a phenomenon in which unburned gas in a combustion chamber compressed by a piston and combustion gas suffer compression auto-ignition. It is necessary to avoid knocking because the amplitude of the large pressure wave may cause noise and damage to the engine. Also, knocking is not a steady phenomenon but a phenomenon that fluctuates from cycle to cycle.

A single action rapid compression machine was developed to observe the soot formation and oxidation processes in a diesel spray flame. Two color method was applied to analyze the flame temperature and KL factor from the flame image taken by high speed camera. Variation in gas oxygen concentration of the surrounding gas was achieved by adding different quantities of pure oxygen, nitrogen, carbon dioxide and argon gases to charged air within a range from 17 to 25 vol.% oxygen to examine the effects of the surrounding gas composition and the temperature, and of the flame temperature on soot formation and extinction. The initial gas temperature has much effect not only on the ignition but on soot formation speed. The higher oxygen concentration gives the higher flame temperature and the faster soot oxidation rate in the flame. Carbon dioxide has a soot reduction effect in spite of its lower flame temperature.

An on-board measurement system that simultaneously measures road traffic, vehicle running conditions and exhaust emissions was installed in a diesel freight vehicle with two tons payload. Actual NOx mass emissions were compared with that measured in a typical test mode for urban cities on a chassis dynamometer. The frequency of vehicle accelerations in actual urban cities was found to exceed that of a typical test mode for urban cities on a chassis dynamometer, which resulted in increased NOx from actual running conditions compared with the typical test mode for urban cities. The dynamics of NOx emissions at an actual roadside was also analyzed. It was observed that NOx emission based on distance with an actual city route test was about two times higher than that of a free way route and a typical test mode for urban cities. The reason for high NOx with the city route was explained by the higher frequency of lower gears at which higher NOx is emitted.

Reduction of particulate emissions from diesel engine is an important theme from the view point of air pollution. Experiments were carried out using a four-stroke single cylinder direct-injection diesel engine. A new method to measure diesel particulates has been developed. Particulates were sampled with a freezing method just behind an exhaust valve and examined through a scanning electron microscope. Shape and structure of particulates and the size distributions are measured under wide operating conditions obtained with above method. The total mass of particulate emissions was measured using a dilution tunnel sampling system. The heat release processes were analyzed using indicator diagrams and the relation between burning condition and particulate emissions were discussed, after systematic experiments under constant revolution speed of 2000 r/min for several load and injection timing conditions.

In the HCCI (Homogeneous Charge Compression Ignition) engine, a mixture of fuel and air is supplied to the cylinder and auto-ignition occurs resulting from compression. This method can expand the lean flammability limit, realizing smokeless combustion and also having the potential for realizing low NOx and high efficiency. The optimal ignition timing is necessary in order to keep high thermal efficiency. The Ignition in the HCCI engine largely depends on the chemical reaction between the fuel and the oxidizer. Physical methods in conventional engines cannot control it, so a chemical method is demanded. Combustion duration is maintained properly to avoid knocking. In addition, the amount of HC and CO emissions must be reduced. The objective of this study is to clarify the following through calculations with detailed chemical reactions and through experiment with the 2-stroke HCCI engine: the chemical reaction mechanism, and HC and CO emission mechanisms.

The charge stratification has been thought as one of the ways to reduce the sharp pressure rises of HCCI combustion. The objective of this study is to evaluate the potential of equivalence ratio, initial temperature, and EGR gas stratifications for reducing pressure-rise rate of HCCI combustion. Using rapid compression machine, the stratified pre-mixture is charged, and compressed to analyze the change of in-cylinder gas pressure and temperature traces during compression process. Based on the experiment results, numerical calculations by CHEMKIN are conducted to more specifically analyze the potential of equivalence ratio, initial temperature, and EGR gas stratifications on the reduction of pressure rise rate. Multi-zone model is used to simulate the thermal stratification, fuel stratification and EGR gas stratification of in-cylinder charge as like real engine.

This study tried to find a potential of dedicated EGR (d-EGR) system added to the four-cylinder spark ignition (SI) engine to decrease heat loss (Qheatloss) and improve thermal efficiency (ηth). Test fuels were chosen by methane and propane. PREMIX code in CHEMKIN-PRO was employed to calculate laminar burning velocity (SL) and flame temperature (Tf). Wiebe function and Wocshni's heat transfer coefficient were considered to calculate ηth. The results show that the d-EGR system increased ηth and it was higher than that of stoichiometric combustion of conventional SI engines due to the low Tf and fast SL.

The combustion mechanism of the homogeneous charge compression ignition (HCCI) engine has been investigated by numerical calculations. Calculations were carried out using n-butane/air elementary reactions at 0 dimension and adiabatic condition to simplify the understanding of chemical reaction mechanisms in the HCCI engine without complexities of walls, crevices, and mixture inhomogeneities. n-Butane is the fuel with the smallest carbon number in the alkane family that shows two-stage auto-ignition, heat release with low temperature reaction (LTR) and high temperature reaction (HTR), similar to higher hydrocarbons such as gasoline at HCCI combustion. The CHEMKIN II code, SENKIN and kojima's n-butane elementary reaction scheme were used for the calculations. This paper consists of three main topics. First, the heat release mechanisms of the HCCI engine were investigated. The results show that heat release with LTR is HCHO oxidation reactions.

