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A single cylinder indirect injection diesel engine was used to evaluate the emissions, fuel consumption, and ignition delay of non-petroleum liquid fuels derived from coal, shale, and tar sands. Correlations were made relating fuel properties with exhaust emissions, fuel consumption, and ignition delay. The results of the correlation study showed that the indicated fuel consumption, ignition delay, and CO emissions significantly correlated with the H/C ratio, specific gravity, heat of combustion, aromatics and saturates content, and cetane number, Multiple fuel properties were necessary to correlate the hydrocarbon emissions. The NOx emissions did not correlate well with any fuel property. Because these fuels from various resources were able to correlate succesfully with many of the fuel properties suggests that the degree of refinement or the chemical composition of the fuel is a better predictor of its performance than its resource.

New regulations from the state of California have established, for the first time, reactivity-based exhaust emissions standards for new vehicles and require that any clean alternative fuels needed by these vehicles be made available. Contained in these regulations are provisions for “reactivity adjustment factors” which will provide credit for vehicles which run on reformulated gasoline. The question arises: given two fuels of different chemical composition, but both meeting the criteria for CA Phase 2 gasoline (reformulated gasoline), how different might the specific reactivity of the exhaust hydrocarbons be? In this study we explored this question by examining the engine-out HC emissions from a single-cylinder version of the 5.4 L modular truck engine run on two different CA Phase 2 fuels.

A 1990 Ford Taurus operated on reformulated gasoline was tested under three modes of malfunction: disabled heated exhaust gas oxygen (HEGO) sensor, inactive catalytic converter, and controlled misfire. The vehicle was run for four U.S. EPA UDDS driving schedule (FTP-75) tests at each of the malfunction conditions, as well as under normal operating conditions. An extensive set of emissions data were collected. In addition to the regulated emissions (HC, CO, and NOx), a detailed chemical analysis was carried out to determine the gas- and particle-phase non-regulated emissions. The effect of vehicle malfunction on gas phase emissions was significantly greater than it was on particle phase emissions. For example, CO emissions ranged from 2.57 g/mi (normal operation) to 34.77 g/mi (disable HEGO). Total HCs varied from 0.22 g/mi (normal operation) to 2.21 g/mi (blank catalyst). Emissions of air toxics (1,3-butadiene, benzene, acetaldehyde, and formaldehyde) were also significantly effected.

Four vehicle fleets, consisting of 3 to 4 vehicles each, were emission tested on a 48″ roll chassis dynamometer using both the FTP urban dynamometer driving cycle and the REP05 driving cycle. The REP05 cycle was developed to test vehicles under high speed and high load conditions not included in the FTP. The vehicle fleets consisted of 1989 light-duty gasoline vehicles, 1992-93 limited production FFV/VFV methanol vehicles, 1992-93 compressed natural gas (CNG) vehicles and their gasoline counterparts, and a 1992 production and two prototype ethanol FFV/VFV vehicles. All vehicles (except the dedicated CNG vehicles) were tested using Auto/Oil AQIRP fuels A and C2. Other fuels used were M85 blended from A and C2, E85 blended from C1, which is similar to C2 but without MTBE, and four CNG fuels representing the range of in-use CNG fuels. In addition to bag measurements, tailpipe exhaust concentration and A/F data were collected once per second throughout every test.

Although much has been learned in recent years about the atmospheric reactivity of the hydrocarbon (HC) emissions from gasoline-fueled vehicles, there is only a limited database of corresponding information for exhaust emissions from diesel-fueled vehicles. An assessment of exhaust reactivity requires “speciation”, or measurement of the individual species of the HC fraction. The HC exhaust emissions are a complex mixture of unburned and partially burned fuel components. Because diesel fuel contains a much higher molecular weight range (typically C9-C26) than gasoline (typically C5-C12), new methodology was required to accommodate the collection and analysis of the >C12 fraction of the HC exhaust. As part of a study of the effects of fuel and other factors on the chemical nature of diesel emissions, we have developed a method for the collection and analysis of the semivolatile or heavy HC (>C12) fraction of the exhaust.

Although the intent of the SHED test (Sealed Housing for Evaporative Determination) is to measure evaporative fuel losses, the SHED sampling methodology in fact measures hydrocarbons from all vehicle and test equipment sources. Leakage of air conditioning (AC) refrigerant is one possible non-fuel source contributing to the SHED hydrocarbon measurement. This report describes a quick and relatively simple method to identify the contribution of AC refrigerant to the SHED analyzer reading. R134A (CH2FCF3), the hydrofluorocarbon refrigerant used in all current automotive AC systems, as well as its predecessor, the chlorofluorocarbon R12, can be detected using the gas chromatography methods currently in place at many emissions labs for the speciation of exhaust and evaporative hydrocarbon emissions.

