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A single cylinder indirect injection diesel engine was used to evaluate the emissions, fuel consumption, and ignition delay of non-petroleum liquid fuels derived from coal, shale, and tar sands. Correlations were made relating fuel properties with exhaust emissions, fuel consumption, and ignition delay. The results of the correlation study showed that the indicated fuel consumption, ignition delay, and CO emissions significantly correlated with the H/C ratio, specific gravity, heat of combustion, aromatics and saturates content, and cetane number, Multiple fuel properties were necessary to correlate the hydrocarbon emissions. The NOx emissions did not correlate well with any fuel property. Because these fuels from various resources were able to correlate succesfully with many of the fuel properties suggests that the degree of refinement or the chemical composition of the fuel is a better predictor of its performance than its resource.

A 1990 Ford Taurus operated on reformulated gasoline was tested under three modes of malfunction: disabled heated exhaust gas oxygen (HEGO) sensor, inactive catalytic converter, and controlled misfire. The vehicle was run for four U.S. EPA UDDS driving schedule (FTP-75) tests at each of the malfunction conditions, as well as under normal operating conditions. An extensive set of emissions data were collected. In addition to the regulated emissions (HC, CO, and NOx), a detailed chemical analysis was carried out to determine the gas- and particle-phase non-regulated emissions. The effect of vehicle malfunction on gas phase emissions was significantly greater than it was on particle phase emissions. For example, CO emissions ranged from 2.57 g/mi (normal operation) to 34.77 g/mi (disable HEGO). Total HCs varied from 0.22 g/mi (normal operation) to 2.21 g/mi (blank catalyst). Emissions of air toxics (1,3-butadiene, benzene, acetaldehyde, and formaldehyde) were also significantly effected.

Recent Federal and California legislation have mandated major improvements in emission control. Tailpipe HC emission must be decreased an order of magnitude for the California Ultra Low Emission Vehicle (ULEV) standard. Present feedback A/F* control systems employ a Heated Exhaust Gas Oxygen sensor (HEGO sensor) upstream of the catalyst to perform A/F feedback control. Limitations on the ultimate accuracy of these switching sensors are well known. To overcome these limitations a linear Universal Exhaust Gas Oxygen sensor (UEGO sensor) placed downstream from the minicatalyst is employed to attain improved A/F control and therefore, higher three-way catalyst (TWC) conversion efficiency. This configuration was granted a patent in 1992 (1**). This study compares performance differences between the two feedback control systems on a Ford Mustang. In initial studies both the UEGO and HEGO sensors were compared at the midposition location downstream of a minicatalyst.

Afterburning of a rich exhaust/air mixture ahead of the catalyst has been shown in earlier papers to offer an effective means of achieving catalyst light-off in very short times. Protection of the catalyst from overheating is an important aspect of systems using EGI, and on board diagnostics will be required to check for proper function of EGI. In this paper, some options for these requirements are discussed, using a high temperature linear thermistor.

A new laboratory test for measuring catalyst oxygen storage capacity has been developed. The test accurately predicts catalyst performance on the vehicle during transient A/F excursions and correlates well with vehicle CO and Nox tailpipe emissions. The test was subsequently used to facilitate improved oxygen storage capacity for new Pd-only washcoat formulations.

This paper provides an overview of the dual EGO sensor method for OBD-II catalyst efficiency monitoring. The processes governing the relationship between catalyst oxygen storage, HC conversion efficiency, and rear EGO sensor response are reviewed in detail. A simple physical model relating catalyst oxygen storage capacity and rear EGO sensor response is constructed and used in conjunction with experimental data to provide additional insight into the operation of the catalyst monitor. The effect that the catalyst washcoat formulation has in determining the relationship between catalyst oxygen storage capacity and HC conversion efficiency and its impact on the catalyst monitor is also investigated. Lastly, the effects of catalyst failure mode, fuel sulfur, and the fuel additive MMT on the catalyst monitor's ability to properly diagnose catalyst function are discussed.