To approach realization of Homogeneous Charge Compression Ignition (HCCI) combustion without external combustion ignition trigger, it is necessary to construct HCCI engine control system. In this study, HCCI research engine equipped with the EGR passage for external EGR and the two-stage exhaust cam for exhaust rebreathed. This system can control the mixing ratio of four gases (air, fuel, rebreathed EGR gas, external EGR gas) of in-cylinder by operating four throttles and fuel injection duration while maintaining acceptable pressure rise rate (PRR) and cycle-to-cycle variation of Indicated Mean Effective Pressure (IMEP), closed-loop control system designed by applying feedback variables (equivalence ratio, combustion-phasing, IMEP) for feedback control. Those control inputs (four throttles and fuel injection) has correlation mutually, control inputs cause interference, response become low and hunching occurs.

Nitrogen oxides, collectively called NOx, from diesel vehicles are considered to be accumulated by particular area of roadsides, so-called "Hot-spot," and result in harmful influence to pedestrians and residents by roadsides. Japanese regulations over emissions of diesel vehicles have been tightened year by year and adopting regulations, emissions in mode test on chassis dynamometer or engine dynamometer have reduced. In this research, it was investigated the effect of introduce of transient mode test, Japanese JE05 mode, to NOx emission in real world and to roadside NOx pollution by road test using on-board measurement system. As test vehicles, 2 ton diesel vehicle which is adopted for Long Term Regulation (steady-state mode test, Diesel 31 mode test, 1998) and 3 ton diesel vehicle adopted for New Long Term Regulation (transient mode test, Japanese JE05 mode, 2005) with on-board measurement system was used.

The thermal efficiency of a spark-ignition (SI) engine must be improved to reduce both environmental load and fuel consumption. Although lean SI engine operation can strongly improve thermal efficiency relative to that of stoichiometric SI operation, the cycle-to-cycle variation (CCV) of combustion increases with the air dilution level. Combustion CCV is caused by CCVs of many factors, such as EGR, spark energy, air-fuel ratio, and in-cylinder flow structure related to engine speed. This study focuses on flow structures, especially the influence of a tumble structure on flow fluctuation intensity near ignition timing. We measured the flow field at the vertical center cross section of an optically accessible high-tumble flow engine using time-resolved particle image velocimetry. There are many factors considered to be sources of CCV, we analyzed three factors: the intake jet distribution, distribution of vortex core position and trajectory of the fluid particle near the spark plug.

Lean burn is one method for improving thermal efficiency in spark ignition (SI) engines. Suppression of knocking provides higher thermal efficiency, and ethanol blending is considered an effective way to suppress knocking due to its high octane and high latent heat of evaporation. We investigate the effect of ethanol blending on knocking in an SI engine under lean operating conditions. The Livengood-Wu (LW) integral was performed based on ignition delay duration estimated from a zero-dimensional detailed chemical reaction calculation with pressure and temperature histories. Knocking was suppressed and thermal efficiency increased with ethanol-gasoline blending fuel, even at 0.5 equivalence ratio. Decrease in unburned gas temperature by latent heat of evaporation had a comparable influence on knocking suppression, which was supported by LW integral analysis.

This work experimentally investigates how the dwell time between pilot injection and main injection influences combustion characteristics and emissions (NOx, CO, THC and Smoke) in a single-cylinder DI diesel engine. Additionally, results from diesel injection are compared with those shown in dimethyl ether (DME) injection under the identical injection strategy to demonstrate the sensitivity of the combustion characteristics and emissions to changes of the fuel type. Two fuel injection systems are applied for this experiment due to the differences of fuel characteristic with regard to physical and chemical properties. The injection strategy is accomplished by varying the dwell time (10°CA, 16°CA and 22°CA) between injections at five main injection timings (-4°CA aTDC, -2°CA aTDC, TDC, 2°CA aTDC and 4°CA aTDC). It was found that pilot injection offers good potential to lower the heat-release rate with reduced pressure traces regardless of the dwell time between injections and fuel type.

The purpose of this study is to determine a pilot injection control strategy for the improvement of dual-fuel combustion with a lean natural gas/air mixture. Experiments were performed using a single cylinder test engine equipped with a common-rail injection system. The injection pressure, timing and quantity were varied at a fixed overall equivalence ratio of 0.5. The results of single-stage-injection experiments show that middle injection timings (−20 to −10 degATDC) produce low emissions of unburned species, because the pilot-fuel vapor spreads into the natural-gas lean mixture and raises the effective equivalence ratio, which leads to fast flame propagation. Early injection (−35degATDC) is advantageous for low NOx emission; however, increased emissions of unburned species are barriers.

The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

A fuel design concept for an HCCI engine based on chemical kinetics to optimize the heat release profile and achieve robust ignition was proposed, and applied to the design of the optimal methane-based blend. Ignition process chemistry of each single-component of natural gas, methane, ethane, propane, n-butane and isobutane, was analyzed using detailed chemical kinetic computations. Ethane exhibits low ignitability, close to that of methane, when the initial temperature is below 800 K, but higher ignitability, close to those of propane, n-butane and isobutane, when the initial temperature is above 1100 K. Furthermore, ethane shows a higher heat release rate during the late stage of the ignition process. If the early stage of an ignition process takes place during the compression stroke, this kind of heat release profile is desirable in an HCCI engine to reduce cycle-to-cycle variation during the expansion stroke.