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The long-term durability of a vehicle's exhaust catalyst is essential for emission control. Catalyst durability can be affected by a variety of factors including engine oil consumption. During normal engine operation, some of the lubricating oil is combusted. The deposition of combustion products from phosphorus containing lubricant additives on the catalyst can adversely affect catalyst durability. In an attempt to minimize the impact of oil consumption on additive performance, engines have been designed to reduce oil consumption and oils are being formulated with lower concentrations of phosphorus compounds. However, these phosphorus compounds protect the engine from excessive wear and cannot be easily removed from lubricant oil due to concerns over engine durability. The use of a phosphorus scavenger is an approach that works together with engine design to minimize catalyst deterioration.

In July 2002, the Alliance of Automobile Manufacturers, the Association of International Automobile Manufacturers and the Canadian Vehicle Manufacturers Association released the results of a 6-year, two-part vehicle fleet test program to determine the effects of methyl-cyclopentadienyl manganese tricarbonyl (MMT®*) on vehicles equipped with state of the art emission control systems. Analysis of the data reports from this study shows that all of the vehicles met applicable emission standards, even though the fleet accumulated mileage under very severe conditions that accelerate degradation of vehicle emission control systems in excess of that expected from actual vehicle mileage. The study also demonstrated that gasoline-containing MMT had no adverse impact on vehicular emission control equipment.

MMT (methylcyclopentadienyl manganese tricarbonyl) is an antiknock additive for unleaded gasoline, which is now required for cars equipped with catalytic converters. Because of its effectiveness, MMT is economically attractive compared with achieving antiknock quality by refinery processing. Use of MMT in gasoline at a concentration of 0.125 g of contained manganese per gallon provides, on the average, about 2 road octane numbers. Compared to processing, this could represent a savings in crude oil of about 1%. Like other antiknocks, the economic attractiveness of MMT is greatest at low concentrations. Extensive road and dynamometer engine tests have shown that use of MMT in the recommended concentration range is compatible with general aspects of car operation--octane number requirement, exhaust valve and spark plug durability, and exhaust gas recycle for NOx control. Moreover, beneficial effects in exhaust valve guide and seat wear have been observed with MMT in some tests.

In designing fuel economy oils, two useful approaches are reduction of viscosity and incorporation of friction reducers. To achieve viscosity reduction without incurring problems of high oil consumption and possible interference with catalyst or oxygen sensor performance, the use of part-synthetic lubricants can be helpful. In this way, oil volatility (therefore oil consumption) is reduced and fuel economy is improved without incurring engine operating penalties. Friction reducers also can be used to improve fuel economy. The combination of these approaches furnishes the benefits of both. Laboratory and road testing of such combinations show important fuel economy benefits in normal vehicle operation, greater than those achievable from either approach alone. In addition, all other engine performance requirements are completely met. This advance in engine oil formulation technology, which opens up new possibilities to both vehicle manufacturers and consumers, is being further pursued.

Automotive gear oil development has expanded beyond the historical requirements of emphasizing wear protection to encompass modern needs for fuel economy and limited slip frictional properties. This paper describes the development process of a new generation, fuel efficient gear lubricant for use in light duty vehicles. A systematic formulation approach was used, encompassing fluid viscometrics and additive optimization. Performance testing in both laboratory and vehicle tests is described. Though standard GL-5 tests were used to confirm oxidation, wear and corrosion performance, emphasis is given to those methods used for optimizing fuel economy.

The Clean Air Act of 1990 requires on-board diagnostics (OED) capabilities on all new vehicles. These diagnostic systems monitor the performance of engine and emission system components and inform the vehicle operator when component or system degradation could significantly impact emissions. Acceptable operation of the monitor requires proper treatment of system variables. Fuel composition is one of many possible variables that must be considered for monitoring components directly in the exhaust stream. Recently, the octane enhancing, emissions reducing additive methylcyclopentadienyl manganese tricarbonyl (MMT) was reintroduced into unleaded gasoline in the U.S. Prior to reintroduction, the additive underwent extensive testing to demonstrate that use of MMT does not adversely affect vehicle emissions or the operation of emission systems such as OBD. However, questions have been raised about the influence of the additive on OBD systems.

This paper describes a method for accurately measuring sulfur oxides in automotive exhaust. In this method, the exhaust from a car is diluted with ambient air, then introduced into a large bag filled with clean dry air. The temperature, pressure, and humidity of the diluted exhaust are measured, along with the concentrations of hydrocarbons, carbon monoxide, carbon dioxide, SO2, and sulfates. Bag concentrations are related to the exhaust by using the sulfur/carbon ratio of the fuel. Established instrumental methods are used for the carbon compounds. The sulfur dioxide in the diluted exhaust gas is measured by the West-Gaeke method, which involves collecting a gaseous sample in a scrubber containing potassium tetrachloromecurate. The sulfates are collected on a particulate filter and measured by a new colorimetric method. The techniques we have developed have been applied to both non-catalyst and catalyst-equipped cars. These studies have shown that: 1.

Throughout the world, governments are promulgating regulations that are intended to improve air quality. Some of these regulations affect the physical and chemical properties of gasoline. Consequently, refiners are under increasing pressure to reformulate their gasoline to be lower emitting when handled and combusted. These regulatory actions have also greatly reduced flexibility in the fuel formulation process. In many cases, refiners are attempting to reduce gasoline vapor pressure, sulfur, aromatic, and olefin content while simultaneously tightening distillation characteristics by removing butane and reducing the use of heavy reformate and FCC fractions. Because butane, aromatics and olefins can contribute substantially to pool octane levels, blending clean-burning gasoline with the required octane rating for acceptable vehicle performance can be difficult.

Extensive vehicle fleet testing has demonstrated that use of MMT can reduce net tailpipe out emissions. The use of fuel containing the octane-enhancing, emission-reducing fuel additive leads to manganese oxide deposits in the vehicle exhaust system. Studies of the physical and chemical effects of manganese oxide deposits on the performance of catalytic converters conclusively demonstrated that MMT does not adversely affect catalytic converters and, in fact, protected the converters from phosphorus and zinc. Despite the overwhelming evidence that MMT is compatible with catalytic converters and vehicle emission control systems, concerns have recently been raised about the effect of manganese oxides on OBD-II catalytic converter monitoring.