The optimized design of an exhaust emission system in terms of performance, cost, packaging, and engine control strategy will be a key part of competitively meeting future more stringent emission standards. Extensive use of vehicle experiments to evaluate design system tradeoffs is far too time consuming and expensive. Imperative to successfully meeting the challenges of future emission regulations and cost constraints is the development of an exhaust system simulation model which offers the ability to sort through major design alternatives quickly while assisting in the interpretation of experimental data. Previously, detailed catalyst models have been developed which require the specification of intricate kinetic mechanisms to determine overall catalyst performance. While yielding extremely valuable results, these models use complex numerical algorithms to solve multiple partial differential equations which are time consuming and occasionally numerically unstable.

The small-displacement direct-injection (DI) diesel engine is a prime candidate for future transportation needs because of its high thermal efficiency combined with near term production feasibility. Ford Motor Company and FEV Engine Technology, Inc. are working together with the US Department of Energy to develop a small displacement DI diesel engine that meets the key challenges of emissions, NVH, and power density. The targets for the engine are to meet ULEV emission standards while maintaining a best fuel consumption of 200g/kW-hr. The NVH performance goal is transparency with state-of-the-art, four-cylinder gasoline vehicles. Advanced features are required to meet the ambitious targets for this engine. Small-bore combustion systems enable the downsizing of the engine required for high fuel economy with the NVH advantages a four- cylinder has over a three-cylinder engine.

A structural ceramic diesel engine has the potential to provide low heat rejection and significant improvements in fuel economy. Analytical and experimental evaluations were conducted on the critical elements of this engine. The structural ceramic components, which included the cylinder, piston and pin, operated successfully in a single cylinder engine for over 100 hours. The potential for up to 8-11% improvement in indicated specific fuel consumption was projected when corrections for blow-by were applied. The ringless piston with gas squeeze film lubrication avoided the difficulty with liquid lubricants in the high temperature piston/cylinder area. The resulting reduction in friction was projected to provide an additional 15% improvement in brake specific fuel consumption for a multi-cylinder engine at light loads.

The purpose of this paper is to make a preliminary assessment of the potential toxicity of compounds that might be emitted from diesel vehicles using urea/SCR technology. The use of urea as a reductant in the removal of NOx from the exhaust of diesel-powered vehicles has the potential to emit at least seven thermal decomposition products and unreacted urea from the tail-pipe. These compounds include: urea, ammonia, cyanate ion, biuret, cyanuric acid, ammelide, ammeline, and melamine. The toxicity data base for these compounds, in general, is poor. In addition, there have been few, if any, studies examining the inhalation route of exposure - the most likely route of exposure for people from vehicle exhaust. The measurement and identification of these compounds from the exhaust of urea/SCR- equipped vehicles is needed to prioritize the kinds of health effects studies required to understand the toxicity of these compounds.

Various methods are available to predict future cylinder air charge for improved air/fuel control. However, there can never be perfect prediction. This paper presents an algorithm to correct for imperfect cylinder charge prediction. This is done by expanding the air/fuel control boundary to include the catalyst, and correcting prediction errors as soon as possible using small corrective changes to later cylinder fuel inputs. The method was experimentally tested and showed improved air/fuel control as indicated by reduced variability of catalyst downstream air/fuel ratio. Additional vehicle testing showed potential to further reduce emissions.

Two combustion systems were developed and optimized for an engine for a power cylinder of 0.8-0.9L/cylinder. The first design was a re-entrant bowl concept which was based on the combustion system of a smaller engine with roughly 0.5L/cylinder. The second design was a chamfered bowl concept, a variant of a reentrant bowl that deliberately splits fuel between the bowl and the squish region. For each combustion system concept, nozzle tip protrusion, swirl, and nozzle configuration (number of holes, nozzle flow, and spray angle) were optimized. Several similarities between combustion system concepts were noted, including the optimal swirl and number of holes. The resulting optimums for each concept were compared. The chamfered combustion system was found to have better part-load emissions and fuel consumption tradeoffs. Full load performance was similar at low speed between the two combustion systems, but the reentrant combustion system had advantages at high engine speed and load.

Natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics are employed to investigate fuel-property effects on mixing-controlled combustion, using select research fuels-a #2 ultra-low sulfur emissions-certification diesel fuel (CF) and four of the Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8)-that varied in cetane number (CN), distillation characteristics, and aromatic content. The experiments were performed in a single-cylinder heavy-duty optical compression-ignition (CI) engine at two injection pressures, three dilution levels, and constant start-of-combustion timing. If the experimental results are analyzed only in the context of the FACE fuel design parameters, CN had the largest effect on emissions and efficiency.

