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Technical Paper

50,000 Mile Vehicle Road Test of Three-Way and NOx Reduction Catalyst Systems

1978-02-01
780608
The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).
Technical Paper

A Comparison of Four Methods for Determining the Octane Index and K on a Modern Engine with Upstream, Port or Direct Injection

2017-03-28
2017-01-0666
Combustion in modern spark-ignition (SI) engines is increasingly knock-limited with the wide adoption of downsizing and turbocharging technologies. Fuel autoignition conditions are different in these engines compared to the standard Research Octane Number (RON) and Motor Octane Numbers (MON) tests. The Octane Index, OI = RON - K(RON-MON), has been proposed as a means to characterize the actual fuel anti-knock performance in modern engines. The K-factor, by definition equal to 0 and 1 for the RON and MON tests respectively, is intended to characterize the deviation of modern engine operation from these standard octane tests. Accurate knowledge of K is of central importance to the OI model; however, a single method for determining K has not been well accepted in the literature.
Technical Paper

A Comparison of the Effect of E85 vs. Gasoline on Exhaust System Surface Temperatures

2007-04-16
2007-01-1392
With concerns over increasing worldwide demand for gasoline and greenhouse gases, many automotive companies are increasing their product lineup of vehicles to include flex-fuel vehicles that are capable of operating on fuel blends ranging from 100% gasoline up to a blend of 15% gasoline/85% ethanol (E85). For the purpose of this paper, data was obtained that will enable an evaluation relating to the effect the use of E85 fuel has on exhaust system surface temperatures compared to that of regular unleaded gasoline while the vehicle undergoes a typical drive cycle. Three vehicles from three different automotive manufacturers were tested. The surface of the exhaust systems was instrumented with thermocouples at specific locations to monitor temperatures from the manifold to the catalytic converter outlet. The exhaust system surface temperatures were recorded during an operation cycle that included steady vehicle speed operation; cold start and idle and wide open throttle conditions.
Technical Paper

A Diesel Lean Nox Trap Model for Control Strategy Verification

2004-03-08
2004-01-0526
Lean NOx traps are considered as a possible means to reduce diesel powertrain tail pipe NOx emissions to future stringent limits. Several publications have proposed models for lean NOx traps [1, 2, 3 and 4]. This paper focuses on a lean NOx trap model that can be used for the verification of control strategies before these strategies are implemented in target microprocessors. Strategy verification in a simulation environment is a crucial tool for reducing control strategy development and implementation time.
Technical Paper

A LNT+SCR System for Treating the NOx Emissions from a Diesel Engine

2006-04-03
2006-01-0210
An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.
Technical Paper

A Modeling Analysis of Fibrous Media for Gasoline Particulate Filters

2017-03-28
2017-01-0967
With an emerging need for gasoline particulate filters (GPFs) to lower particle emissions from gasoline direct injection (GDI) engines, studies are being conducted to optimize GPF designs in order to balance filtration efficiency, backpressure penalty, filter size, cost and other factors. Metal fiber filters could offer additional designs to the GPF portfolio, which is currently dominated by ceramic wall-flow filters. However, knowledge on their performance as GPFs is still limited. In this study, modeling on backpressure and filtration efficiency of fibrous media was carried out to determine the basic design criteria (filtration area, filter thickness and size) for different target efficiencies and backpressures at given gas flow conditions. Filter media with different fiber sizes (8 - 17 μm) and porosities (80% - 95%) were evaluated using modeling to determine the influence of fiber size and porosity.
Technical Paper

A NOx Reduction Solution for Retrofit Applications: A Simple Urea SCR Technology

2005-04-11
2005-01-1857
This paper presents the development and performance of a Selective Catalytic Reduction (SCR) aftertreatment system designed for diesel retrofit applications. It has been proven that Urea SCR represents a convenient and very efficient solution for NOx reduction that can be used for stationary and mobile powerplants with NOx reduction efficiencies that can exceed 95%. The cooperative efforts between ServoTech Engineering, Ford Motor Company, KleenAir Systems, Tenneco, and the City of Dearborn have led to the development of a simple aftertreatment system for NOx reduction. This system consists of a catalyzed diesel particulate filter (CDPF), a SCR catalyst system, and a diesel oxidation catalyst. As part of the system, an effective and compact air-assisted dosing unit developed by ServoTech Engineering in collaboration with Ford Motor Company was used for effective urea delivery and atomization.
Technical Paper

