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The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.

Significant A/F ratio excursion may occur during some engine transient operations, especially for transient periods of throttle tip in or tip out. A/F ratio excursion results in excessive emissions, extra fuel consumption, driveability deterioration and three-way-catalyst (TWC) efficiency drop. Simple two-parameter (X, τ) wall wetting models have traditionally been used to describe this transient A/F ratio excursion phenomenon. The transient fuel control techniques are utilized for this model to be applicable across vehicles, engines, fuel types and ambient conditions, so as to compensate for the A/F ratio excursion with the extra compensation fuel. More complicated model structures must be further expanded and model dependence on various environment conditions must be established to achieve a precise model. In this paper, a simple linear approach is proposed for transient fuel control, using least squares estimation.

Close coupled catalysts and new ceramic catalyst substrates have significantly improved the light-off performance of automotive converters required to meet stringent emission requirements. The hotter environment of these catalytic converters and the lower structural strength of the ceramic substrates require the rethinking of converter designs. The development of new package requirements to accommodate the change in environment and new substrates are discussed. A historical perspective on converter durability is presented as reference. Development of durability test protocols is essential to verifying product durability performance to these new environments. Data collection and documentation of testing templates are shown to demonstrate the effectiveness of tests that represent real world environments. Design improvements to address failure modes are discussed along with durability improvement results.

Gasoline is a complex fuel. Many of the constituents of gasoline that are beneficial for the internal combustion engine (ICE) are expected to be challenging for on-board reformers in fuel-cell vehicles. To address these issues, the autothermal reforming of gasoline and individual components of gasoline has been investigated. The results indicate that aromatic components require higher temperatures and longer contact times to reform than paraffinic components. Napthenic components require higher temperatures to reform, but can be reformed at higher space velocities than paraffinic components. The effects of sulfur are dependent on the catalyst. These results suggest that further evolution of gasoline could reduce the demands on the reformer and provide a better fuel for a fuel-cell vehicle.

Similar to single-brick SCR architectures, the multi-brick SCR systems described in this paper require urea injection control software that meets the NOx conversion performance target while maintaining the tailpipe NH3 slip below a given threshold, under all driving conditions. The SCR architectures containing a close-coupled SCRoF and underfloor SCR are temperature-wise more favorable than the under-floor location and lead to significant improvement of the global NOx conversion, compared to a single-brick system. But in order to maximize the benefit of close-coupling, the urea injection control must maximize the NH3 stored in the SCRoF. The under-floor SCR catalyst can be used as an NH3 slip buffer, lowering the risk of NH3 slip at the tailpipe with some benefit on the global NOx conversion of the system. With this approach, the urea injection strategy has a limited control on the NH3 coverage of the under-floor SCR catalyst.

High cell density (HCD) (≥ 600 cpsi) and /or ultra thin wall (UTW) (≤ 4 mil) extruded ceramic monolith substrates are being used in many new automotive catalyst applications because they offer (1) increased geometric surface area, (2) lower thermal mass, (3) increased open frontal area and (4) higher heat and mass transfer rates. Delphi has shown in previous papers how to use the effectiveness, NTU theory, to optimize the various benefits of these HCD / UTW catalysts. A primary disadvantage of these low solid fraction substrates is their reduced structural strength, as measured by a 3-D hydrostatic (isostatic) test. The weakest of these new substrates is only 10 to 20% as strong as standard 400 × 6.5 substrates. Improved converter assembly methods with lower, more uniform forces will likely be required to successfully assemble converters with such weak substrates in production.

FTP emissions from a 2.2L four cylinder vehicle are measured from six different converters. These converters have been designed to have both similar flow restriction and to have similar platinum group metals. The durability of these six converters is evaluated after dynamometer aging of both 125 and 250 hours of RATsm aging. These catalytic converters use various combinations of 400/3.5 (400 cells/in2/3.5mil wall), 400/4.5, 400/6.5, 600/3.5, 600/4.5, and 900/2.5 ceramic substrates in order to meet a restriction target and to maximize converter geometric surface area. Total catalyst volume of the converters varies from 1.9 to 0.82 liters. Catalyst frontal area varies from 68 cm2 to 88 cm2. Five of the six converters use two catalyst bricks. The front catalyst brick uses either a three-way Pd washcoat technology containing ceria or a non-ceria Pd washcoat technology. To minimize dependence on palladium the rear brick uses a Pt/Rh washcoat at a loading of 0.06 Toz and a ratio of 5/0/1.

The detailed morphological properties of diesel particulate matter were analyzed along the exhaust system at various engine operating conditions (in a range of 1000 - 2500 rpm and 10 - 75 % loads of maximum torques). A 1.7-L turbocharged light-duty diesel engine was powered with California low-sulfur diesel fuel injected by a common-rail injection system, of which particulate emissions were controlled by an exhaust gas recirculation (EGR) system and two oxidation catalysts. A unique thermophoretic sampling system first developed for internal combustion engine research, a high-resolution transmission electron microscope (TEM), and a customized image processing/data acquisition system were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

In order to determine any synergistic effects from reforming multicomponent fuels and to determine the effects of fuel additives and impurities we have investigated the autothermal reforming of fuel blends, including paraffin-aromatic, paraffin-naphthene, paraffin-oxygenate, and paraffin-detergent binary mixtures. The results indicate that aromatic, naphthenic, and detergent components adversely effect the reforming of paraffinic species. The results suggest that competitive adsorption at the catalyst sites decreases conversion rates of the paraffinic species. The paraffinic species are displaced by more strongly adsorbing species, leading to decreased kinetics for paraffin conversion.

