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Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.

With the increasing demand of emission reductions from the automotive industry, advanced after-treatment strategies have been investigated to overcome the challenges associated with meeting increasingly stringent emission regulations. Ongoing investigations on low temperature combustion (LTC) strategies are being researched to meet future emission regulations, however, the lowered exhaust temperature presents an even greater issue for exhaust after-treatment due to the change in combustion modes. Catalyst temperature is critical for the catalytic ability to maintain effective conversion efficiency of regulated emissions. The use of periodic flow reversal has shown benefits of maintaining catalyst temperature by alternating the exhaust flow direction through the catalytic converter, reducing the catalyst sensitivity to inlet gas temperature fluctuations.

Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.

Cold starting problems of diesel engines are caused mainly by the failure of the auto-ignition process or the subsequent combustion of the rest of the charge. The problems include long cranking periods and combustion instability leading to an increase in fuel consumption in addition to the emission of undesirable unburned hydrocarbons which appear in the exhaust as white smoke. The major cause of these problems is the low temperature and pressure of the charge near the end of the compression stroke and/or the poor ignition quality of the fuel. This paper presents the results of an experimental investigation of cold starting of a high speed diesel engine with ULSD (Ultra Low Sulphur Diesel) and JP8 (Jet Propulsion) fuels at ambient temperature (25°C). A detailed analysis is made of the autoignition and combustion of the two fuels in the first few cycles in the cold start transient. In addition, a comparison is made between these processes for the two fuels during idle operation.

Engine-out HC emissions were investigated during cold and hot starts. The tests were conducted at room temperature, on a new Chrysler 2.4-L, 4-cylinder, 16-valve, DOHC, multipoint-port-fuel-injection gasoline engine. Real time engine-out HC emissions were measured using Cambustion Fast Response Flame Ionization Detector (FRFID). Sources of unburned hydrocarbon emissions were discussed in details. Unburned hydrocarbons emitted during the cold-start were much higher than the hot-start. Cylinder-to-cylinder variation was investigated. A fuel inventory program was used to characterize total injected fuel, burned fuel, unburned HC, and fuel unaccounted for (mainly accumulated fuel in the engine system and CO). A fuel interrupt test was run to examine the possibility of burning the leftover fuel after the fuel shut-off. The contribution of the cold and hot start modes in engine-out HC emissions was determined.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

A production V-8 engine was redesigned to run on low temperature combustion (LTC) with conventional Diesel fuel. Two fuel injection strategies were used to attain reduction in soot and NOx; a) early premixed injection strategy: fuel injected early during the compression stroke and b) late premixed injection strategy: fuel injected close to TDC with heavy EGR. The early premixed injection strategy yielded low NOx and soot but struggled to vaporize the fuel as noted in unburned hydrocarbons readings. The late premixed injection strategy introduced the fuel at higher in-cylinder temperatures and densities, improving the fuel's vaporization and limited the unburned hydrocarbon and carbon monoxide. The use of high EGR and high injection pressure for late premixed injection strategy provided sufficiently long ignition delay that resulted in partially premixed cylinder charge before combustion, and thereby prevented high soot, even in presence of high EGR.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

I The effect of Cetane Number (CN) of the fuel and the addition of cetane improvers on the cold starting and white smoke emissions of a diesel engine was investigated. Tests were conducted on a single-cylinder, four-stroke-cycle, air-cooled, direct-injection, stand-alone diesel engine in a cold room at ambient temperatures ranging from 25 °C to - 5 °C. Five fuels were used. The base fuel has a CN of 49.2. The CN of the base fuel was lowered to 38.7 and 30.8 by adding different amounts of aromatic hydrocarbons. Iso-octyl nitrate is added to the high aromatic fuels in order to increase their CN to 48.6 and 38.9 respectively. Comparisons are made between the five fuels to determine the effect of CN and the additive on cylinder peak pressure, heat release rate, cold start-ability, combustion instability, hydrocarbon emissions and solid and liquid particulates.

The effects of different blends of Soybean Methyl Ester (biodiesel) and ultra low sulfur diesel (ULSD) fuel: B-00 (ULSD), B-20, B-40, B-60, B-80 and B-100 (biodiesel); on autoignition, combustion, performance, and engine out emissions of different species including particulate matter (PM) in the exhaust, were investigated in a single-cylinder, high speed direct injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated at 1500 rpm under simulated turbocharged conditions at 5 bar IMEP load with varied injection pressures at a medium swirl of 3.77 w ithout EGR. Analysis of test results was done to determine the role of biodiesel percentage in the fuel blend on the basic thermodynamic and combustion processes under fuel injection pressures ranging from 600 bar to 1200 bar.

