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Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

A CAE Based Stochastic Assessment and Improvement of Vehicle NCAP Response

2004-03-08
2004-01-0458
One of the primary issues in the interpretation of vehicle impact response data, observed from vehicle crash test events, is coping with variability. This vehicle response inconsistency generally causes test results to be unpredictable and makes CAE test validation work difficult as well. This paper, considering the uncertain characteristics of vehicle impact events, has implemented a stochastic assessment of vehicle NCAP response variation through a CAE vehicle impact model, and it has accomplished the three primary study objectives as stated follows: 1) Identify the response variation causing factors stochastically from various structural and environmental factor candidates and quantify the degree of their influences on crash response, 2) Develop a methodology for interpreting the significance of the factor effects in conjunction with vehicle impact mechanics and physics, and 3) Implement a stochastic improvement of the vehicle NCAP responses and their repeatability
Technical Paper

A Method for Improving the Accuracy of Standard Stereo Photogrammetry When Using Small Subtended Angles

2005-04-11
2005-01-0751
In stereo photogrammetry, the accuracy of calculating the location of a point in space, decreases as the angle between the two cameras decreases. For vehicle crash testing, the need for accurate 3D data conflicts with the need for flexible positioning of the cameras, to enable unobstructed views of the targets inside the vehicle throughout the impact event. This paper discusses a method for increasing the quantity and quality of film analysis data when small subtended angles are used. The method uses the 3D information developed through triangulation of two cameras as input to a single camera analysis.
Technical Paper

A Modeling Study of SCR Reaction Kinetics from Reactor Experiments

2013-04-08
2013-01-1576
In order to further characterize and optimize the performance of Selective Catalytic Reduction (SCR) aftertreatment systems used on heavy-duty diesel engines, an accurately calibrated high-fidelity multi-step global kinetic SCR model and a reduced order estimator for on-board diagnostic (OBD) and control are desirable. In this study, a Cu-zeolite SCR catalyst from a 2010 Cummins ISB engine was experimentally studied in a flow reactor using carefully designed protocols. A 2-site SCR model describing mass transfer and the SCR chemical reaction mechanisms is described in the paper. The model was calibrated to the reactor test data sets collected under temperatures from 200 to 425 °C and SCR space velocities of 60000, 90000, and 120000 hr-1. The model parameters were calibrated using an optimization code to minimize the error between measured and simulated NO, NO₂, N₂O, and NH₃ gas concentration time histories.
Technical Paper

A New Method for Obtaining FRF of a Structure in Area Where Impact Hammer Cannot Reach

2007-05-15
2007-01-2385
The Frequency Response Function (FRF) is a fundamental component to identifying the dynamic characteristics of a system. FRF's have a significant impact on modal analysis and root cause analysis of NVH issues. In most cases the FRF can be easily measured, but there are instances when the measurement is unobtainable due to spatial constraints. This paper outlines a simple experimental method for obtaining a high quality input-output FRF of a structure in areas where an impact hammer can not reach during impact testing. Traditionally, the FRF in such an area is obtained by using a load cell extender with a hammer impact excitation. A common problem with this device is a double hit, that yields unacceptable results.
Technical Paper

Air Bag Loading on In-Position Hybrid III Dummy Neck

2001-03-05
2001-01-0179
The Hybrid III family of dummies is used to estimate the response of an occupant during a crash. One recent area of interest is the response of the neck during air bag loading. The biomechanical response of the Hybrid III dummy's neck was based on inertial loading during crash events, when the dummy is restrained by a seat belt and/or seat back. Contact loading resulting from an air bag was not considered when the Hybrid III dummy was designed. This paper considers the effect of air bag loading on the 5th percentile female Hybrid III dummies. The response of the neck is presented in comparison to currently accepted biomechanical corridors. The Hybrid III dummy neck was designed with primary emphasis on appropriate flexion and extension responses using the corridors proposed by Mertz and Patrick. They formulated the mechanical performance requirements of the neck as the relationship between the moment at the occipital condyles and the rotation of the head relative to the torso.
Journal Article

Ammonia Generation and Utilization in a Passive SCR (TWC+SCR) System on Lean Gasoline Engine

2016-04-05
2016-01-0934
Lean gasoline engines offer greater fuel economy than the common stoichiometric gasoline engine, but the current three way catalyst (TWC) on stoichiometric engines is unable to control nitrogen oxide (NOX) emissions in oxidizing exhaust. For these lean gasoline engines, lean NOX emission control is required to meet existing Tier 2 and upcoming Tier 3 emission regulations set by the U.S. Environmental Protection Agency (EPA). While urea-based selective catalytic reduction (SCR) has proven effective in controlling NOX from diesel engines, the urea storage and delivery components can add significant size and cost. As such, onboard NH3 production via a passive SCR approach is of interest. In a passive SCR system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean operation, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst.
Journal Article

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines

2014-04-01
2014-01-1505
A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant.
Technical Paper