European legislation covering noise, smoke emission and industrial pollution, all seeking to improve the environment are not addressed in this paper, which takes only exhaust emission and fuel complexity as its subjects. It describes how this complexity can inhibit the development capacity, thus restricting the model offering of a major european automobile manufacturer. The paper concludes that general benefit would be derived from genuine pan european emission legislation, particularly if that legislation was established at levels of control that allowed the development and use of modern engine technology.

A technique is presented that has been successfully demonstrated to non-intrusively and quickly sample gases typically found in PCV systems. Color Detection Tubes (CDTs) were used with a simple sampling arrangement to monitor CO2, NOx, O2, and H2O(g) at the closure line, crankcase, and PCV line. Measurements were accurate and could be made instantaneously. Short Path Thermal Desorbtion Tubes (SPTDTs) were used at the same engine locations for the characterization of fuel- and oil-derived hydrocarbon (HC) fractions and required only 50 cc samples. High engine loads caused pushover of blowby vapors as indicated by increased concentrations of CO2, NOx, H2O(g), and fuel HCs in the engines' fresh air inlets during WOT operation. Peak concentrations of blowby vapors were measured in the crankcase under no load and part throttle conditions. Oxygen concentrations always opposed the trends of CO2, NOx, and H2O(g).

As automakers strategize approaches to sustainable vehicle technologies, alternative powertrains must be considered to reduce future fleet vehicle emissions and improve energy security. These alternative vehicles include different fuels and electrification. The ultimate for on-road CO2 reductions is a zero emission vehicle, which can be achieved by either a hydrogen fuel cell or battery electric vehicle. These vehicles would also require a renewable energy source to provide their propulsion energy in order to achieve maximum sustainability for both CO2 reduction and energy security. Renewable energy sources such as wind or solar result in heat or electricity that needs to be generated into an energy carrier such as hydrogen or stored in a battery. When examining these options based strictly on the efficiency path, previous analysis have concluded fuel cell vehicles may not be an appropriate suitability strategy in comparison to battery electric vehicles.

A feedgas hydrocarbon emissions model that extends the usefulness of fully-warmed steady-state engine maps to the cold transient regime was developed for use within a vehicle simulation program that focuses on the powertrain control system (Virtual Powertrain and Control System, VPACS). The formulation considers three main sources of hydrocarbon. The primary component originates from in-cylinder crevice effects which are correlated with engine coolant temperature. The second component includes the mass of fuel that enters the cylinder but remains unavailable for combustion (liquid phase) and subsequently vaporizes during the exhaust portion of the cycle. The third component includes any fuel that remains from a slow or incomplete burn as predicted by a crank angle resolved combustion model.

A proportional sampler for vehicle feedgas and tailpipe emissions has been developed that extracts a small, constant fraction of the total exhaust flow during rapid transient changes in engine speed. Heated sampling lines are used to extract samples either before or after the catalytic converter. Instantaneous exhaust mass flow is measured by subtracting the CVS dilution air volume from the total CVS volume. This parameter is used to maintain a constant dilution ratio and proportional sample. The exhaust sample is diluted with high-purity air or nitrogen and is delivered into Tedlar sample bags. These transient test cycle weighted feedgas samples can be collected for subsequent analysis of hydrocarbons and oxygenated hydrocarbon species. This “mini-diluter” offers significant advantages over the conventional CVS system. The concentration of the samples are higher than those collected from the current CVS system because the dilution ratio can be optimized depending on the fuel.

The optimized design of an exhaust emission system in terms of performance, cost, packaging, and engine control strategy will be a key part of competitively meeting future more stringent emission standards. Extensive use of vehicle experiments to evaluate design system tradeoffs is far too time consuming and expensive. Imperative to successfully meeting the challenges of future emission regulations and cost constraints is the development of an exhaust system simulation model which offers the ability to sort through major design alternatives quickly while assisting in the interpretation of experimental data. Previously, detailed catalyst models have been developed which require the specification of intricate kinetic mechanisms to determine overall catalyst performance. While yielding extremely valuable results, these models use complex numerical algorithms to solve multiple partial differential equations which are time consuming and occasionally numerically unstable.

The small-displacement direct-injection (DI) diesel engine is a prime candidate for future transportation needs because of its high thermal efficiency combined with near term production feasibility. Ford Motor Company and FEV Engine Technology, Inc. are working together with the US Department of Energy to develop a small displacement DI diesel engine that meets the key challenges of emissions, NVH, and power density. The targets for the engine are to meet ULEV emission standards while maintaining a best fuel consumption of 200g/kW-hr. The NVH performance goal is transparency with state-of-the-art, four-cylinder gasoline vehicles. Advanced features are required to meet the ambitious targets for this engine. Small-bore combustion systems enable the downsizing of the engine required for high fuel economy with the NVH advantages a four- cylinder has over a three-cylinder engine.

