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Natural gas, biogas, and biomethane are attractive fuels for compressed natural gas (CNG) engines because of their beneficial physical and chemical characteristics. This paper examines three combustion modes - homogeneous stoichiometric, homogeneous lean burn, and stratified combustion - in an optical single cylinder engine with a gas direct injection system operating with an injection pressure of 18 bar. The combustion process in each mode was characterized by indicated parameters, recording combustion images, and analysing combustion chemiluminescence emission spectra. Pure methane, which is the main component of CNG (up to 98%) or biomethane (> 98 %), was used as the fuel. Chemiluminescence emission spectrum analysis showed that OH* and CN* peaks appeared at their characteristic wavelengths in all three combustion modes. The peak of OH* and broadband CO2* intensities were strongly dependent on the air/fuel ratio conditions in the cylinder.

Future demands for improvements in the fuel economy of gasoline passenger car engines will require the development and implementation of advanced combustion strategies, to replace, or combine with the conventional spark ignition strategy. One possible strategy is homogeneous charge compression ignition (HCCI) achieved using negative valve overlap (NVO). However, several issues need to be addressed before this combustion strategy can be fully implemented in a production vehicle, one being to increase the upper load limit. One constraint at high loads is the combustion becoming too rapid, leading to excessive pressure-rise rates and large pressure fluctuations (ringing), causing noise. In this work, efforts were made to reduce these pressure fluctuations by using a late injection during the later part of the compression. A more appropriate acronym than HCCI for such combustion is SCCI (Stratified Charge Compression Ignition).