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Technical Paper

50,000 Mile Vehicle Road Test of Three-Way and NOx Reduction Catalyst Systems

1978-02-01
780608
The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).
Journal Article

A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine

2012-09-10
2012-01-1695
Two oxygenated fuels were evaluated on a single-cylinder diesel engine and compared to three hydrocarbon diesel fuels. The oxygenated fuels included canola biodiesel (canola methyl esters, CME) and CME blended with dibutyl succinate (DBS), both of which are or have the potential to be bio-derived. DBS was added to improve the cold flow properties, but also reduced the cetane number and net heating value of the resulting blend. A 60-40 blend of the two (60% vol CME and 40% vol DBS) provided desirable cold flow benefits while staying above the U.S. minimum cetane number requirement. Contrary to prior vehicle test results and numerous literature reports, single-cylinder engine testing of both CME and the 60-40 blend showed no statistically discernable change in NOx emissions relative to diesel fuel, but only when constant intake oxygen was maintained.
Technical Paper

A Comparison of the Effect of E85 vs. Gasoline on Exhaust System Surface Temperatures

2007-04-16
2007-01-1392
With concerns over increasing worldwide demand for gasoline and greenhouse gases, many automotive companies are increasing their product lineup of vehicles to include flex-fuel vehicles that are capable of operating on fuel blends ranging from 100% gasoline up to a blend of 15% gasoline/85% ethanol (E85). For the purpose of this paper, data was obtained that will enable an evaluation relating to the effect the use of E85 fuel has on exhaust system surface temperatures compared to that of regular unleaded gasoline while the vehicle undergoes a typical drive cycle. Three vehicles from three different automotive manufacturers were tested. The surface of the exhaust systems was instrumented with thermocouples at specific locations to monitor temperatures from the manifold to the catalytic converter outlet. The exhaust system surface temperatures were recorded during an operation cycle that included steady vehicle speed operation; cold start and idle and wide open throttle conditions.
Technical Paper

A Diesel Lean Nox Trap Model for Control Strategy Verification

2004-03-08
2004-01-0526
Lean NOx traps are considered as a possible means to reduce diesel powertrain tail pipe NOx emissions to future stringent limits. Several publications have proposed models for lean NOx traps [1, 2, 3 and 4]. This paper focuses on a lean NOx trap model that can be used for the verification of control strategies before these strategies are implemented in target microprocessors. Strategy verification in a simulation environment is a crucial tool for reducing control strategy development and implementation time.
Technical Paper

A LNT+SCR System for Treating the NOx Emissions from a Diesel Engine

2006-04-03
2006-01-0210
An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.
Technical Paper

A Methodology of Real-World Fuel Consumption Estimation: Part 1. Drive Cycles

2018-04-03
2018-01-0644
To assess the fuel consumption of vehicles, three sets of input data are required; drive cycles, vehicle parameters, and environmental conditions. As the first part of a series of studies on real-world fuel consumption, this study focuses on the drive cycles. In principle, drive cycles should represent real-world usage. Some of them aim at a specific usage such as a city driving condition or an aggressive driving style. However, the definition of city or aggressive driving is very subjective and difficult to quantitatively correlate with the real-world usage. This study proposes a methodology to quantify the speed and dynamics of drive cycles, or vehicle speed traces in general, against the real-world usage. After reviewing parameter sets found in other studies, relative cubic speed (RCS) and positive kinetic energy (PKE) are selected to represent the speed and dynamics through energy flow balance at the wheels.
Technical Paper

A Modeling Analysis of Fibrous Media for Gasoline Particulate Filters

2017-03-28
2017-01-0967
With an emerging need for gasoline particulate filters (GPFs) to lower particle emissions from gasoline direct injection (GDI) engines, studies are being conducted to optimize GPF designs in order to balance filtration efficiency, backpressure penalty, filter size, cost and other factors. Metal fiber filters could offer additional designs to the GPF portfolio, which is currently dominated by ceramic wall-flow filters. However, knowledge on their performance as GPFs is still limited. In this study, modeling on backpressure and filtration efficiency of fibrous media was carried out to determine the basic design criteria (filtration area, filter thickness and size) for different target efficiencies and backpressures at given gas flow conditions. Filter media with different fiber sizes (8 - 17 μm) and porosities (80% - 95%) were evaluated using modeling to determine the influence of fiber size and porosity.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Journal Article

A Novel Technique for Measuring Cycle-Resolved Cold Start Emissions Applied to a Gasoline Turbocharged Direct Injection Engine

