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The addition of metal nanoparticles to standard coolant fluids dramatically increases the thermal conductivity of the liquid. The properties of the prepared nanofluids will allow for lighter, smaller, and higher efficiency spacecraft thermal control systems to be developed. Nanofluids with spherical or rod-shaped metal nanoparticles were investigated. At a volume concentration of 0.5%, the room temperature thermal conductivity of a 2 nm spherical gold nanoparticle-water solution was increased by more than 10% over water alone. Silver nanorods increased the thermal conductivity of ethylene glycol by 53% and water by 26%.

The sustainability of Martian outposts development is strongly based on the capability of achieving a high level of autonomy both in terms of operations management and of resources availability. In situ production of consumables is a key point to allow humans to work and live on Mars avoiding or limiting the need for re-supplies of materials from Earth. Required consumables can be produced in situ exploiting the locally available resources, but also by means of green-houses and waste recycle systems. Dedicated robotic missions for in situ demonstration of this type of technologies are a fundamental step of the Martian In Situ Resources Utilization (ISRU) development roadmap. This paper is focused on the extraction of oxygen and fuels (e.g. methane) from the Martian atmosphere, and presents a feasibility study for a small technological demonstration plant.

Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.

The operating pressure is one of the critical issues in designing a gasoline-fueled PEM fuel cell system for transportation applications. Pressurized (3atm) and atmospheric pressure (1atm) fuel cell systems are being considered by various developers for automotive applications. Systems analyses have been performed for the two systems using GCtool, a computer simulation code developed at Argonne National Laboratory. The two systems were designed for comparable overall system efficiencies at a rated design power of 50 kW. The characteristics and performance of the different components of the two systems were compared at the design power and at part-load operating conditions. Transient analyses were performed to investigate the dynamic response of the two systems during cold startup. The pros and cons of the two systems regarding their performance, size, and preliminary cost estimates are presented.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.