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A supercritical organic Rankine cycle (ORC) system for recovery of waste heat from heavy-duty diesel engines is proposed. In this system, an organic, medium-boiling-point fluid is selected as the working fluid, which also serves as the coolant for the charge air cooler and the EGR coolers. Because the exhaust temperature can be as high as 650 °C during the DPF regeneration, an exhaust cooler is included in the system to recover some of the high level exhaust energy. In the present ORC system, the expansion work is conducted by a uniflow reciprocating expander, which simplifies the waste-heat-recovery (WHR) system significantly. This reciprocating Rankine engine is more appropriate for on-road-vehicle applications where the condition for waste heat is variable. The energy level of waste heat from a heavy-duty diesel engine is evaluated by the analyses of the first and second law of thermodynamics.