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A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC.

A study for improving the resistance to fretting corrosion of SCr 420 pinion gear was conducted. Fretting is the damage to contacting surfaces experiencing slight relative reciprocating sliding motion of low amplitude. Fretting corrosion is the fretting damage to unlubricated contacting surfaces accompanied by corrosion, mostly oxidation that occurs if the fretting occurs in air. Two kinds of conventional heat treatment and a newly designed one suggested for improving the resistance to the fretting corrosion of pinion gear were compared each other to find out what is the main factor for generating fretting corrosion phenomenon. Increased carbon potential at both the heating and diffusing zone and reduced time of tempering was found out to be a solution for improving the resistance to fretting corrosion of forged and heat treated gear steel. On the contrary, modified carbo-nitriding using ammonia gas has been getting worse the fretting corrosion problem.

A study of unsteady compressible flow for two types of exhaust manifold and CCC (Close-Coupled Catalyst) systems attached to a 4-cylinder DOHC gasoline engine was carried out to investigate the flow distribution of exhaust gases and finally to make the conversion efficiency of catalyst better. An experimental study was conducted, using LDV technique, to measure the velocity distributions inside exhaust manifolds and CCC under practical engine conditions. In this study, through experiment and calculation, the effects of geometric configuration of exhaust manifold on flow maldistribution in monolith were mainly investigated to understand the exhaust flow structure in terms of flow uniformity and to improve the conversion efficiency. As a result of this fundamental study, the modified exhaust manifold (Type B) was designed and manufactured. Full load performance tests and vehicle emission tests were performed to see the effects of flow characteristics on engine performance and emission.

In diesel engine development, the new technology is coming out to meet the stringent exhaust emission regulation. The regulation demands more eco-friendly vehicles. Euro6c demands to meet not only WLTP mode, but also RDE(Real Driving Emission). In order to satisfy RDE mode, the new technology to reduce emissions should cover all operating areas including High Load & High Speed. It is a big challenge to reduce NOx on the RDE mode and a lot of DeNOx technologies are being developed. So the new DeNOx technology is needed to cover widened operating area and strict acceleration / deacceleration. The existing LNT(Lean NOx Trap) and Urea SCR(Selective Catalytic Reduction) is necessary to meet the typical NEDC or WLTP, but the RDE mode demands the powerful DeNOx technology. Therefore, the LNT & Urea SCR on DPF was developed through this study.

Recently, the environmental temperature of vehicles is changing due to the electrification of vehicles and improved internal combustion engine system to reduce carbon emissions. However, mechanical properties of plastic materials change very sensitively to environmental temperature changes, and mechanical properties decrease when exposed to high temperatures. Therefore, it is important to estimate lifespan estimation of plastic parts according to temperature changes. In this paper, reliability analysis process to estimate the maximum service temperature of plastic parts was developed using aging data of material properties, environmental condition data of automotive parts, and field driving condition data. Changes in the mechanical properties of plastic materials such as glass fiber reinforced polyamide materials were tested. The environmental exposure temperature of the vehicle and parts was measured, and the general driving pattern of the vehicle was analyzed.

Impact resistance of plastic underbody parts was studied using simulated injection-molded specimen which can be tested according to different types of material used, injection molding variants like position and number of injection molding gates, and features of ribs. Material applied was glass fiber reinforced polyamide which can be used in underbody parts. Test was performed using several combinations of injection molding gates and rib types. From the test result, optimal design guide for plastic underbody parts was determined. Also, new high impact resistant plastic material made of glass fiber reinforced polyamide 66 (PA66) and polyamide 6 (PA6) alloy was developed and the material properties useful for CAE were determined. As a case study, oil pan and muffler housing were designed following the optimal design guide and CAE. And the reliability of the sample muffler housing designed was verified.

The primary purpose of using a plastic material instead of conventional aluminum cast for intake manifold is to reduce its weight and cost. Moreover, the use of plastic for intake manifold is regarded as a key for further development of so called an “intake modular system”. As a secondary effect, the engine power can be increased with the help of improved interior surface roughness and lowered air temperature. With regard to NVH, however, plastic intake manifold is considered somewhat negative since it is less rigid and less dense than aluminum one. In this paper, the mechanism that plastic intake manifold affects the performance and NVH of in-line 4 cylinder gasoline engine is presented. In connection with engine performance, air flow efficiency of not only intake manifold itself but also other components of intake system and also cylinder head is evaluated.

A combined experimental and computational study of 3-D unsteady compressible flow in exhaust manifold and CCC system was performed to understand the flow characteristics and to improve the flow distribution of pulsating exhaust gases within monolith. An experimental study was carried out to measure the velocity distribution in production exhaust manifold and CCC under engine operating conditions using LDV (Laser Doppler Velocimetry) system. Velocity characteristics were measured at planes 25 mm away from the front surface of first monolith and between two monolithic bricks. To provide boundary conditions for the computational study, velocity fields according to crank angle were also measured at the entrance of exhaust manifold. The comparisons of exhaust gas flow patterns in the junction and mixing pipe between experimental and computational results were made.

For optimizing the performance of SI engine such as engine torque, fuel consumption, and emissions, various types of system for variable valve timing were developed by many automotive researchers. In this paper, we investigated the relationship between valve timing and intake orifice noise, and suggested how to improve NVH (Noise, Vibration and Harshness) performance as well as engine torque. Some experiments using the engine dynamometer were carried over about 150 different operating conditions. BEM analysis was also conducted in order to calculate acoustic modes of intake system. The results show that the valve timing and overlap of breathing systems have influence on NVH behavior, especially intake orifice noise over whole range of operating conditions. Valve timing and overlap of intake and exhaust valve were optimized in the view of sound quality as well as overall noise level.

