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A single cylinder indirect injection diesel engine was used to evaluate the emissions, fuel consumption, and ignition delay of non-petroleum liquid fuels derived from coal, shale, and tar sands. Correlations were made relating fuel properties with exhaust emissions, fuel consumption, and ignition delay. The results of the correlation study showed that the indicated fuel consumption, ignition delay, and CO emissions significantly correlated with the H/C ratio, specific gravity, heat of combustion, aromatics and saturates content, and cetane number, Multiple fuel properties were necessary to correlate the hydrocarbon emissions. The NOx emissions did not correlate well with any fuel property. Because these fuels from various resources were able to correlate succesfully with many of the fuel properties suggests that the degree of refinement or the chemical composition of the fuel is a better predictor of its performance than its resource.

Four vehicle fleets, consisting of 3 to 4 vehicles each, were emission tested on a 48″ roll chassis dynamometer using both the FTP urban dynamometer driving cycle and the REP05 driving cycle. The REP05 cycle was developed to test vehicles under high speed and high load conditions not included in the FTP. The vehicle fleets consisted of 1989 light-duty gasoline vehicles, 1992-93 limited production FFV/VFV methanol vehicles, 1992-93 compressed natural gas (CNG) vehicles and their gasoline counterparts, and a 1992 production and two prototype ethanol FFV/VFV vehicles. All vehicles (except the dedicated CNG vehicles) were tested using Auto/Oil AQIRP fuels A and C2. Other fuels used were M85 blended from A and C2, E85 blended from C1, which is similar to C2 but without MTBE, and four CNG fuels representing the range of in-use CNG fuels. In addition to bag measurements, tailpipe exhaust concentration and A/F data were collected once per second throughout every test.

The purpose of this paper is to make a preliminary assessment of the potential toxicity of compounds that might be emitted from diesel vehicles using urea/SCR technology. The use of urea as a reductant in the removal of NOx from the exhaust of diesel-powered vehicles has the potential to emit at least seven thermal decomposition products and unreacted urea from the tail-pipe. These compounds include: urea, ammonia, cyanate ion, biuret, cyanuric acid, ammelide, ammeline, and melamine. The toxicity data base for these compounds, in general, is poor. In addition, there have been few, if any, studies examining the inhalation route of exposure - the most likely route of exposure for people from vehicle exhaust. The measurement and identification of these compounds from the exhaust of urea/SCR- equipped vehicles is needed to prioritize the kinds of health effects studies required to understand the toxicity of these compounds.

Natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics are employed to investigate fuel-property effects on mixing-controlled combustion, using select research fuels-a #2 ultra-low sulfur emissions-certification diesel fuel (CF) and four of the Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8)-that varied in cetane number (CN), distillation characteristics, and aromatic content. The experiments were performed in a single-cylinder heavy-duty optical compression-ignition (CI) engine at two injection pressures, three dilution levels, and constant start-of-combustion timing. If the experimental results are analyzed only in the context of the FACE fuel design parameters, CN had the largest effect on emissions and efficiency.

Future European air quality standards for light duty diesel vehicles will include stringent NOx emission regulations. In order to meet these regulations, a lean NOx catalyst system may be necessary. Since the catalytic removal of NOx is very difficult with the large concentration of oxygen present in diesel exhaust, a reductant is usually added to the exhaust to increase the NOx conversion. This paper describes a lean NOx catalyst system for a Transit light-duty truck which uses a reductant solution of urea in water. In this work, a microprocessor was used to vary the amount of the reductant injected depending on the operating conditions of a 2,5 L naturally aspirated HSDI engine. The NOx conversions were 60% and 80% on the current European driving cycle and the U.S. FTP cycles, respectively. Data on the emissions of HC, CO, NOx, particulate mass and composition, individual HC species, aldehydes, PAH and most HC species were evaluated.

