Search Results

In this work autoignition delay times of two multi-component surrogates (high and low RON) were experimentally compared with their target full blend gasoline fuels. The study was conducted in a rapid compression machine (RCM) test facility and a direct test chamber (DTC) charge preparation approach was used for mixture preparation. Experiments were carried over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. Dilution in the reactant mixture was varied from 0% to 30% CO2 (by mass), with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy emulates exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines. The multicomponent surrogate captured the reactivity trends of the gasoline-air mixtures reasonably well in comparison to the single component (iso-octane) surrogate.

In 1990, Roy Douglas developed an analytical method to calculate the global air-to-fuel ratio of a two-stroke engine from exhaust gas emissions. While this method has considerable application to two-stroke engines, it does not permit the calculation of air-to-fuel ratios for oxygenated fuels. This study proposed modifications to the Roy Douglas method such that it can be applied to oxygenated fuels. The ISO #16183 standard, the modified Spindt method, and the Brettschneider method were used to evaluate the modifications to the Roy Douglas method. In addition, a trapped air-to-fuel ratio, appropriate for two-stroke engines, was also modified to incorporate oxygenated fuels. To validate the modified calculation method, tests were performed using a two-stroke carbureted and two-stroke direct injected marine outboard engine over a five-mode marine test cycle running indolene and low level blends of ethanol and iso-butanol fuels.

Spark ignition engines utilize catalytic converters to reform harmful exhaust gas emissions such as carbon monoxide, unburned hydrocarbons, and oxides of nitrogen into less harmful products. Aftertreatment devices require the use of expensive catalytic metals such as platinum, palladium, and rhodium. Meanwhile, tightening automotive emissions regulations globally necessitate the development of high-performance exhaust gas catalysts. So, automotive manufactures must balance maximizing catalyst performance while minimizing production costs. There are thousands of different recipes for catalytic converters, with each having a different effect on the various catalytic chemical reactions which impact the resultant tailpipe gas composition. In the development of catalytic converters, simulation models are often used to reduce the need for physical parts and testing, thus saving significant time and money.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

An experimental study and analysis was conducted to investigate cold start robustness of an ethanol flex-fuel spark ignition (SI) direct injection (DI) engine. Cold starting with ethanol fuel blends is a known challenge due to the fuel characteristics. The program was performed to investigate strategies to reduce the enrichment requirements for the first firing cycle during a cold start. In this study a single-cylinder SIDI research engine was used to investigate gasoline and E85 fuels which were tested with three piston configurations (CR11F, CR11B, CR15.5B - which includes changes in compression ratio and piston geometry), at three intake cam positions (95, 110, 125 °aTDC), and two fuel pressures (low: 0.4 MPa and high: 3.0 MPa) at 25°C±1°C engine and air temperature, for the first cycle of an engine start.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

Optical and laser diagnostics enable in-depth spray characterization in regards to macroscopic spray characteristics and in-situ fuel mixture quality information, which are needed in understanding the spray injection process and for spray model development, validation and calibration. Use of fuel surrogates in spray researches is beneficial in controlling fuel parameters, developing spray and combustion kinetic models, and performing laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of a single and multi-component surrogate in comparison to a gasoline with 10% ethanol under gasoline direct injection (GDI) engine conditions. In addition, the effect of fuel tracers on spray evolution and vaporization is also investigated. Both diethyl-methyl-amine/fluorobenzene as a laser-induced exciplex (LIEF) fluorescence tracer pair and 3-pentanone as a laser-induced fluorescence (LIF) tracer are examined.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

Two diagnostics were developed that are particularly suitable for use with natural gas-fuelled reciprocating engines that are used for power generation applications. The first diagnostic relates flame chemiluminescence to thermodynamic metrics relevant to engine combustion - Heat Release Rate (HRR) and in-cylinder bulk gas temperature. Studies were conducted in a single-cylinder natural gas-fired reciprocating engine that could simulate turbocharged conditions with Exhaust Gas Recirculation. Crank-angle-resolved spectra (266 to 795 nm) of flame luminosity were measured for various operational conditions by varying the ignition timing for MBT conditions and by holding the speed at 1800 rpm and Brake Mean Effective Pressure (BMEP) at 12 bar. The effect of dilution on CO₂* chemiluminescence intensities was studied, by varying the global equivalence ratio (0.6 - 1.0) and by varying the Exhaust Gas Recirculation rate.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.

The knock resistance of fuels has been historically measured using the ASTM RON and MON methods. However, significant discrepancies between the fuel octane number and knock-limited performance in modern spark-ignited (SI) engines have been well-documented. Differences between the operating conditions of the Cooperative Fuels Research (CFR) engine during RON rating and those attained in modern SI engines have been highlighted in the literature. While octane ratings are performed for each fuel on the CFR engine at the lambda that provides the highest knockmeter reading, modern SI engines are generally operated at stoichiometry and knock intensity is based on the high frequency cylinder pressure oscillations associated with knocking combustion. In the present work, an instrumented CFR engine was used to analyze lambda effects on both the conventional knockmeter RON rating method and cylinder pressure transducer based knock intensity.

This paper reviews and summarizes recent developments in hydrogen (H2) powered engine and vehicle research. Following an overview of mixture formation strategies, general trade-offs when operating engines on hydrogen are analyzed and highlights regarding accomplishments in efficiency improvement and emissions reduction are presented. These include estimates of efficiency potential of direct-injection hydrogen engines based on single-cylinder research engine data, fuel economy and emissions results of hydrogen powered passenger cars and pickup trucks as well as the impact and potential of hydrogen/methane blended operation.

SunDiesel™ is an alternative bio-fuel derived from wood chips that has certain properties that are superior to those of conventional diesel (D2). In this investigation, 100% SunDiesel was tested in a Mercedes A-Class (model year 1999), 1.7L, turbocharged, direct-injection diesel engine (EURO II) equipped with a common-rail injection system. By using an endoscope system, Argonne researchers collected in-cylinder visualization data to compare the engine combustion characteristics of the SunDiesel with those of D2. Measurements were made at one engine speed and load condition (2,500 rpm, 50% load) and four start-of-injection (SOI) points, because of a limited source of SunDiesel fuel. Significant differences in soot concentration, as measured by two-color optical pyrometry, were observed. The optical and cylinder pressure data clearly show significant differences in combustion duration and ignition delay between the two fuels.

Their easy availability, lower well-to-wheel emissions, and relative ease of use with existing engine technologies have made ethanol and ethanol-gasoline blends a viable alternative to gasoline for use in spark-ignition (SI) engines. The lower energy density of ethanol and ethanol-gasoline blends, however, results in higher volumetric fuel consumption compared with gasoline. Also, the higher latent heat of vaporization can result in cold-start issues with higher-level ethanol blends. On the other hand, a higher octane number, which indicates resistance to knock and potentially enables more optimal combustion phasing, results in better engine efficiency, especially at higher loads. This paper compares the fuel consumption and emissions of two ethanol blends (E50 and E85) with those for gasoline when used in conventional (non-hybrid) and power-split-type plug-in hybrid electric vehicles (PHEVs).