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Due to stringent environmental requirements, the vehicle under-hood and underbody temperatures have been steadily increasing. The increased temperatures affect components life and therefore, more thermal protection measures may be necessary. In this paper, we present an algorithm for estimation of automotive component life due to thermal effects through the vehicle life. Traditional approaches consider only the maximum temperature that a component will experience during severe driving maneuvers. However, that approach does not consider the time duration or frequency of exposure to temperature. We have envisioned a more realistic and science based approach to estimate component life based on vehicle duty cycles, component temperature profile, frequency and characteristics of material thermal degradation. In the proposed algorithm, a transient thermal analysis model provides the exhaust gas and exhaust surface temperatures for all exhaust system segments, and for any driving scenario.