Ammonia Production and Utilization in a Hybrid LNT+SCR System

2009-11-02
2009-01-2739
A hybrid LNT+SCR system is used to control NOx from a light-duty diesel engine with in-cylinder regeneration controls. A diesel oxidation catalyst and diesel particulate filter are upstream of the LNT and SCR catalysts. Ultraviolet (UV) adsorption spectroscopy performed directly in the exhaust path downstream of the LNT and SCR catalysts is used to characterize NH3 production and utilization in the system. Extractive exhaust samples are analyzed with FTIR and magnetic sector mass spectrometry (H2) as well. Furthermore, standard gas analyzers are used to complete the characterization of exhaust chemistry. NH3 formation increases strongly with extended regeneration (or “over regeneration”) of the LNT, but the portion of NOx reduction occurring over the SCR catalyst is limited by the amount of NH3 produced as well as the amount of NOx available downstream of the LNT. Control of lean-rich cycling parameters enables control of the ratio of NOx reduction between the LNT and SCR catalysts.
Technical Paper

An Efficient Procedure for Vehicle Thermal Protection Development

2005-04-11
2005-01-1904
Vehicle thermal protection is an important aspect of the overall vehicle development process. It involves optimizing the exhaust system routing and designing heat shields to protect various components that are in near proximity to the exhaust system. Reduced time to market necessitates an efficient process for thermal protection development. A robust procedure that utilizes state of the art CFD simulation techniques proactively during the design phase is described. Simulation allows for early detection of thermal issues and development of countermeasures several months before prototype vehicles are built. Physical testing is only used to verify the thermal protection package rather than to develop heat shields. The new procedure reduces the number of physical tests and results in a robust, efficient methodology.
Technical Paper

An Optical Backscatter Sensor for Particulate Matter Measurement

2009-04-20
2009-01-0687
An optical-based sensor for detecting particulate matter (PM) in diesel engine exhaust has been demonstrated. The position of the sensor during the experiments was the exhaust manifold prior to the turbocharger. The sensor is constructed of fiber optics which transmit 532-nm laser light into the exhaust pipe and collect backscattered light in a 180° geometry. Due to the optical nature of the probe, PM sensing can occur at high temporal rates. Experiments conducted by changing the fuel injection properties of one cylinder of a four cylinder engine demonstrated that the sensor can resolve cycle dependent events. The feasibility of the probe for examining PM emissions in the exhaust manifold will be discussed.
Technical Paper

Application of Multi-Parameter and Boundary Mannequin Techniques in Automotive Assembly Process

2003-06-17
2003-01-2198
This paper deals with the multi-parameter and boundary mannequin techniques in creating human models in automotive applications. The concepts and applications of single-parameter, multiple parameter and boundary mannequin method are discussed respectively to clarify certain confusion. Emphasis is put on how to create boundary mannequins for a specific application, which may have been puzzling many engineers in practical applications. The authors would like to share their experience in using the digital human modeling software and make discussions on some common issues. A number of case studies from typical automotive manufacturing assembly operations are also presented to demonstrate the usage of the multi-parameter and boundary mannequin techniques.
Technical Paper

Assessing Reductant Chemistry During In-Cylinder Regeneration of Diesel Lean NOx Traps

2004-10-25
2004-01-3023
Lean NOx Trap (LNT) catalysts are capable of reducing NOx in lean exhaust from diesel engines. NOx is stored on the catalyst during lean operation; then, under rich exhaust conditions, the NOx is released from and reduced by the catalyst. The process of NOx release and reduction is called regeneration. One method of obtaining the rich conditions for regeneration is to inject additional fuel into the engine cylinders while throttling the engine intake air flow to effectively run the engine at rich air:fuel ratios; this method is called “in-cylinder” regeneration. In-cylinder regeneration of LNT catalysts has been demonstrated and is a candidate emission control technique for commercialization of light-duty diesel vehicles to meet future emission regulations. In the study presented here, a 1.7-liter diesel engine with a LNT catalyst system was used to evaluate in-cylinder regeneration techniques.
Technical Paper

Axial NO2 Utilization Measurements within a Partial Flow Filter during Passive Regeneration

2017-03-28
2017-01-0988
Measuring axial exhaust species concentration distributions within a wall-flow aftertreatment device provides unique and significant insights regarding the performance of complex devices like the SCR-on-filter. In this particular study, a less complex aftertreatment configuration which includes a DOC followed by two uncoated partial flow filters (PFF) was used to demonstrate the potential and challenges. The PFF design in this study was a particulate filter with alternating open and plugged channels. A SpaciMS [1] instrument was used to measure the axial NO2 profiles within adjacent open and plugged channels of each filter element during an extended passive regeneration event using a full-scale engine and catalyst system. By estimating the mass flow through the open and plugged channels, the axial soot load profile history could be assessed.
Technical Paper