Catalyzed hydrocarbon traps have shown promise in reducing cold-start tailpipe hydrocarbon emissions from gasoline powered vehicles. In this paper, we report the use of catalyzed hydrocarbon trap technology to reduce the non-methane hydrocarbon emissions from a flex-fuel vehicle that can operate on fuel mixtures ranging from pure gasoline to 85% ethanol/15% gasoline. We have found that hydrocarbon traps show a substantially greater reduction in hydrocarbon emissions when used with ethanol fuel than with gasoline. We present laboratory and vehicle test results that show that tailpipe non-methane hydrocarbon emissions from a flex-fuel vehicle can be reduced by 43% when using 85% ethanol/15% gasoline fuel and 16% when using gasoline fuel from a baseline exhaust system using a three-way catalyst. These results were obtained using a catalyzed hydrocarbon trap specifically formulated for use with ethanol fuel.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

The study investigated the characteristics of the combustion, the emissions and the thermal efficiency of a direct injection diesel engine fuelled with neat n-butanol. Engine tests were conducted on a single cylinder four-stroke direct injection diesel engine. The engine ran at 6.5 bar IMEP and 1500 rpm engine speed. The intake pressure was boosted to 1.0 bar (gauge), and the injection pressure was controlled at 60 or 90 MPa. The injection timing and the exhaust gas recirculation (EGR) rate were adjusted to investigate the engine performance. The effect of the engine load on the engine performance was also investigated. The test results showed that the n-butanol fuel had significantly longer ignition delay than that of diesel fuel. n-Butanol generally led to a rapid heat release pattern in a short period, which resulted in an excessively high pressure rise rate. The pressure rise rate could be moderated by retarding the injection timing and lowering the injection pressure.

Three techniques for the measurement of the oxides of nitrogen in automotive exhaust were evaluated. These included a “nitrous fume” analyzer, a gaseous NO2 colorimeter, and a movable mass spectrometer. All data obtained were compared to data from currently accepted wet chemical methods, the phenoldisulfonic acid and the “modified” Saltzman. Of the techniques evaluated, the mass spectrometer analysis of NO has been found to be the most useful for the study of nitrogen oxides in engine exhaust. The high cost of wet chemical analysis has indicated a need for an improved and continuous analytical method. The mass spectrometer approach measures NO within seconds of its discharge, thus minimizing any reactions prior to measurement.

Urea-selective catalytic reduction (SCR) after-treatment systems are used for reducing oxides of nitrogen (NOx) emissions in medium and heavy duty diesel vehicles. This paper addresses control-oriented modeling, starting from first-principles, of SCR after-treatment systems. Appropriate simplifications are made to yield governing equations of the Urea-SCR. The resulting nonlinear partial differential equations (PDEs) are discretized and linearized to yield a family of linear finite-dimensional state-space models of the SCR at different operating points. It is further shown that this family of models can be reduced to three operating regions. Within each region, parametric dependencies of the system on physical mechanisms are derived. Further model reduction is shown to be possible in each of the three regions resulting in a second-order linear model with sufficient accuracy.

During the 1980s, the U.S. Environmental Protection Agency (EPA) incorporated the R factor into fuel economy calculations in order to address concerns about the impacts of test fuel property variations on corporate average fuel economy (CAFE) compliance, which is determined using the Federal Test Procedure (FTP) and Highway Fuel Economy Test (HFET) cycles. The R factor is defined as the ratio of the percent change in fuel economy to the percent change in volumetric heating value for tests conducted using two differing fuels. At the time the R-factor was devised, tests using representative vehicles initially indicated that an appropriate value for the R factor was 0.6. Reassessing the R factor has recently come under renewed interest after EPA's March 2013 proposal to adjust the properties of certification gasoline to contain significant amounts of ethanol.