2020-04-14
2020-01-0312
There is keen interest in understanding the origins of engine-out unburned hydrocarbons emitted during SI engine cold start. This is especially true for the first few firing cycles, which can contribute disproportionately to the total emissions measured over standard drive cycles such as the US Federal Test Procedure (FTP). This study reports on the development of a novel methodology for capturing and quantifying unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start. The method was demonstrated by applying it to a 4 cylinder 2 liter GTDI (Gasoline Turbocharged Direct Injection) engine for cold start conditions at an ambient temperature of 22°C. For this technique, the entirety of the engine exhaust gas was captured for a predetermined number of firing cycles.
Technical Paper

A Phenomenological Control Oriented Lean NOx Trap Model

2003-03-03
2003-01-1164
Lean NOx Trap (LNT) is an aftertreatment device typically used to reduce oxides of nitrogen (NOx) emissions for a lean burn engine. NOx is stored in the LNT during the lean operation of an engine. When the air-fuel ratio becomes rich, the stored NOx is released and catalytically reduced by the reductants such as CO, H2 and HC. Tailpipe NOx emissions can be significantly reduced by properly modulating the lean (storage) and rich (purge) periods. A control-oriented lumped parameter model is presented in this paper. The model captures the key steady state and transient characteristics of an LNT and includes the effects of the important engine operating parameters. The model can be used for system performance evaluation and control strategy development.
Technical Paper

A Simplified Method to Make Temperature Measurements of a Metal Surface using the Surface as One Component of Thermocouple

2008-04-14
2008-01-0918
Instrumentation of an exhaust system to measure surface temperature at multiple locations usually involves welding independent thermocouples to the surface of the system. This report describes a new type of thermocouple fabricated to measure temperature at a point or temperature difference between points on a metallic object utilizing the metal as one component of the new thermocouple. AISI 316 stainless steel is used in the current study to represent automotive exhaust pipe. The other component of the thermocouple is Nickel-Chromium (Chromel, Chromega), one of the two metals used in type K thermocouples, which are generally used for exhaust temperature measurements during emission tests. Use of the new thermocouple is contingent upon an accurate calibration of its response to changes in temperature.
Technical Paper

A View of Flexible Fuel Vehicle Aldehyde Emissions

1988-08-01
881200
The aldehyde emissions of 1.6L and 5.0L flexible fuel vehicles (FFV) have been measured, with and without a catalyst, on a range of fuels. The “zero mile” catalyzed emission levels of formaldehyde when operating on M85 (85% methanol and 15% gasoline) are in the 5-15 mg/mi range, but as mileage accumulates they tend to be in the 30-50 mg/mi range. The feedgas levels are high and appear to correlate with engine displacement. The formaldehyde and methanol emissions are higher when operating on M100, compared to M85, but the non-oxygenated hydrocarbon emissions are about the same for both fuels, which suggests that the use of M85 may actually provide more air quality benefit than M100. High mileage control of aldehydes to the level of gasoline vehicles does not appear possible with current technology.
Technical Paper

Adaptive Temperature Control for Diesel Particulate Filter Regeneration

2013-04-08
2013-01-0517
The regeneration process of a Diesel Particulate Filter (DPF) consists of an increase in the engine exhaust gas temperature by using post injections and/or exhaust fuel injection during a period of time in order to burn previously trapped soot. The DPF regeneration is usually performed during a real drive cycle, with continuously changing driving conditions. The quantity of post injection/exhaust fuel to use for regeneration is calculated using a combination of an open loop term based on engine speed, load and exhaust gas flow and a closed loop term based on an exhaust gas temperature target and the feedback from a number of sensors. Due to the nature of the system and the slow response of the closed loop term for correcting large deviations, the authority of the fuel calculation is strongly biased to the open loop. However, the open loop fuel calculation might not be accurate enough to provide adequate temperature tracking due to several disturbances in the system.
Technical Paper

Advanced Predictive Diesel Combustion Simulation Using Turbulence Model and Stochastic Reactor Model

2017-03-28
2017-01-0516
Today numerical models are a major part of the diesel engine development. They are applied during several stages of the development process to perform extensive parameter studies and to investigate flow and combustion phenomena in detail. The models are divided by complexity and computational costs since one has to decide what the best choice for the task is. 0D models are suitable for problems with large parameter spaces and multiple operating points, e.g. engine map simulation and parameter sweeps. Therefore, it is necessary to incorporate physical models to improve the predictive capability of these models. This work focuses on turbulence and mixing modeling within a 0D direct injection stochastic reactor model. The model is based on a probability density function approach and incorporates submodels for direct fuel injection, vaporization, heat transfer, turbulent mixing and detailed chemistry.
Journal Article