Environmental standards concerning Suspended Particulate Matter (SPM) are continuously becoming stricter. The light-duty diesel passenger car market is rapidly increasing due to performance improvements and the economic advantages of the diesel engine. To meet EURO 4 diesel passenger car emission regulations, regeneration experiments of a catalyzed particulate filter (CPF) system have been performed with 2.0L common-rail diesel engine. For effective regeneration of the CPF system, we investigated the effects of various regeneration conditions on the system. Conditions such as exhaust gas temperature, oxygen/hydrocarbon concentrations, gas compositions, etc. were investigated. We found that the regeneration efficiency was improved when the exhaust gas temperature increased to more than 700°C during CPF regeneration using engine post injection. An additional amount of post injection increased the exhaust gas temperature and residual hydrocarbon content.

The key technical aspects of a catalyzed particulate filter (CPF) system development are software calibration for regeneration and component optimization for system performance. It is important that the optimized component specification be selected an early stage since the components have an effect on the overall regeneration strategy. Accordingly, in a catalyzed particulate filter system the washcoat and precious metal loading are main components that should be optimized at an early stage of the system development. An accelerated aging protocol is needed in order to properly evaluate the performance of various catalyst systems in a timely manner.

The thermoplastic automotive pulley has been developed and will be commercialized to high volume production that achieves cost saving and weight reduction over other automotive pulleys in the metal and thermosetting resin by Hyundai Motor Company. Design feature incorporated in this automotive pulley allow it to be manufactured and assembled onto the water pump more efficiently in consequence of design integration with the water pump and power steering pulley. However, the harsh environment and dynamic loads that the thermoplastic pulley has to withstand required extensive CAE analysis and testing of the molded parts and the standard glass reinforced PA was selected for the application to maximize cost savings. The key aspects of the plastic automotive pulley as well as its advantage are presented.

In recent years, the emerging technology competitions in automotive industry are improving engine efficiency and electronizing for coping with stringent fuel-economy regulations. However, fuel-economy technologies such as engine down-sizing and numerous electronic parts entrust burden plastic materials acing as mainly electric insulation and housing to have to be higher performance, especially temperature endurance. Engineering plastics (EPs) have critical limitations in terms of degradation by heat. Heat-resisting additives in EP are generally used to be anti-degradation as activating non-radical decomposition of peroxide. However, it could not be effective way to impede the degradation in long term heat aging over 1,000 hours at high temperature above 180 °C. In this study, we suggested the new solution called ‘shield effect’ that is purposeful oxidation at the surface and local crystallization of EP to stop prevent penetrating oxygen to inside of that.

Thii paper describes Hyundai's research and development work on the dedicated compressed natural gas (CNG) engine, A conventional light duty gasoline engine, a 1.5 liter four cylinder DOHC, has been modified to run on natural gas (NG) by a gas injection system and engine dynamometer test has been performed with emphasis on optimizations of compression ratio and intake port. Also presented are the results on the exhaust emissions characteristic and the purification performance of three-way catalytic converters developed for NG engine. Fuel composition and THC emissions are analyzed quantitatively using gas chromatography devices.

This study provides a tire puncture sealant including NR latex and acrylic emersion, which has a reduced viscosity at -40°C, and is also excellent storage stability at -40°C to 70°C, initial sealing performance. Also, this study provides device for sealing inflatable objects. 'One- Piece Tire Repair Kit' can reduce weight and operation steps.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

A battery pack case of an electric vehicle was developed with a fibrous thermoplastic composite material. Due to cost effectiveness, long-fiber-reinforced thermoplastics by direct process (D-LFT) were adopted. PA6 (Polyamide 6)-based composites were processed using a D-LFT pilot machine at the temperature range between 250° and 290°. Glass and carbon fibers were added in the matrix varying the mixture ratio of the fibers while keeping the weight fraction 40%. The increase of carbon fibers in the mixture increased tensile modulus and strength, however, decreased Izod impacts strength. The fatigue life of developed composites was evaluated by fatigue tests in tension, which were over one million cycles at the maximum fatigue loading less than 60% of the composite strength. Associated with fiber orientation, anisotropic mechanical behavior was investigated in terms of flexural properties and mold shrinkage.

Recently, the design of automotive headlamps has become diversified and complicated according to customer needs. Hence, structural complexity of the headlamps has also increased. Complex structure of the headlamps inevitably causes a disturbance in air circulation. For this reason, inadvertent micro-sized water droplets, called fogging, are condensed on the inner surface of headlamp lens due to temperature difference between the inner and outer lens surfaces. To circumvent fogging inside of the headlamp lens, an anti-fogging coating is indispensable. Conventionally, diverse surfactants have been adopted as substantial material for the anti-fogging coating. However, the usage of the surfactants causes undesirable side effect such as water mark arising from vapor condensation, which is an important issue that must be fully resolved. In this study, we developed an innovative anti-fogging coating material without using conventional surfactant.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

A new heat-resistant cast iron alloy has been developed for the exhaust manifolds of new passenger-car diesel engines. This development occurred because operating demands on exhaust manifolds have increased significantly over the past decade. These demands are due to higher exhaust gas temperatures resulting from tighter emission requirements, improved fuel efficiencies, and designs for higher specific engine power. These factors have led to much higher elevated temperature strength and oxidation resistance requirements on exhaust manifold alloys. Additionally, thermal fatigue that occurs directly as a result of thermal expansions and mechanical constraint has become an increasingly important issue. The research detailed in this paper focused on the optimization of the chemical composition of a Si-Mo ductile iron to improve the mechanical and physical properties for use in an engine exhaust manifold.