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The Major Constituent Analyzer (MCA) is a mass spectrometer-based atmospheric monitoring instrument in the Laboratory Module of the International Space Station (ISS). The MCA is used for continuous environmental monitoring of 6 major gas constituents in the ISS atmosphere as well as safety-critical monitoring for special Environmental Control and Life Support (ECLS) operations such as Pre-Breathe in the Airlock for Extra-Vehicular Activities (EVAs) and oxygen re-pressurizations. For the latter, it is desirable to make most efficient use of consumables by transferring the maximum amount from O2 re-supply tanks on board the shuttle or Progress. The upper safety limit for O2 transfer is constrained by the MCA measurement error bands. A study was undertaken to tighten these error bands and afford NASA-Mission Operations Directorate (MOD) more operational flexibility.

Increased nickel concentrations in the IATCS coolant prompted a study of the corrosion rates of nickel-brazed heat exchangers in the system. The testing has shown that corrosion is occurring in a silicon-rich intermetallic phase in the braze filler of coldplates and heat exchangers as the result of a decrease in the coolant pH brought about by cabin carbon dioxide permeation through polymeric flexhoses. Similar corrosion is occurring in the EMU de-ionized water loop. Certain heat exchangers and coldplates have more silicon-rich phase because of their manufacturing method, and those units produce more nickel corrosion product. Silver biocide additions did not induce pitting corrosion at silver precipitate sites.

The Crew Exploration Vehicle (CEV), also known as Orion, will ferry a crew of up to six astronauts to the International Space Station (ISS), or a crew of up to four astronauts to the moon. The first launch of CEV is scheduled for approximately 2014. A stored water system on the CEV will supply the crew with potable water for various purposes: drinking and food rehydration, hygiene, medical needs, sublimation, and various contingency situations. The current baseline biocide for the stored water system is ionic silver, similar in composition to the biocide used to maintain quality of the water transferred from the Orbiter to the ISS and stored in Contingency Water Containers (CWCs). In the CEV water system, the ionic silver biocide is expected to be depleted from solution due to ionic silver plating onto the surfaces of the materials within the CEV water system, thus negating its effectiveness as a biocide.

Under a NASA-sponsored technology development project, a multi-disciplinary team consisting of industry, academia, and government organizations lead by Hamilton Sundstrand is developing an amine-based humidity and CO2 removal process and prototype equipment for Vision for Space Exploration (VSE) applications. Originally this project sought to research enhanced amine formulations and incorporate a trace contaminant control capability into the sorbent. In October 2005, NASA re-directed the project team to accelerate the delivery of hardware by approximately one year and emphasize deployment on board the Crew Exploration Vehicle (CEV) as the near-term developmental goal. Preliminary performance requirements were defined based on nominal and off-nominal conditions and the design effort was initiated using the baseline amine sorbent, SA9T.

Under a NASA sponsored technology development activity, Hamilton Sundstrand has designed, fabricated, tested and delivered a prototype solid amine-based carbon dioxide (CO2) and water (H2O) vapor removal system sized for Extravehicular Activity (EVA) operation. The prototype system employs two alternating and thermally-linked solid amine sorbent beds to continuously remove CO2 and H2O vapor from a closed environment. While one sorbent bed is exposed to the vent loop to remove CO2 and water vapor, the other bed is exposed to a regeneration circuit, defined as either vacuum or an inert sweep gas stream. A linear spool valve, coupled directly to the amine canister assembly, is utilized to simultaneously divert the vent loop flow and regeneration circuit flow between the two sorbent beds.

Under a cooperative agreement with NASA, Hamilton Sundstrand has successfully designed, fabricated, tested and delivered three, state-of-the-art, solid amine prototype systems capable of continuous CO2 and humidity removal from a closed, habitable atmosphere. Two prototype systems (CAMRAS #1 and #2) incorporated a linear spool valve design for process flow control through the sorbent beds, with the third system (CAMRAS #3) employing a rotary valve assembly that improves system fluid interfaces and regeneration capabilities. The operational performance of CAMRAS #1 and #2 has been validated in a relevant environment, through both simulated human metabolic loads in a closed chamber and through human subject testing in a closed environment.

Under a NASA-sponsored technology development project, a multi-disciplinary team consisting of industry, academia, and government organizations led by Hamilton Sundstrand is developing an amine based humidity and carbon dioxide (CO2) removal process and prototype equipment for Vision for Space Exploration (VSE) applications. This system employs thermally linked amine sorbent beds operating as a pressure swing adsorption system, using the vacuum of space for regeneration. The prototype hardware was designed based on a two fault tolerant requirement, resulting in a single system that could handle the metabolic water and carbon dioxide load for a crew size of six. Two, full scale prototype hardware sets, consisting of a linear spool valve, actuator and amine sorbent canister, have been manufactured, tested, and subsequently delivered to NASA JSC. This paper presents the design configuration and the pre-delivery performance test results for the CAMRAS hardware.

