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Due to their excellent fuel efficiency, reliability, and durability, compression ignition direct injection (CIDI) engines have been used extensively to power almost all highway trucks, urban buses, off-road vehicles, marine carriers, and industrial equipment. CIDI engines burn 35 to 50% less fuel than gasoline engines of comparable size, and they emit far less greenhouse gases (Carbon Dioxides), which have been implicated in global warming. Although the emissions of CIDI engines have been reduced significantly over the last decade, there remains concern with the Nitrogen Oxides (NOX) and Particulate Matter (PM) emission levels. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15ppm) diesel fuel.

Testing to investigate biodiesel's impact on the performance of a zeolite-based selective catalytic reduction (SCR) system was conducted. The tests employed a 2004 compliant Cummins ISB with common rail fuel injection, EGR, and variable geometry turbo. This 5.9L, 300HP engine was retrofitted with a Johnson-Matthey DPF + SCR (SCRT™) system. Testing was conducted over eight steady-state engine operating modes which provided a wide range of exhaust temperature and exhaust chemistry conditions. Fuels tested were a 2007 certification quality ultra-low sulfur diesel (ULSD), as well as a soy derived biodiesel in a B20 blend. B20 produced slightly lower catalyst temperatures and higher NO2:NOx ratios relative to ULSD, but no measureable difference in the overall NOx conversion over the SCR system. The dominant variable influencing SCR performance is the catalyst space velocity, which is unchanged with the use of B20.

Selective catalytic reduction (SCR) of NOx is coming into worldwide use for automotive diesel emissions control. To meet the most stringent standards, NOx conversion efficiency must exceed 80% while NH3 emissions or slip must be kept below 10-30 ppm. At such high levels of performance, non-uniformities in ammonia-to-NOx ratio (ANR) at the converter inlet can limit the achievable NOx reduction. Despite its significance, this effect is frequently ignored in 1D catalyst models. The corresponding model error is important to system integration engineers because it affects system sizing, and to control engineers because it affects both steady-state and dynamic SCR converter performance. A probability distribution function (PDF) based method is introduced to include mixture non-uniformity in a 1D, real-time catalyst model.

Despite the fact that urea-based selective catalytic reduction (SCR) of NOx is a key technology for achieving on- and off-highway diesel emission standards, significant control challenges remain. Transient operation, combined with dramatic changes in catalyst dynamics over the operating range, cause highly nonlinear system behavior. Moreover, these effects depend on catalyst formulation and new catalysts continue to be developed. With many controllers, any difference in catalyst formulation, converter size, and engine emissions calibration require control system re-tuning. To minimize control development effort, this paper presents a novel “generic” controller for SCR systems. Control action is grounded in a physics-based, nonlinear, embedded model. Through the model, controller parameters are adjusted a priori for catalyst formulation and converter size. The few remaining tuning levers are quite intuitive, and require no special knowledge of controls theory.

A dynamic system model for simulating the transient performance of a NOx aftertreatment system using Selective Catalytic Reduction with urea as a reductant (urea-SCR) was developed, calibrated for a heavy-duty engine application, and used to develop a closed loop self-tuning control strategy. The closed loop controller was able to reduce the FTP cycle NOx emissions from a Cummins heavy-duty engine by 84% while maintaining the mean ammonia slip below 7 ppm and the peak ammonia slip below 55 ppm. The peak ammonia slip occurred during the LA Freeway phase of the FTP cycle. Components of the urea-SCR aftertreatment system model include a urea dosing system, an exhaust pipe and a fresh vanadia-based SCR catalyst. The urea dosing system model incorporates the evaporation, thermolysis and hydrolysis stages in the conversion of urea to ammonia in the exhaust pipe and on the catalyst.

As the world market develops for biodiesel fuels, it is likely that a wider variety of biodiesels will become available, both locally and globally, and require engines to operate on a wider variety of fuels than experienced today. At the same time, tighter emissions regulations and a drive for improved fuel economy have focused interest on advanced combustion modes such as HCCI or PCCI, which are known to be more sensitive to fuel properties. This research covers two series of biodiesel fuels. In the first, B20 blends of natural methyl esters derived from palm, coconut, rape, soy, and mustard were evaluated at light load in an HCCI research engine to determine combustion and performance characteristics. These fuels showed performance differences between the biodiesels and the base #2 ULSD fuel, but did not allow separation of chemical effects due to the small number of fuels and correlation of various properties.