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In July 1997, the Pacific Northwest and Alaska Regional Bioenergy Program, in cooperation with several industrial and institutional partners initiated a long-haul 322,000 km (200,000 mile) operational demonstration using a biodiesel and diesel fuel blend in a 324 kW (435 HP), Caterpillar 3406E Engine, and a Kenworth Class 8 heavy duty truck. This project was designed to: develop definitive biodiesel performance information, collect emissions data for both regulated and non-regulated compounds including mutagenic activity, and collect heavy-duty operational engine performance and durability information. To assess long-term engine durability and wear; including injector, valve and port deposit formations; the engine was dismantled for inspection and evaluation at the conclusion of the demonstration. The fuel used was a 50% blend of biodiesel produced from used cooking oil (hydrogenated soy ethyl ester) and 50% 2-D petroleum diesel.

There is an ongoing interest in biodegradable hydraulic fluids. Biodegradable fluids are often considered to include only vegetable oils, polyol esters and diester base stocks. However, other fluid base stocks including highly refined mineral oils, poly(alpha olefins) and fire-resistant fluids such as water-glycol hydraulic fluids are also biodegradable fluid alternatives. This paper will provide an overview of the international literature on biodegradable fluids, various international testing protocol, fluid base stocks, effect of oxidative stability, material compatibility and pump performance.

This paper discusses the compression ratio influence on maximum load of a Natural Gas HCCI engine. A modified Volvo TD100 truck engine is controlled in a closed-loop fashion by enriching the Natural Gas mixture with Hydrogen. The first section of the paper illustrates and discusses the potential of using hydrogen enrichment of natural gas to control combustion timing. Cylinder pressure is used as the feedback and the 50 percent burn angle is the controlled parameter. Full-cycle simulation is compared to some of the experimental data and then used to enhance some of the experimental observations dealing with ignition timing, thermal boundary conditions, emissions and how they affect engine stability and performance. High load issues common to HCCI are discussed in light of the inherent performance and emissions tradeoff and the disappearance of feasible operating space at high engine loads.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

This paper features an application study on the impact of different blend levels of commercially-supplied biodiesel on engine and aftertreatment systems' durability and reliability as well as the impact on owning and operating factors: service intervals and fuel economy. The study was conducted on a bus application with a 2007 on highway emissions equipped engine running biodiesel blends of B5, B20, and B99 for a total period approaching 4500 hours. Biodiesel of waste cooking grease feedstock was used for the majority of the testing, including B5 and B20 blends. Biodiesel of soybean feedstock was used for testing on B99 blend. No negative impacts on engine and aftertreatment performance and durability or indication of future potential issues were found when using B5 and B20. For B99 measurable impacts on engine and aftertreatment performance and owning and operating cost were observed.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

The road freight transport sector is one of the main responsible for the air pollution (as the case of particulate matter) and greenhouse gases emissions worldwide. Different types of fuel technologies have been developed in order to improve efficiency, reduce air pollution impacts, such as the case of liquefied natural gas (LNG) for heavy-duty vehicles. Many studies show the relationship between the effects of short and long-term exposure to particulate matter (PM) and, according to the World Health Organization (WHO), premature deaths worldwide as well as cardiorespiratory diseases in elderly population are related to this pollutant. In this context, this paper aims at evaluating the atmospheric dispersion of PM in a stretch of a highway (Anhanguera-Bandeirantes) in the São Paulo State in Brazil due to the road freight transport considering the use of diesel and LNG in heavy-duty vehicles and the impacts on human health. The software AERMOD designed by U.S.

The bio-fuel, 2,5 - dimethylfuran (DMF) is currently regarded as a potential alternative fuel to gasoline due to the development of new production technology. However, little is known about the flame behavior in an optical engine. In this paper, high speed imaging (with intensifier) was used during the combustion of DMF and its blends with gasoline and ethanol (D50, D85, E50D50 and E85D15) in an SI optical engine. The flame images from the combustion of each fuel were analyzed at two engine loads: 3bar and 4bar IMEP. For DMF, D50 and E50D50, two modes were compared: DI and PFI. The average flame shapes (in 2D) and the average flame speeds were calculated and combined with mass fraction burned (MFB) data. The results show that when using DMF, the rate of flame growth development and flame speed is higher than when using gasoline. The differences in flame speed between DMF and gasoline is about 10% to 14% at low IMEP.

Little research has been done on spray characteristics of 2,5-dimethylfuran (DMF), since the breakthrough in its production method as an alternative fuel candidate. In this paper, the spray characteristics of pure fuels (DMF, Isooctane) and DMF-Isooctane blends under different ambient pressures (1 bar, 3 bar and 7 bar) and injection pressures (50 bar, 100 bar and 150 bar) were studied using Phase Doppler Particle Analyzer (PDPA) and high speed imaging. Droplet velocity, size distribution, spray angle and penetration of sprays were examined. Based on the results, DMF had larger SMD and penetration length than isooctane. The surface tension of fuel strongly influenced spray characteristics. Increasing the surface tension by 26 % resulted in 12 % increase in SMD. Higher ambient pressure increased the drag force, but SMD was not influenced by the increased drag force. However, the increased ambient pressure reduced the injection velocity and We number resulting in higher SMD.

2, 5-Dimethylfuran (DMF) has been receiving increasing interest as a potential alternative fuel to fossil fuels, owing to the recent development of new production technology. However, the influence of DMF properties on the in-cylinder fuel spray and its evaporation, subsequent combustion processes as well as emission formation in current gasoline direct injection (GDI) engines is still not well understood, due to the lack of comprehensive understanding of its physical and chemical characteristics. To better understand the spray characteristics of DMF and its application to the IC engine, the fuel sprays of DMF and gasoline were investigated by experimental and computational methods. The shadowgraph and Phase Doppler Particle Analyzer (PDPA) techniques were used for measuring spray penetration, droplet velocity and size distribution of both fuels.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Homogeneous Charge Compression Ignition (HCCI) has been proposed for natural gas engines in heavy duty stationary power generation applications. A number of researchers have demonstrated, through simulation and experiment, the feasibility of obtaining high gross indicated thermal efficiencies and very low NOx emissions at reasonable load levels. With a goal of eventual commercialization of these engines, this paper sets forth some of the primary challenges in obtaining high brake thermal efficiency from production feasible engines. Experimental results, in conjunction with simulation and analysis, are used to compare HCCI operation with traditional lean burn spark ignition performance. Current HCCI technology is characterized by low power density, very dilute mixtures, and low combustion efficiency. The quantitative adverse effect of each of these traits is demonstrated with respect to the brake thermal efficiency that can be expected in real world applications.

A model for the evaporation of a multi-component fuel droplet is presented that takes account of temperature dependent fuel and vapour properties, evolving droplet internal temperature distribution and composition, and enhancement to heat and mass transfer due to droplet motion. The effect on the internal droplet mixing of non-ideal fluid diffusion is accounted for. Activity coefficients for vapour-liquid equilibrium and diffusion coefficients are determined using the UNIFAC method. Both well-mixed droplet evaporation (assuming infinite liquid mass diffusivity) and liquid diffusion-controlled droplet evaporation (iteratively solving the multi-component diffusion equation) have been considered. Well-mixed droplet evaporation may be applicable with slow evaporation, for example early gasoline direct injection; diffusion-controlled droplet evaporation must be considered when faster evaporation is encountered, for example when injection is later, or when the fuel mixture is non-ideal.

Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.