The physical and morphological properties of the particulate matter emitted from a 1.7-liter light-duty diesel engine were characterized by observing its evolution in size and fractal geometry along the exhaust system. A common-rail direct-injection diesel engine, the exhaust system of which was equipped with a turbocharger, EGR, and two oxidation catalysts, was powered with a California low-sulfur diesel fuel at various engine-operating conditions. A unique thermophoretic sampling system, a high-resolution transmission electron microscope (TEM), and customized image processing/data acquisition systems were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively. The measurements were carried out at four different positions along the exhaust pipe.

Thinwall substrates used in modern catalytic converters are more sensitive to assembly and operating forces. Various converter assembly processes are characterized using real time force transducer technology. The force distribution data from these assembly methods are presented. The analysis of this data leads to recommendations for packaging of converters depending on catalyst strength.

Particulate and gaseous emissions from a Mitsubishi Legnum GDI™ wagon were measured for FTP-75, HWFET, SC03, and US06 cycles. The vehicle has a 1.8-L spark-ignition direct-injection engine. Such an engine is considered a potential alternative to the compression-ignition direct-injection engine for the PNGV program. Both engine-out and tailpipe emissions were measured. The fuels used were Phase-2 reformulated gasoline and Indolene. In addition to the emissions, exhaust oxygen content and exhaust-gas temperature at the converter inlet were measured. Results show that the particulate emissions are measurable and are significantly affected by the type of fuel used and the presence of an oxidation catalyst. Whether the vehicle can meet the PNGV goal of 0.01 g/mi for particulates depends on the type of fuel used. Both NMHC and NOx emissions exceed the PNGV goals of 0.125 g/mi and 0.2 g/mi, respectively. Meeting the NOx goal will be especially challenging.

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800°C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h-1) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

The Prius is a major achievement by Toyota: it is the first mass-produced HEV with the first available HEV-optimized engine. Argonne National Laboratory's Advanced Powertrain Test Facility has been testing the Prius for model validation and technology performance and assessment. A significant part of the Prius test program is focused on testing and mapping the engine. A short-length torque sensor was installed in the powertrain in-situ. The torque sensor data allow insight into vehicle operational strategy, engine utilization, engine efficiency, and specific emissions. This paper describes the design and process necessary to install a torque sensor in a vehicle and shows the high-fidelity data measured during chassis dynamometer testing. The engine was found to have a maximum thermodynamic efficiency of 36.4%. Emissions and catalyst efficiency maps were also produced.

This paper reports an effort to measure particulate emissions from a modern light duty CIDI engine equipped with a common-rail fuel injection system, a closed loop EGR system and a state-of-the-art aftertreatment system. Particulate emissions both upstream and downstream of the catalyst were measured using an SMPS system and a TEOM while operating the engine at various steady-state conditions. The measurements upstream of the catalyst show that the particulate emissions are strongly dependent on the engine speed, load and EGR conditions. The measurements downstream of the catalyst show the effectiveness of the catalyst in reducing particulate mass emissions by 20-80%, with reductions in particulate mean diameters averaging about 10%. The trends observed are discussed in terms of previously established particulate formation and destruction mechanisms.

We have prepared and tested laboratory scale monoliths wash-coated with 10, 20 and 30 wt% of either CeO2 or Ce.75Zr.25O2 (remainder is alumina). Wet impregnation was used to load the wash-coated monoliths with 50g/ft Pt:Rh at a 5:1 ratio. The catalyst were aged at temperatures between 825°C and 950°C using a cycled redox aging. The catalysts were then tested in a full-feed simulated exhaust laboratory reactor with air-to-fuel ratio (A/F) perturbations (frequencies at 1 and 3 Hz and amplitudes up to +/- 0.8 A/F). Even the lowest loading of Ce.75Zr.25O2 outperformed all three loadings of CeO2 over a full range of reaction temperatures, A/F perturbations, and catalyst space velocity (SV). Our data indicates that the ceria-zirconia catalysts can tolerate cycled redox aging at sustained bed temperatures at least 25°C higher (∼925°C vs. < 900°C) than can ceria. For the CeO2 catalysts aged at or above 900°C we observed an inverse correlation of catalyst activity to CeO2 loading.

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior.

It is widely understood that cold ambient temperatures increase vehicle fuel consumption due to heat transfer losses, increased friction (increased viscosity lubricants), and enrichment strategies (accelerated catalyst heating). However, relatively little effort has been dedicated to thoroughly quantifying these impacts across a large set of real world drive cycle data and ambient conditions. This work leverages experimental dynamometer vehicle data collected under various drive cycles and ambient conditions to develop a simplified modeling framework for quantifying thermal effects on vehicle energy consumption. These models are applied over a wide array of real-world usage profiles and typical meteorological data to develop estimates of in-use fuel economy. The paper concludes with a discussion of how this integrated testing/modeling approach may be applied to quantify real-world, off-cycle fuel economy benefits of various technologies.

Gasoline Direct Injection (GDI) engine has a significant fuel economy improvement over the traditional port fuel injection engine. The tradeoff for this benefit is excessive exhaust emissions, especially NOx. Three-way-catalyst (TWC) is inefficient to treat NOx emission during lean operation. So Lean NOx Trap (LNT) is invented for NOx aftertreatment and it has both storage mode and purge mode. Research on modeling and control of LNT has been conducted, but it is still lack of the essential information on the temperature effect. This research focuses on the impact of trap temperature on LNT storage time, purge time and fuel economy. The mechanism of temperature effect on LNT is investigated at first. Then the temperature control strategy based on fuel economy improvement is proposed.