Wall-wetting due to liquid fuel film motion and fuel droplet impingement on combustion chamber walls is a major source of unburned hydrocarbons (UBHC), and is a concern for oil dilution in PFI engines. An experimental study was carried out to investigate the effects of injection timing, a charge motion control device, and the matching of injector with port geometry, on the “footprints” of liquid fuel inside the combustion chamber during the PFI engine starting process. Using a gasoline-soluble dye and filter paper deployed on the cylinder liner and piston top land surfaces to capture the liquid fuel footprints, the effects of the mixture formation processes on the wetted footprints can be qualitatively and quantitatively examined by comparing the wetted footprint locations and their color intensities. Real-time filming of the development of wetted footprints using a high-speed camera can also show the time history of the fuel wetting process inside an optically accessible engine.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested via a variety of driving cycles using California Phase 2 reformulated gasoline. A comparable PFI vehicle was also evaluated. The standard driving cycles examined were the Federal Test Procedure (FTP), Highway Fuel Economy Test, US06, simulated SC03, Japanese 10-15, New York City Cycle, and European ECE+EDU. Engine-out and tailpipe emissions of gas phase species were measured each second. Hydrocarbon speciations were performed for each phase of the FTP for both the engine-out and tailpipe emissions. Tailpipe particulate mass emissions were also measured. The results are analyzed to identify the emissions challenges facing the DISI engine and the factors that contribute to the particulates, NOx, and hydrocarbon emissions problems of the DISI engine.

Modern diesel engines were known for producing ultra-low levels of hydrogen and hydrocarbons. However, as emission control techniques such as exhaust gas recirculation (EGR) are implemented to meet stringent NOx standards, the resulting increase in partial-combustion products can be significant in quantity both as pollutants and sources of lost engine efficiency. In this work, a modern common-rail diesel engine was configured to investigate the EGR threshold for elevated carbon monoxide, hydrocarbon, and hydrogen emissions at fixed loads and fixed heat-release phasing. It is noted that increase in hydrocarbons, in particular light hydrocarbons (such as methane, ethylene, and acetylene) was concurrent with ultra-low NOx emissions. Hydrogen gas can be emitted in significant quantities with the application of very high EGR. Under ultra-low NOx production conditions for medium and high load conditions, the light hydrocarbon species can account for the majority of hydrocarbon emissions.

Hybrid electric vehicles (HEVs) may have key fuel economy and emissions advantages over current conventional vehicles, but they have drawbacks such as frequent engine starts that can slow down market penetration of HEVs. First, the hydrocarbon emissions due to the numerous engine starts would make newly developed HEV powertrains even more demanding on the emission control system. Second, frequent starts may make the engine deteriorate quickly. This study is an attempt to gain a better understanding of the engine start characteristics of two limited-production HEVs (Toyota Prius and Honda Insight). Using fast-response (5 ms) hydrocarbon and NO (nitric oxide) analyzers, the transient emissions were measured in the engine exhaust ports during cold and hot engine starts. On the basis of the experimental findings, several recommendations were made to improve performance and emissions of future HEVs.

The necessity to study spray-wall interaction in internal combustion engines is driven by the evidence that fuel sprays impinge on chamber and piston surfaces resulting in the formation of wall films. This, in turn, may influence the air-fuel mixing and increase the hydrocarbon and particulate matter emissions. This work reports an experimental and numerical study on spray-wall impingement and liquid film formation in a constant volume combustion vessel. Diesel and n-heptane were selected as test fuels and injected from a side-mounted single-hole diesel injector at injection pressures of 120, 150, and 180 MPa on a flat transparent window. Ambient and plate temperatures were set at 423 K, the fuel temperature at 363 K, and the ambient densities at 14.8, 22.8, and 30 kg/m3. Simultaneous Mie scattering and schlieren imaging were carried out in the experiment to perform a visual tracking of the spray-wall interaction process from different perspectives.

Diesel aided by gasoline low temperature combustion offers low NOx and low soot emissions, and further provides the potential to expand engine load range and improve engine efficiency. The diesel-gasoline operation however yields high unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions. This study aims to correlate the chemical origins of the key hydrocarbon species detected in the engine exhaust under diesel-gasoline operation. It further aims to help develop strategies to lower the hydrocarbon emissions while retaining the low NOx, low soot, and efficiency benefits. A single-cylinder research engine was used to conduct the engine experiments at a constant engine load of 10 bar nIMEP with a fixed engine speed of 1600 rpm. Engine exhaust was sampled with a FTIR analyzer for speciation investigation.

In this work, empirical investigations of the diesel-ethanol Premixed Pilot-Assisted Combustion (PPAC) are carried out on a high compression ratio (18.2:1) single-cylinder diesel engine. The tests focus on determining the minimum ethanol fraction for ultra-low NOx & soot emissions, effect of single-pilot vs. twin-pilot strategies on emissions and ignition controllability, reducing the EGR requirements, enabling clean combustion across the load range and achieving high efficiency full-load operation. The results show that both low NOx and almost zero soot emissions can be achieved but at the expense of higher unburned hydrocarbons. Compared to a single-pilot injection, a twin-pilot strategy reduces the soot emissions significantly and also lowers the NOx emissions, thereby reducing the requirements for EGR. The near-TDC pilot provides excellent control over the combustion phasing, further reducing the need of a higher EGR quantity for phasing control.

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800°C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h-1) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.