A New Approach of Accelerated Life Testing for Metallic Catalytic Converters

2004-03-08
2004-01-0595
The Environmental Protection Agency (EPA) and California Air Resources Board (CARB) requirements for high mileage durability of emission components make it necessary to ensure the mechanical robustness of metallic catalytic converters. In addition, the robustness of design features must be assessed in the early design development phase without resorting to vehicle fleet testing. By following established reliability methods, a new approach for time and cost efficient accelerated durability testing was developed, which can account for the combined effects of critical stressors of a metallic catalytic converter. This paper describes the methodology used to determine the critical stressors and their levels in actual operating conditions which were determined by analyzing a broad range of vehicle test information. This information was used to develop a temperature profile and a high vibration load profile for the new life test method.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Technical Paper

A Phenomenological Control Oriented Lean NOx Trap Model

2003-03-03
2003-01-1164
Lean NOx Trap (LNT) is an aftertreatment device typically used to reduce oxides of nitrogen (NOx) emissions for a lean burn engine. NOx is stored in the LNT during the lean operation of an engine. When the air-fuel ratio becomes rich, the stored NOx is released and catalytically reduced by the reductants such as CO, H2 and HC. Tailpipe NOx emissions can be significantly reduced by properly modulating the lean (storage) and rich (purge) periods. A control-oriented lumped parameter model is presented in this paper. The model captures the key steady state and transient characteristics of an LNT and includes the effects of the important engine operating parameters. The model can be used for system performance evaluation and control strategy development.
Technical Paper

A Simplified Method to Make Temperature Measurements of a Metal Surface using the Surface as One Component of Thermocouple

2008-04-14
2008-01-0918
Instrumentation of an exhaust system to measure surface temperature at multiple locations usually involves welding independent thermocouples to the surface of the system. This report describes a new type of thermocouple fabricated to measure temperature at a point or temperature difference between points on a metallic object utilizing the metal as one component of the new thermocouple. AISI 316 stainless steel is used in the current study to represent automotive exhaust pipe. The other component of the thermocouple is Nickel-Chromium (Chromel, Chromega), one of the two metals used in type K thermocouples, which are generally used for exhaust temperature measurements during emission tests. Use of the new thermocouple is contingent upon an accurate calibration of its response to changes in temperature.
Technical Paper

A Study on Charge Motion Requirements for a Class-Leading GTDI Engine

2017-09-04
2017-24-0065
An integral part of combustion system development for previous NA gasoline engines was the optimization of charge motion towards the best compromise in terms of full load performance, part load stability, emissions and, last but not least, fuel economy. This optimum balance may potentially be different in GTDI engines. While it is generally accepted that an increased charge motion level improves the mixture preparation in direct injection gasoline engines, the tradeoff in terms of performance seems to become less dominant as the boosting systems of modern engines are typically capable enough to compensate the flow losses generated by the more restrictive ports. Nevertheless, the increased boost level does not come free; increased charge motion generates higher pumping- and wall heat losses. Hence it is questionable and engine dependent, whether more charge motion is always better.
Technical Paper

A Thermoviscoplastic FE Model for the Strain Prediction in High Temperature, Thermal Cycling Applications for Silicon Molybdenum Nodular Cast Iron

1998-02-23
980697
The design of components for high temperature, thermal cycling situations has traditionally been a challenging problem because the analysis must compensate for the non-linear behavior of the material. One example for automotive applications is the exhaust manifold, where temperatures may reach 900°C during thermal cycling. Fatigue failure and excessive deformation of these components must be analyzed with thermoviscoplastic models. A Finite Element (FE) model is developed to simulate the material behavior at high temperature, thermal cycling conditions. A specimen of Silicon Molybdenum Nodular Cast Iron (4% Si, 0.8% Mo) is cycled between maximum temperatures of 500°C and 960°C while the stress is measured with respect to time. The model predictions for stress are compared to the experimental results for two rates of thermal cycling. The analysis is conducted with and without creep effects to understand its contribution to the overall strain.
Technical Paper

A View of Flexible Fuel Vehicle Aldehyde Emissions

1988-08-01
881200
The aldehyde emissions of 1.6L and 5.0L flexible fuel vehicles (FFV) have been measured, with and without a catalyst, on a range of fuels. The “zero mile” catalyzed emission levels of formaldehyde when operating on M85 (85% methanol and 15% gasoline) are in the 5-15 mg/mi range, but as mileage accumulates they tend to be in the 30-50 mg/mi range. The feedgas levels are high and appear to correlate with engine displacement. The formaldehyde and methanol emissions are higher when operating on M100, compared to M85, but the non-oxygenated hydrocarbon emissions are about the same for both fuels, which suggests that the use of M85 may actually provide more air quality benefit than M100. High mileage control of aldehydes to the level of gasoline vehicles does not appear possible with current technology.
Technical Paper

