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A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC.

On-board diagnostics (OBD) of diesel vehicles require various sensors to detect system malfunctions. The Particulate Matter (PM) sensor is one of OBD devices which gather information which could be critical in determining a crack in the diesel particulate filters (DPFs). The PM sensor detects PM which penetrates cracked DPFs and converts the amount of PM into electrical values. The PM sensor control unit (SCU) receives those analog signals and converts them to digital values through hardware and software solutions. A capacitive sensing method would be a stable solution because it detects not raw analog signals but electrical charges or a time constant going through the capacitive load. Therefore, amount of PM would be converted reasonable value of capacitance even though there is a little amount of PM.

A study for improving the resistance to fretting corrosion of SCr 420 pinion gear was conducted. Fretting is the damage to contacting surfaces experiencing slight relative reciprocating sliding motion of low amplitude. Fretting corrosion is the fretting damage to unlubricated contacting surfaces accompanied by corrosion, mostly oxidation that occurs if the fretting occurs in air. Two kinds of conventional heat treatment and a newly designed one suggested for improving the resistance to the fretting corrosion of pinion gear were compared each other to find out what is the main factor for generating fretting corrosion phenomenon. Increased carbon potential at both the heating and diffusing zone and reduced time of tempering was found out to be a solution for improving the resistance to fretting corrosion of forged and heat treated gear steel. On the contrary, modified carbo-nitriding using ammonia gas has been getting worse the fretting corrosion problem.

A study of unsteady compressible flow for two types of exhaust manifold and CCC (Close-Coupled Catalyst) systems attached to a 4-cylinder DOHC gasoline engine was carried out to investigate the flow distribution of exhaust gases and finally to make the conversion efficiency of catalyst better. An experimental study was conducted, using LDV technique, to measure the velocity distributions inside exhaust manifolds and CCC under practical engine conditions. In this study, through experiment and calculation, the effects of geometric configuration of exhaust manifold on flow maldistribution in monolith were mainly investigated to understand the exhaust flow structure in terms of flow uniformity and to improve the conversion efficiency. As a result of this fundamental study, the modified exhaust manifold (Type B) was designed and manufactured. Full load performance tests and vehicle emission tests were performed to see the effects of flow characteristics on engine performance and emission.

In diesel engine development, the new technology is coming out to meet the stringent exhaust emission regulation. The regulation demands more eco-friendly vehicles. Euro6c demands to meet not only WLTP mode, but also RDE(Real Driving Emission). In order to satisfy RDE mode, the new technology to reduce emissions should cover all operating areas including High Load & High Speed. It is a big challenge to reduce NOx on the RDE mode and a lot of DeNOx technologies are being developed. So the new DeNOx technology is needed to cover widened operating area and strict acceleration / deacceleration. The existing LNT(Lean NOx Trap) and Urea SCR(Selective Catalytic Reduction) is necessary to meet the typical NEDC or WLTP, but the RDE mode demands the powerful DeNOx technology. Therefore, the LNT & Urea SCR on DPF was developed through this study.

Impact resistance of plastic underbody parts was studied using simulated injection-molded specimen which can be tested according to different types of material used, injection molding variants like position and number of injection molding gates, and features of ribs. Material applied was glass fiber reinforced polyamide which can be used in underbody parts. Test was performed using several combinations of injection molding gates and rib types. From the test result, optimal design guide for plastic underbody parts was determined. Also, new high impact resistant plastic material made of glass fiber reinforced polyamide 66 (PA66) and polyamide 6 (PA6) alloy was developed and the material properties useful for CAE were determined. As a case study, oil pan and muffler housing were designed following the optimal design guide and CAE. And the reliability of the sample muffler housing designed was verified.