It is frequently useful to calculate the theoretical composition of the major components of vehicle exhaust. A software program has been written in Basic (or Quick Basic) which allows the convenient calculation of volume percents of CO, CO2, O2, H2, and H2O from fuel composition (H/C and O/C ratios), the water content (dew point) of the combustion air, and a chosen stoichiometry (air/fuel ratio). The program considers the Water Gas Shift reaction and the production of hydrogen under fuel rich conditions. The program is valid for both standard gasolines and oxygenated blends. Vehicle emissions data, collected to compare values calculated by the program with actual experimentally determined values from vehicle exhaust, show good agreement for measurements made at a series of air/fuel ratios ranging from lambda of 0.85-1.2.

A structural ceramic diesel engine has the potential to provide low heat rejection and significant improvements in fuel economy. Analytical and experimental evaluations were conducted on the critical elements of this engine. The structural ceramic components, which included the cylinder, piston and pin, operated successfully in a single cylinder engine for over 100 hours. The potential for up to 8-11% improvement in indicated specific fuel consumption was projected when corrections for blow-by were applied. The ringless piston with gas squeeze film lubrication avoided the difficulty with liquid lubricants in the high temperature piston/cylinder area. The resulting reduction in friction was projected to provide an additional 15% improvement in brake specific fuel consumption for a multi-cylinder engine at light loads.

In this study an attempt to understand and demonstrate the effects of various washcoat technologies under active and passive regeneration conditions was performed. Six different formulations, on 1.0" D. x 3.0" L. SiC wall flow filters at the laboratory level were used at various test conditions, including variable NO₂/NO ratios and O₂ concentrations. Samples were regenerated using active and passive conditions to evaluate regeneration rates and the potential impact of regeneration at the vehicle level. Results were applied to vehicle operating conditions to determine passive functionality and potential benefits. Active regenerations at 2% O₂ and 5% O₂ showed no significant difference in time to complete regeneration and soot burn rates. Active regenerations performed at 1% O₂ and 5% O₂ concentration showed that the regeneration temperature was shifted by approximately 50°C.

The effective deployment of FMEAs within complex automotive applications faces a number of challenges, including the complexity of the system being analysed, the need to develop a series of coherently linked FMEAs at different levels within the systems hierarchy and across intrinsically interlinked engineering disciplines, and the need for coherent linkage between critical design characteristics cascaded through the systems levels with their counterparts in manufacturing. The approach presented in this paper to address these challenges is based on a structured Failure Mode Avoidance (FMA) framework which promotes the development of FMEAs within an integrated Systems Engineering approach. The effectiveness of the framework is illustrated through a case study, centred on the development of a diesel exhaust aftertreatment system.

The purpose of this paper is to make a preliminary assessment of the potential toxicity of compounds that might be emitted from diesel vehicles using urea/SCR technology. The use of urea as a reductant in the removal of NOx from the exhaust of diesel-powered vehicles has the potential to emit at least seven thermal decomposition products and unreacted urea from the tail-pipe. These compounds include: urea, ammonia, cyanate ion, biuret, cyanuric acid, ammelide, ammeline, and melamine. The toxicity data base for these compounds, in general, is poor. In addition, there have been few, if any, studies examining the inhalation route of exposure - the most likely route of exposure for people from vehicle exhaust. The measurement and identification of these compounds from the exhaust of urea/SCR- equipped vehicles is needed to prioritize the kinds of health effects studies required to understand the toxicity of these compounds.

An analytical method for the determination of hydrocarbon and ether emissions from gasoline-, methanol-, and flexible-fueled vehicles is described. This method was used in Phase I of the Auto/Oil Air Quality Improvement Research Program to provide emissions data for various vehicles using individual reformulated gasolines and alternate fuels. These data would then be used for air modeling studies. Emission samples for tailpipe, evaporative, and running loss were collected in Tedlar bags. Gas chromatographic analysis of the emissions samples included 140 components (hydrocarbons, ethers, alcohols and aldehydes) between C1 and C12 in a single analysis of 54-minutes duration. Standardization, quality control procedures, and inter-laboratory comparisons developed and completed as part of this program are also described.

A study was carried out to increase our understanding of the emissions of air toxics from normal and high-emitting vehicles. This study is part of a larger study on fuel effects in high-emitting vehicles, and is part of the Auto/Oil Air Quality Improvement Research Program (AQIRP). Detailed measurements were carried out on the emissions of two vehicles run on industry-average gasoline. The two vehicles, having similar emissions control technologies, represent a high-emitting vehicle and a normal-emitting vehicle. In addition to the regulated emissions (HC, CO, and NOx), a detailed chemical analysis was carried out on the gas - and particle-phase non-regulated emissions. The vehicles were tested over the U.S. EPA UDDS driving schedule. The high emitter was highly variable with regard to emissions, but always operated rich of the stoichiometric point. Up to 46% of fuel carbon was emitted as CO and unburned HC for the high emitter, compared to less than 1.4% for the normal emitter.