Characterization of In-Cylinder Techniques for Thermal Management of Diesel Aftertreatment

2007-10-29
2007-01-3997
One challenge in meeting emission regulations with catalytic aftertreatment systems is maintaining the proper catalyst temperatures that enable the catalytic devices to perform the emissions reduction. In this study, in-cylinder techniques are used to actively control the temperature of a catalyzed diesel particulate filter (DPF) in order to raise the DPF temperature to induce particulate oxidation. The performance of four strategies is compared for two different starting DPF temperatures (150°C and 300°C) on a 4-cylinder 1.7-liter diesel engine. The four strategies include: (1) addition of extra fuel injection early in the combustion cycle for all four cylinders, (2) addition of extra fuel injection late in the combustion cycle for all four cylinders, (3) operating one-cylinder with extra fuel injection early in the combustion cycle, and (4) operating one-cylinder with extra fuel injection late in the combustion cycle.
Technical Paper

Characterization of Lean NOx Trap Catalysts with In-Cylinder Regeneration Strategies

2008-04-14
2008-01-0448
Lean NOx trap (LNT) catalysts with different formulations have been characterized on a light-duty diesel engine platform. Two in-cylinder regeneration strategies were used during the study. The reductant chemistry differed for both strategies with one strategy having high levels of CO and H2 and the other strategy having a higher hydrocarbon component. The matrix of LNT catalysts that were characterized included LNTs with various sorbate loads and varying ceria content; the sorbate was Ba. Intra-catalyst measurements of exhaust gas composition were obtained at one quarter, one half, and three quarters of the length of the catalysts to better understand the affect of formulation on performance. Exhaust analysis with FTIR allowed measurement of NH3 and thereby, a measurement of N2 selectivity for the catalysts. Although overall NOx conversion increased with increasing sorbate load, the formation of NH3 increased as well.
Technical Paper

Combustion, Control, and Fuel Effects in a Spark Assisted HCCI Engine Equipped with Variable Valve Timing

2006-04-03
2006-01-0872
Widespread implementation of homogeneous charge compression ignition (HCCI) engines is presently hindered by stability, control, and load range issues. Although the operable HCCI speed/load range is expanding, it is likely that the initial HCCI engines will rely on conventional combustion for part of the operating cycle. In the present study, we have investigated the role of fuel properties and chemistry on the operation of a spark-assisted gasoline HCCI engine. The engine employed is a single cylinder, 500 cc, port fuel injected research engine, operating near lambda = 1.0 and equipped with hydraulic variable valve actuation. HCCI is initiated by early exhaust valve closing to retain exhaust in the cylinder, thereby increasing the cylinder gas temperature. This is also referred to as a ‘negative overlap’ strategy.
Journal Article

Comparative Study of Hybrid Powertrains on Fuel Saving, Emissions, and Component Energy Loss in HD Trucks

2014-09-30
2014-01-2326
Two hybrid powertrain configurations, including parallel and series hybrids, were simulated for fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving conditions. A comprehensive set of component models describing engine fuel consumption, emissions control, battery energy, and accessory power demand interactions was developed and integrated with the simulated hybrid trucks to identify heavy-duty (HD) hybrid technology barriers. The results show that series hybrid is absolutely negative for fuel-economy improvement of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical).
Technical Paper

Comparison of Parametric and Non-Parametric Methods for Determining Injury Risk

2003-03-03
2003-01-1362
This paper contains a review of methods for deriving risk curves from biomechanical data obtained from impact experiments on human surrogates. It covers many of the problems and pitfalls of obtaining realistic human risk curves from impact experiments. The strength and weakness of both parametric and non-parametric methods are evaluated. The limitations of standard analysis of censored impact test data are presented. Methods are given for determining risk curves from both doubly censored data and data obtained from impacts to body regions in which there are more than one mechanism of injury. A detailed set of examples is presented in which different experimental data are analyzed using the Consistent Threshold method and the logistic approach. Finally risk curves for published data are presented for the femur, head, thorax, and neck.
Technical Paper

Considerations of Bio-fidelity Corridors for Lateral Impacts

2005-04-11
2005-01-0308
Developing an effective side impact ATD for assessing vehicle impact responses requires a method for evaluating that ATD's bio-fidelity. ISO/TR9790 has been in existence for some years to serve that purpose. Recently, NHTSA sponsored a research project on the post-mortem human subjects (PMHS) responses subjected to side impact conditions. Based on those newly available PMHS data, Maltese generated a new approach for creating bio-fidelity corridors for human surrogates. The approach incorporates the time factor into the evaluation equation and automates the process (Maltese et al. 2002). This paper serves as the first attempt to look closely at the new bio-fidelity corridor generation process (hereafter referred as the Maltese approach) with respect to its validity, effectiveness, as well as its practicality. The effect of mass scaling was first examined in order to ensure the integrity of the data. The time alignment scheme and the formation of the corridors were then tested.
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