A combined experimental and computational study of 3-D unsteady compressible flow in exhaust manifold and CCC system was performed to understand the flow characteristics and to improve the flow distribution of pulsating exhaust gases within monolith. An experimental study was carried out to measure the velocity distribution in production exhaust manifold and CCC under engine operating conditions using LDV (Laser Doppler Velocimetry) system. Velocity characteristics were measured at planes 25 mm away from the front surface of first monolith and between two monolithic bricks. To provide boundary conditions for the computational study, velocity fields according to crank angle were also measured at the entrance of exhaust manifold. The comparisons of exhaust gas flow patterns in the junction and mixing pipe between experimental and computational results were made.

In this work, the operating strategy for diesel injection methods and a way to control the exhaust gas recirculation (EGR) rate under dual-fuel PCCI combustion with an appropriate ratio of low-reactivity fuel (propane) to achieve high combustion stability and low emissions is introduced. The standards of combustion stability were carbon monoxide (CO) emissions below 5,000 ppm and a CoV of the indicated mean effective pressure (IMEP) below 5 %. Additionally, the NOx emissions was controlled to not exceed 50 ppm, which is the standard of conventional diesel combustion, and PM emissions was kept below 0.2 FSN, which is a tenth of the conventional diesel value without a diesel particulate filter (DPF). The operating condition was a low speed and load condition (1,500 rpm/ near gIMEP of 0.55 MPa).

For optimizing the performance of SI engine such as engine torque, fuel consumption, and emissions, various types of system for variable valve timing were developed by many automotive researchers. In this paper, we investigated the relationship between valve timing and intake orifice noise, and suggested how to improve NVH (Noise, Vibration and Harshness) performance as well as engine torque. Some experiments using the engine dynamometer were carried over about 150 different operating conditions. BEM analysis was also conducted in order to calculate acoustic modes of intake system. The results show that the valve timing and overlap of breathing systems have influence on NVH behavior, especially intake orifice noise over whole range of operating conditions. Valve timing and overlap of intake and exhaust valve were optimized in the view of sound quality as well as overall noise level.

We used a one-dimensional monolithic catalyst model to predict the transient thermal and conversion characteristics of a dual monolithic catalytic converter with a Palladium only (Pd-only) catalyst and a Palladium/Rhodium (Pd/Rh) catalyst. Prior to the numerical investigation of the dual-catalyst converter, we modified the pre-exponential factor and activation energy of each reaction for both catalysts to achieve acceptable agreement with experimental data under typical operating conditions of automobile applications. We validated the conversion behavior of the lumped parameter model for each catalyst against different engine operating conditions. Two higher cell density substrates, Pd-only catalyst (600cpsi/3.9mil) and Pd/Rh catalyst (600cpsi/4mil), for faster light-off and improved warm-up performance are used in this study and the two monoliths has been connected without the space between monoliths.

Environmental standards concerning Suspended Particulate Matter (SPM) are continuously becoming stricter. The light-duty diesel passenger car market is rapidly increasing due to performance improvements and the economic advantages of the diesel engine. To meet EURO 4 diesel passenger car emission regulations, regeneration experiments of a catalyzed particulate filter (CPF) system have been performed with 2.0L common-rail diesel engine. For effective regeneration of the CPF system, we investigated the effects of various regeneration conditions on the system. Conditions such as exhaust gas temperature, oxygen/hydrocarbon concentrations, gas compositions, etc. were investigated. We found that the regeneration efficiency was improved when the exhaust gas temperature increased to more than 700°C during CPF regeneration using engine post injection. An additional amount of post injection increased the exhaust gas temperature and residual hydrocarbon content.

The key technical aspects of a catalyzed particulate filter (CPF) system development are software calibration for regeneration and component optimization for system performance. It is important that the optimized component specification be selected an early stage since the components have an effect on the overall regeneration strategy. Accordingly, in a catalyzed particulate filter system the washcoat and precious metal loading are main components that should be optimized at an early stage of the system development. An accelerated aging protocol is needed in order to properly evaluate the performance of various catalyst systems in a timely manner.