Future European air quality standards for light duty diesel vehicles will include stringent NOx emission regulations. In order to meet these regulations, a lean NOx catalyst system may be necessary. Since the catalytic removal of NOx is very difficult with the large concentration of oxygen present in diesel exhaust, a reductant is usually added to the exhaust to increase the NOx conversion. This paper describes a lean NOx catalyst system for a Transit light-duty truck which uses a reductant solution of urea in water. In this work, a microprocessor was used to vary the amount of the reductant injected depending on the operating conditions of a 2,5 L naturally aspirated HSDI engine. The NOx conversions were 60% and 80% on the current European driving cycle and the U.S. FTP cycles, respectively. Data on the emissions of HC, CO, NOx, particulate mass and composition, individual HC species, aldehydes, PAH and most HC species were evaluated.

Catalyzed hydrocarbon traps have shown promise in reducing cold-start tailpipe hydrocarbon emissions from gasoline powered vehicles. In this paper, we report the use of catalyzed hydrocarbon trap technology to reduce the non-methane hydrocarbon emissions from a flex-fuel vehicle that can operate on fuel mixtures ranging from pure gasoline to 85% ethanol/15% gasoline. We have found that hydrocarbon traps show a substantially greater reduction in hydrocarbon emissions when used with ethanol fuel than with gasoline. We present laboratory and vehicle test results that show that tailpipe non-methane hydrocarbon emissions from a flex-fuel vehicle can be reduced by 43% when using 85% ethanol/15% gasoline fuel and 16% when using gasoline fuel from a baseline exhaust system using a three-way catalyst. These results were obtained using a catalyzed hydrocarbon trap specifically formulated for use with ethanol fuel.

This paper reports on the development of a new methodology for OBD-II catalyst efficiency monitoring. Temperature measurements taken from the center of the catalyst substrate or near the exterior surface of the catalyst brick were used in conjunction with macroscopic energy balances to calculate the instantaneous rate of exothermic energy generation within the catalyst. The total calculated rate of exothermic energy release over the FTP test cycle was within 10% of the actual or theoretical value and provided a good indicator of catalyst light-off for a variety of aged catalytic converters. Normalization of the rate of exothermic energy release in the front section of the converter by the mass flow rate of air inducted through the engine was found to provide a simple yet practical means of monitoring the converter under both FTP and varying types of road driving.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

Two types of catalysts were tested in a fleet of twenty-four 1969 vehicles, operated in customer-type urban driving regimes, on both leaded and nonleaded fuels over a period of 18 months. The two catalyst types and the converter systems chosen for this evaluation were selected on the basis of information obtained from an earlier test program involving four cars that were durability tested on a more rapid “test track mileage accumulation cycle.” Comparisons are made between the vehicles running rapid mileage accumulation and the vehicles running slower customer-type mileage accumulation. Catalyst life and system performance depreciation were relatively similar in both fleets and did not seem to be significantly affected by the method of mileage accumulation. The 24-vehicle fleet was equipped with a programmed protection system (PPS) designed to protect the catalysts from damage due to over-temperature operation. Problems with this prototype protection system are discussed.

An experimental study of the performance of a reverse tumble, DISI engine is reported. Specific fuel consumption and engine-out emissions have been investigated for both homogeneous and stratified modes of fuel injection. Trends in performance with varying AFR, EGR, spark and injection timings have been explored. It is shown that neural networks can be trained to describe these trends accurately for even the most complex case of stratified charge operation with exhaust gas recirculation.

A series of in-use catalysts having mileage of 22,000 to 43,000 miles was characterized to determine the effect of the fuel additive MMT. The analytical techniques included visual examination, x-ray fluorescence, x-ray diffraction, optical microscopy, scanning electron microscopy, and electron raicroprobe. In addition, catalyst activity was measured and compared to the catalyst activity from a pulsator aged catalyst without the MMT additive in the feed gas composition. Characterization results show a significantly thick layer (5-20 microns) covering the surface of the catalysts which results in the increase of mass transfer resistance. Steady state R and light-off measurements indicated catalyst efficiency is also significantly reduced as exposure to MMT is increased.