Homogeneous-charge compression-ignition (HCCI) technology has high potential to significantly reduce fuel consumption and NOx emissions over PFI engines. Control of the HCCI combustion process over the full range of conventional PFI operating conditions, however, has been a challenge. This study describes an HCCI-SI dual-mode engine system proposal based on new approaches to optimize the engine performance. A 0.658L single-cylinder engine was built and tested using these concepts. The engine was operated in HCCI mode from idle to 5.5 bar NMEP and up to 4750 rpm. NSFC in HCCI mode was about 175 g/kWh over most of the operating range except at very low load or near the high load boundary. At a part load of 1500 rpm and an equivalent BMEP of 2.62 bar, net indicated fuel efficiency was 50% higher than PFI engines and 30% higher than a prototype SC-DISI engine.

In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.

Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This work concentrates on establishing the CAI operating range with regard to Air/Fuel ratio and Exhaust Gas Re-circulation and their effect on the ignition timing, combustion rate and variability, Indicated thermal efficiency, and engine-out emissions such as NOx. Detailed maps are presented, defining how each of the measured variables changes over the entire CAI region. Results indicate that the alcohols have significantly higher tolerance to dilution than the hydrocarbon fuels tested. Also, variations in Gasoline blend have little effect on any of the combustion parameters measured.

A fuel cell is an electrochemical engine which converts fuel and oxidant electrochemically into water, other chemical products and electricity. At present, depending on the electrolytic conducting media, five fuel cell types are recognized, the alkaline fuel cell (AFC), the proton exchange membrane fuel cell (PEMFC), the phosphoric acid fuel cell (PAFC), the molten carbonate fuel cell (MCFC), and the solid oxide fuel cell (SOFC). Various types of hydrogen containing fuels can be used in any of the fuel cells, however only the hydrogen-air fueled fuel cell operating at low to medium temperatures (0-450 C) can be considered to meet the zero emission vehicle (ZEV) requirements. Byproducts of the electrochemical reaction of the fuel cells when hydrocarbons and air are used include carbon monoxide, carbon dioxide and at higher temperatures nitrogen oxide.

Procedures are described for rapidly aging and for testing three-way catalysts on an engine dynamometer which are relatable to actual vehicle aging and CVS testing. The accelerated aging cycle consists of a modification of the AMA durability driving cycle; testing consists of the measurement of HC, CO and NOx conversion as a function of A/F with superimposed perturbations which simulate limit cycle variations of A/F in a closed-loop fuel control system.

This paper presents engine dynamometer testing and modeling analysis of ethanol compared to gasoline at part load conditions where the engine was not knock-limited with either fuel. The purpose of this work was to confirm the efficiency improvement for ethanol reported in published papers, and to quantify the components of the improvement. Testing comparing E85 to E0 gasoline was conducted in an alternating back-to-back manner with multiple data points for each fuel to establish high confidence in the measured results. Approximately 4% relative improvement in brake thermal efficiency (BTE) was measured at three speed-load points. Effects on BTE due to pumping work and emissions were quantified based on the measured engine data, and accounted for only a small portion of the difference.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.

Engine dynamometer testing was performed comparing fuels having different octane ratings and ethanol content in a Ford 3.5L direct injection turbocharged (EcoBoost) engine at three compression ratios (CRs). The fuels included midlevel ethanol “splash blend” and “octane-matched blend” fuels, E10-98RON (U.S. premium), and E85-108RON. For the splash blends, denatured ethanol was added to E10-91RON, which resulted in E20-96RON and E30-101 RON. For the octane-matched blends, gasoline blendstocks were formulated to maintain constant RON and MON for E10, E20, and E30. The match blend E20-91RON and E30-91RON showed no knock benefit compared to the baseline E10-91RON fuel. However, the splash blend E20-96RON and E10-98RON enabled 11.9:1 CR with similar knock performance to E10-91RON at 10:1 CR. The splash blend E30-101RON enabled 13:1 CR with better knock performance than E10-91RON at 10:1 CR. As expected, E85-108RON exhibited dramatically better knock performance than E30-101RON.