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When the California Air Resources Board (ARB) adopted automotive exhaust emission standards for Super Ultra-Low-Emission Vehicles (SULEV), new challenges were encountered for accurately measuring exhaust emissions. This is especially true for measuring NMOG emissions (NMHC and carbonyls) where the SULEV standard is 0.010 g/mi. One of the challenges in accurately measuring NMHC emissions is to find a clean sample bag material that has no or very low outgassing of hydrocarbons. Tedlar, the bag material commonly used for exhaust emission sampling, has been found to emit N,N- dimethylacetamide (DMAc), which interferes with hydrocarbon measurements and can contribute to significant error in SULEV hydrocarbon emission measurements. Several fluorocarbon materials were tested for hydrocarbon (HC) outgassing and carbon dioxide (CO2) permeation. The materials include Tedlar, Baked Tedlar, KynarFlex 2750, Baked KynarFlex 2800, Teflon FEP, TFM TFE, Tefzel, and Halar.

As automotive exhaust emission standards have become more stringent and emission control technologies have advanced over the years, accurately measuring the resulting near zero emissions has become increasingly difficult. To improve measurement accuracy, enhancements have been made to the conventional Constant Volume Sampling system (CVS) and to the analytical instrumentation This study included the evaluation of a CVS enhancement. Specifically, a prototype air filter was utilized to enhance the performance of a CVS by reducing non-methane hydrocarbons (NMHC) from dilution air at ambient temperature. Also incorporated into this study was the assessment of a Bag Mini-Dilute (BMD), a relatively new sampling system developed for measuring low-level vehicle emissions. The BMD can be used as an alternative to the CVS and has been approved for emission measurement by the United States Environmental Protection Agency (US EPA) and the California Air Resources Board (ARB.)