In recent years, the emerging technology competitions in automotive industry are improving engine efficiency and electronizing for coping with stringent fuel-economy regulations. However, fuel-economy technologies such as engine down-sizing and numerous electronic parts entrust burden plastic materials acing as mainly electric insulation and housing to have to be higher performance, especially temperature endurance. Engineering plastics (EPs) have critical limitations in terms of degradation by heat. Heat-resisting additives in EP are generally used to be anti-degradation as activating non-radical decomposition of peroxide. However, it could not be effective way to impede the degradation in long term heat aging over 1,000 hours at high temperature above 180 °C. In this study, we suggested the new solution called ‘shield effect’ that is purposeful oxidation at the surface and local crystallization of EP to stop prevent penetrating oxygen to inside of that.

Thii paper describes Hyundai's research and development work on the dedicated compressed natural gas (CNG) engine, A conventional light duty gasoline engine, a 1.5 liter four cylinder DOHC, has been modified to run on natural gas (NG) by a gas injection system and engine dynamometer test has been performed with emphasis on optimizations of compression ratio and intake port. Also presented are the results on the exhaust emissions characteristic and the purification performance of three-way catalytic converters developed for NG engine. Fuel composition and THC emissions are analyzed quantitatively using gas chromatography devices.

The strict new emission regulations have resulted in the development of new techniques to meet the control of cold-start emission in various competitive ways. In this study, the dual walled air gap exhaust pipe system is developed as an effective countermeasure to reduce pollutant exhaust gas emission, particularly to reduce pollutant exhaust gas emission at cold start and idling stage, in which the catalytic converter has not reached to light-off temperature. In this study, it is shown that dual walled air gap exhaust system can shorten the time to reach to light off temperature of the catalytic converter in cold start state, and reduce the emission of Hydrocarbon (HC) significantly due to its low thermal capacity and high thermal insulation effect. In the study, a thermal analysis of the dual walled air gap exhaust pipe system has been done using the computational fluid dynamics method.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

A new heat-resistant cast iron alloy has been developed for the exhaust manifolds of new passenger-car diesel engines. This development occurred because operating demands on exhaust manifolds have increased significantly over the past decade. These demands are due to higher exhaust gas temperatures resulting from tighter emission requirements, improved fuel efficiencies, and designs for higher specific engine power. These factors have led to much higher elevated temperature strength and oxidation resistance requirements on exhaust manifold alloys. Additionally, thermal fatigue that occurs directly as a result of thermal expansions and mechanical constraint has become an increasingly important issue. The research detailed in this paper focused on the optimization of the chemical composition of a Si-Mo ductile iron to improve the mechanical and physical properties for use in an engine exhaust manifold.

Systematic numerical simulations were performed for the improvement of fuel efficiency and thermal performance of a compact size passenger vehicle. Both aerodynamic and thermal aspects were considered concurrently. For the sake of systematic evaluation, our study was conducted employing various design changes in multiple steps: 1) analysis of the baseline design; 2) elimination of the engine room components; 3) modification of the engine room component layout; 4) modification of the aerodynamic components (such as under body cover and cooling ducts). The vehicle performance characteristics corresponding to different design options were analyzed in terms of aerodynamic coefficient, engine coolant temperature, and surface temperatures of thermally critical components such as battery and exhaust manifold. Finally optimal design modification solutions for better vehicle performance were proposed.

Automotive companies are trying to enhance the customer’s impression by improving engine sound quality. The target of this sound quality is to create a brand sound that is preferred by their customers as well as quietness of interior noise. Over the past decade there have been many studies in the field of automotive sound quality. These have included the technologies such as tuning of intake orifice and exhaust orifice, tuning of structure-borne, intake feedback devices, active exhaust valves, ANC (Active Noise Cancellation) and ASD (Active Sound Design). The three elements of the sound that affect the feeling of the customer are known as engine order arrangement, frequency balance, and linearity. Here, the most important thing in sound quality development is the order arrangement.