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Design of internal combustion (IC) engine pistons is dependent on accurate prediction of the temperature field in the component. Experimental temperature measurements can be taken but are costly and typically limited to a few select locations. High-fidelity computer simulations can be used to predict the temperature at any number of locations within the model, but the models must be calibrated for the predictions to be accurate. The largest barrier to calibration of piston thermal models is estimating the backside boundary conditions, as there is not much literature available for these boundary conditions. Bayesian model calibration is a common choice for model calibration in literature, but little research is available applying this method to piston thermal models. Neural networks have been shown in literature to be effective for calibration of piston thermal models.