Advancements and Opportunities for On-Board 700 Bar Compressed Hydrogen Tanks in the Progression Towards the Commercialization of Fuel Cell Vehicles

2017-03-28
2017-01-1183
Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.
Technical Paper

Air-Fuel Ratio Dependence of Random and Deterministic Cyclic Variability in a Spark-Ignited Engine

1999-10-25
1999-01-3513
One important design goal for spark-ignited engines is to minimize cyclic variability. A small amount of cyclic variability (slow burns) can produce undesirable engine vibrations. A larger amount of cyclic variability (incomplete burns) leads to increased hydrocarbon consumption/emissions. Recent studies have reported deterministic patterns in cyclic variability under extremely lean (misfiring) operating conditions. The present work is directed toward more realistic non-misfiring conditions. Production engine test results suggest that deterministic patterns in cyclic variability are the consequence of incomplete combustion, hence control algorithms based on the occurrence of these patterns are not expected to be of significant practical value.
Journal Article

An EGR Cooler Fouling Model: Experimental Correlation and Model Uses

2017-03-28
2017-01-0535
Thermal effectiveness of Exhaust Gas Recirculation (EGR) coolers used in diesel engines can progressively decrease and stabilize over time due to inner fouling layer of the cooler tubes. Thermophoretic force has been identified as the major cause of diesel exhaust soot fouling, and models are proposed in the literature but improvements in simulation are needed especially for the long-term trend of soot deposition. To describe the fouling stabilization behavior, a removal mechanism is required to account for stabilization of the soot layer. Observations from previous experiments on surrogate circular tubes suggest there are three primary factors to determine removal mechanisms: surface temperature, thickness, and shear velocity. Based on this hypothesis, we developed a 1D CFD fouling model for predicting the thermal effectiveness reduction of real EGR coolers. The model includes the two competing mechanisms mentioned that results in fouling balance.
Technical Paper

An Experimental Investigation of Spray Transfer Processes in an Electrostatic Rotating Bell Applicator

1998-09-29
982290
A better understanding is needed of the electrostatic rotating bell (ESRB) application of metallic basecoat paint to automobile exteriors in order to exploit their high transfer efficiency without compromising the coating quality. This paper presents the initial results from experimental investigation of sprays from an ESRB which is designed to apply water-borne paint. Water was used as paint surrogate for simplicity. The atomization and transport regions of the spray were investigated using laser light sheet visualizations and phase Doppler particle analyzer (PDPA). The experiments were conducted at varying levels of the three important operating parameters: liquid flow rate, shaping-air flow rate, and bellcup rotational speed. The results show that bellcup speed dominates atomization, but liquid and shaping-air flow rate settings significantly influence the spray structure. The visualization images showed that the atomization occurs in ligament breakup regime.
Technical Paper

An Experimental Procedure for Simulating an SC03 Emissions Test with Air Conditioner On

2004-03-08
2004-01-0594
In a continuing effort to include real-world emissions in regulatory testing, the USEPA has included air conditioning operation as part of the Supplemental Federal Test Procedure (SFTP). Known as the SC03, these tests require automobile manufacturers to construct and maintain expensive environmental chambers. However, the regulations make allowances for a simulation test, if one can be shown to demonstrate correlation with the SFTP results. We present the results from an experiment on a 1998 Ford sedan, which simulates the heat load of a full environmental chamber. Moreover, the test procedure is simpler and more cost effective. The process essentially involves heating the condenser of the air conditioning system by using the heat of the engine, rather than heating the entire vehicle. The results indicate that if the head pressure is used as a feedback signal to the radiator fan, the load generated by a full environmental chamber can be duplicated.
Technical Paper

An Investigation of EGR Treatment on the Emission and Operating Characteristics of Modern Diesel Engines

2007-04-16
2007-01-1083
Tests are conducted to improve the use of exhaust gas recirculation on a single cylinder diesel engine with EGR stream treatment techniques that include intake heating, combustible substance oxidation, catalytic fuel reforming, and partial bypass-flow control. In parallel with the empirical work, theoretical modeling analyses are performed to investigate the effectiveness of the reforming process and the combined effects on the overall system efficiency. The research is aimed at stabilizing and expanding the limits of heavy EGR during steady and transient operations so that the individual limiting conditions of EGR can be better identified. Additionally, the heavy EGR is applied to enable in-cylinder low temperature combustion. The effectiveness of EGR treatment on engine emission and operating characteristics are therefore reported.
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