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Previously we reported (SAE Paper 2005-01-0475) that emissions of toxicologically relevant compounds from an engine operating at low NOx conditions using Fischer-Tropsch fuel (FT100) were lower than those emissions from the engine using an ultra-low sulfur (15 PPM sulfur) diesel fuel (BP15). Those tests were performed at two operating modes: Mode 6 (4.2 bar BMEP, 2300 RPM) and Mode 11 (2.62 bar BMEP, 1500 RPM). We wanted to evaluate the effect on emissions of operating the engine at low power (near idle) in conjunction with the low NOx strategy. Specifically, we report on emissions of total hydrocarbon (HC), carbon monoxide (CO), NOx, particulates (PM), formaldehyde, acetaldehyde, benzene, 1,3-butadiene, gas phase polyaromatic hydrocarbons (PAH's) and particle phase PAH's from a DaimlerChrysler OM611 CIDI engine using a low NOx engine operating strategy at Mode 22 (1.0 bar BMEP and 1500 RPM).

The overall program objectives were three fold: assess the benefits and limitations of oxygenated diesel fuels on engine performance and emissions identify oxygenates most suitable for potential use in future diesel formulations based on physico-chemical properties (e.g. flash point), toxicity, biodegradability and estimated cost of production perform limited emissions and performance testing of the oxygenated diesel blends select at least two oxygenated compounds for advanced engine testing In Part 1 of this program which is described in this paper, an extensive literature review was conducted to identify potential oxygenates for blending into diesel fuels. As many as 71 oxygenates were identified for the initial screening process. Based on a set of physical and chemical properties, a screening methodology was developed to select the 8 oxygenates that will be eligible for engine testing.