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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

The benefits of energy and operational cost savings from using copper rotors are well recognized. The main barrier to die casting copper rotors is short mold life. This paper introduces a new approach for manufacturing copper-bar rotors. Either copper, aluminum, or their alloys can be used for the end rings. Both solid-core and laminated-core rotors were built. High quality joints of aluminum to copper were produced and evaluated. This technology can also be used for manufacturing aluminum bar rotors with aluminum end rings. Further investigation is needed to study the lifetime reliability of the joint. The improvement of manufacturing fixture through prototype test is also required.

This work presents a simple fan model that is based on the actuator disk approximation, and the blade element and vortex theory of a propeller. A set of equations are derived that require as input the rotational speed of the fan, geometric fan data, and the lift and drag coefficients of the blades. These equations are solved iteratively to obtain the body forces generated by the fan in the axial and circumferential directions. These forces are used as momentum sources in a CFD code to simulate the effect of the fan in an underhood thermal management simulation. To validate this fan model, a fan experiment was simulated. The model was incorporated into the CFD code STAR-CD and predictions were generated for axial and circumferential air velocities at different radial positions and at different planes downstream of the fan. The agreement between experimental measurements and predictions is good.

The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.

The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

A computational fluid dynamics (CFD) guided combustion system optimization was conducted for a heavy-duty compression-ignition engine with a gasoline-like fuel that has an anti-knock index (AKI) of 58. The primary goal was to design an optimized combustion system utilizing the high volatility and low sooting tendency of the fuel for improved fuel efficiency with minimal hardware modifications to the engine. The CFD model predictions were first validated against experimental results generated using the stock engine hardware. A comprehensive design of experiments (DoE) study was performed at different operating conditions on a world-leading supercomputer, MIRA at Argonne National Laboratory, to accelerate the development of an optimized fuel-efficiency focused design while maintaining the engine-out NOx and soot emissions levels of the baseline production engine.

The development of new catalytic materials is still dominated by trial and error methods, even though the experimental and theoretical bases for their characterization have improved dramatically in recent years. Although it has been successful, the empirical development of catalytic materials is time consuming and expensive with no guarantee of success. We have been exploring computationally complex but experimentally simple systems to establish a “catalysis by design” protocol that combines the power of theory and experiment. We hope to translate the fundamental insights directly into a complete catalyst system that is technologically relevant. The essential component of this approach is that the catalysts are iteratively examined by both theoretical and experimental methods.

One challenge in meeting emission regulations with catalytic aftertreatment systems is maintaining the proper catalyst temperatures that enable the catalytic devices to perform the emissions reduction. In this study, in-cylinder techniques are used to actively control the temperature of a catalyzed diesel particulate filter (DPF) in order to raise the DPF temperature to induce particulate oxidation. The performance of four strategies is compared for two different starting DPF temperatures (150°C and 300°C) on a 4-cylinder 1.7-liter diesel engine. The four strategies include: (1) addition of extra fuel injection early in the combustion cycle for all four cylinders, (2) addition of extra fuel injection late in the combustion cycle for all four cylinders, (3) operating one-cylinder with extra fuel injection early in the combustion cycle, and (4) operating one-cylinder with extra fuel injection late in the combustion cycle.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

In September 1993, the Partnership for a New Generation of Vehicles (PNGV) program, initiated a cooperative research and development (R&D) program between the federal government and the United States Council Automotive Research (USCAR) to develop automotive technologies to reduce the nation's dependence on petroleum and reduce emissions of greenhouse gases by improving fuel economy. A key enabler for the attainment of these goals is a significant reduction in vehicle weight. Thus the major focus of the PNGV materials program is the development of materials and technologies that would result in the reduction of vehicle weight by up to 40%. The Automotive Lightweighting Materials (ALM) Program in the Office of Advanced Automotive Technologies (OAAT) of the Department of Energy (DOE), the PNGV Materials Technical Team and the United States Automotive Materials Partnership (USAMP) collaborate to conduct research and development on these materials.

With the increasing demand for Battery Electric Vehicles (BEVs) capable of extended mileage, optimizing their efficiency has become paramount for manufacturers. However, the challenge lies in balancing the need for climate control within the cabin and precise thermal regulation of the battery, which can significantly reduce a vehicle's driving range, often leading to energy consumption exceeding 50% under severe weather conditions. To address these critical concerns, this study embarks on a comprehensive exploration of the impact of weather conditions on energy consumption and range for the 2019 Nissan Leaf Plus. The primary objective of this research is to enhance the understanding of thermal management for BEVs by introducing a sophisticated thermal management system model, along with detailed thermal models for both the battery and the cabin.

Development of reliable magnesium (Mg) to steel joining methods is one of the critical issues in boarder applications of Mg in automotive body construction. However, due to the large difference of melting temperatures of Mg and steel, fusion welding between two metals is very challenging. Ultrasonic spot welding (USW) has been demonstrated to join Mg to steel without melting and to achieve strong joints. However, galvanic corrosion between Mg and steel is inevitable but not well quantified. In this study, corrosion test of ultrasonic spot welds between 1.6-mm-thick Mg AZ31B-H24 and 0.8-mm-thick galvanized mild steel was conducted. No specific corrosion protection was applied in order to study the worst corrosion behavior. Corrosion test was conducted with an automotive cyclic corrosion test, which includes cyclic exposures of dipping in the salt bath, air drying, then a constant humidity environment. Lap shear strength of the joints decreased linearly with the cycles.

Development of reliable magnesium (Mg) to steel joining methods is one of the critical issues in broader applications of Mg in automotive body construction. Ultrasonic spot welding (USW) has been demonstrated successfully to join Mg to steel and to achieve strong joints. In this study, corrosion test of ultrasonic spot welds between 1.6 mm thick Mg AZ31B-H24 and 0.8 mm thick galvanized mild steel, without and with adhesive, was conducted. Adhesive used was a one-component, heat-cured epoxy material, and was applied between overlapped sheets before USW. Corrosion test was conducted with an automotive cyclic corrosion test, which includes cyclic exposures of dipping in the 0.5% sodium chloride (NaCl) bath, a constant humidity environment, and a drying period. Lap shear strength of the joints decreased with the cycles of corrosion exposure. Good joint strengths were retained at the end of 30-cycle test.

The CFR engine is the widely accepted platform to test standard Research Octane Number (RON) and Motored Octane Number (MON) for determining anti-knock characteristics of motor fuels. With increasing interest in engine downsizing, up-torquing, and alternative fuels for modern spark ignition (SI) engines, there is a need to better understand the conditions that fuels are subjected to in the CFR engine during octane rating. To take into account fuel properties, such as fuel heat of vaporization, laminar flame speed and auto-ignition chemistry; and understand their impacts on combustion knock, it is essential to estimate accurate cylinder conditions. In this study, the CFR F1/F2 engine was modeled using GT-Power with the Three Pressure Analysis (TPA) and the model was validated for different fuels and engine conditions.