Acoustic Characteristics of Automotive Catalytic Converter Assemblies

2004-03-08
2004-01-1002
An experimental study of the acoustic characteristics of automotive catalytic converters is presented. The investigation addresses the effects and relative importance of the elements comprising a production catalytic converter assembly including the housing, substrate, mat and seals. Attenuation characteristics are measured for one circular and one oval catalytic converter geometry, each having 400 cell per square inch substrates. For each geometry, experimental results are presented to address the effect of individual components in isolation, and in combination with other assembly components. Additional experiments investigate the significance of acoustic paths around the substrate and through the peripheral wall of the substrate. The experimental results are compared to address the significance of each component on the overall attenuation.
Technical Paper

Adaptive Temperature Control for Diesel Particulate Filter Regeneration

2013-04-08
2013-01-0517
The regeneration process of a Diesel Particulate Filter (DPF) consists of an increase in the engine exhaust gas temperature by using post injections and/or exhaust fuel injection during a period of time in order to burn previously trapped soot. The DPF regeneration is usually performed during a real drive cycle, with continuously changing driving conditions. The quantity of post injection/exhaust fuel to use for regeneration is calculated using a combination of an open loop term based on engine speed, load and exhaust gas flow and a closed loop term based on an exhaust gas temperature target and the feedback from a number of sensors. Due to the nature of the system and the slow response of the closed loop term for correcting large deviations, the authority of the fuel calculation is strongly biased to the open loop. However, the open loop fuel calculation might not be accurate enough to provide adequate temperature tracking due to several disturbances in the system.
Journal Article

Advancements and Opportunities for On-Board 700 Bar Compressed Hydrogen Tanks in the Progression Towards the Commercialization of Fuel Cell Vehicles

2017-03-28
2017-01-1183
Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.
Technical Paper

An Adaptive Delay-Compensated PID Air Fuel Ratio Controller

2007-04-16
2007-01-1342
In this work, a discrete,time-based, delay-compensated, adaptive PID control algorithm for air fuel ratio control in an SI engine is presented. The controller operates using feedback from a wide-ranging Universal Exhaust Gas Oxygen (UEGO) sensor situated in the exhaust manifold. Time delay compensation is used to address the difficulties traditionally associated with the relatively long and time-varying time delay in the gas transport process and UEGO sensor response. The delay compensation is performed by computing a correction to the current control move based on the current delay and the corresponding values of the past control moves. The current delay is determined from the measured engine speed and load using a two dimensional map. In order to achieve good servo operation during target changes without compromising regulator performance a two degree of freedom controller design has been developed by adding a pre-filter to the air fuel ratio target.
Technical Paper

An Experimental Study of the Spray Characteristics of Pressure-Swirl Atomizers for DISI Combustion Systems

2001-05-07
2001-01-1974
This paper presents results from a comprehensive experimental study of high-pressure pressure-swirl gasoline injectors tested under a range of simulated operating conditions. This study encompassed photographic analysis of single spray sequences and simultaneous measurement of axial velocity, radial velocity and diameter at point locations using the phase-doppler technique. The combination of these measurement techniques permitted an insight into the fluid dynamics of the injected spray and its development with time. Five primary stages in the spray-history were identified and numerated with experimental data.
Journal Article

An Overview of the Effects of Ethanol-Gasoline Blends on SI Engine Performance, Fuel Efficiency, and Emissions

2013-04-08
2013-01-1635
This paper provides an overview of the effects of blending ethanol with gasoline for use in spark ignition engines. The overview is written from the perspective of considering a future ethanol-gasoline blend for use in vehicles that have been designed to accommodate such a fuel. Therefore discussion of the effects of ethanol-gasoline blends on older legacy vehicles is not included. As background, highlights of future emissions regulations are discussed. The effects on fuel properties of blending ethanol and gasoline are described. The substantial increase in knock resistance and full load performance associated with the addition of ethanol to gasoline is illustrated with example data. Aspects of fuel efficiency enabled by increased ethanol content are reviewed, including downsizing and downspeeding opportunities, increased compression ratio, fundamental effects associated with ethanol combustion, and reduced enrichment requirement at high speed/high load conditions.
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