Metabolically produced carbon dioxide (CO2) removal in spacesuit applications has traditionally been accomplished utilizing non-regenerative Lithium Hydroxide (LiOH) canisters. In recent years, regenerative Metal Oxide (MetOx) has been developed to replace the Extravehicular Mobility Unity (EMU) LiOH canister for extravehicular activity (EVA) missions in micro-gravity, however, MetOx may carry a significant weight burden for potential use in future Lunar or planetary EVA exploration missions. Additionally, both of these methods of CO2 removal have a finite capacity sized for the particular mission profile. Metabolically produced water vapor removal in spacesuits has historically been accomplished by a condensing heat exchanger within the ventilation process loop of the suit life support system.

A number of amine-based carbon dioxide (CO2) removal systems have been developed for atmosphere revitalization in closed loop life support systems. Most recently, Hamilton Sundstrand has developed an amine-based sorbent, designated SA9T, possessing approximately 2-fold greater capacity compared to previous formulations. This new formulation has demonstrated applicability for controlling CO2 levels within vehicles and habitats as well as during extravehicular activity (EVA). Our current data demonstrates an amine-based system volume which is competitive with existing technologies which use metal oxides (Metox) and lithium hydroxide sorbents. Further enhancements in system performance can be realized by incorporating humidity and trace contaminant control functions within an amine-based atmosphere revitalization system. A 3-year effort to develop prototype hardware capable of removing CO2, H2O, and trace contaminants from a cabin atmosphere has been initiated.

In future lunar and Mars exploration missions the ability to provide the crewmember navigation information will be critical. Exploration demands that Extravehicular Activity (EVA) astronauts be provided the capability to operate with greater autonomy in accomplishing complex EVA missions than has been the case previously. Robust crew information interfaces and navigation support integral to the EVA spacesuit system are expected to be minimum requirements. Navigation support must allow the EVA crew to determine their position relative to EVA target locations, satellite imagery and maps and assist them in walking or riding to the desired targets on the planetary surface. Together, these needs suggest a requirement for an integrated system that combines data and voice communications, a high performance visual display, and navigation support in a design that is compatible with spacesuit environmental and packaging restrictions and with unique EVA crew interface demands.

As part of NASA's initiative to develop an advanced portable life support system (PLSS), a baseline schematic has been chosen that includes gaseous oxygen in a closed circuit ventilation configuration. Supply oxygen enters the suit at the back of the helmet, passes over the astronaut's body, and is extracted at the astronaut's wrists and ankles through the liquid cooling and ventilation garment (LCVG). The extracted gases are then treated using a rapid cycling amine (RCA) system for carbon dioxide and water removal and activated carbon for trace gas removal before being mixed with makeup oxygen and reintroduced into the helmet. Thermal control is provided by a suit water membrane evaporator (SWME). As an extension of the original schematic development, NASA evaluated several Helmet Exhalation Capture System (HECS) configurations as alternatives to the baseline.

This paper presents and discusses the results of an integrated 4-Bed Molecular Sieve (4BMS), mechanical compressor, and Sabatier Engineering Development Unit (EDU) test. Testing was required to evaluate the integrated performance of these components of a closed loop atmosphere revitalization system together with a proposed compressor control algorithm. A theoretical model and numerical simulation had been used to develop the control algorithm; however, testing was necessary to verify the simulation results and further refine the model. Hardware testing of a fully integrated system also provided a better understanding of the practical inefficiencies and control issues, which are unavailable from a theoretical model.

This paper summarizes the first 5 plus years of on-orbit operation for the Major Constituent Analyzer (MCA). The MCA is an essential part of the International Space Station (ISS) Environmental Control and Life Support System (ECLSS). The MCA is a mass spectrometer instrument in the US Destiny Laboratory Module of the International Space Station. The MCA provides critical monitoring of six major atmospheric constituents (nitrogen (N2), oxygen (O2), hydrogen (H2), carbon dioxide (CO2), methane (CH4) and water vapor (H2O)) sampled continuously and automatically in all United States On-Orbit Segment (USOS) modules via the Sample Distribution System (SDS). Sample lines have been routed throughout the U.S. modules with valves to facilitate software-automated sequential sampling of the atmosphere in the various modules.

This paper summarizes the first seven plus years of on-orbit operation for the Major Constituent Analyzer (MCA). The MCA is an essential part of the International Space Station (ISS) Environmental Control and Life Support System (ECLSS). The MCA is a mass spectrometer instrument in the US Destiny Laboratory Module, which provides critical monitoring of six major atmospheric constituents (nitrogen (N2), oxygen (O2), hydrogen (H2), carbon dioxide (CO2), methane (CH4), and water vapor (H2O)). These gases are sampled continuously and automatically in all United States On Orbit Segment (USOS) modules via the ISS Sample Delivery System (SDS). Continuous readout of the partial pressures of these gases is critical to verifying safe operation of the Atmosphere Re-vitalization (AR) system, Atmosphere Control System (ACS), and crew safety for Airlock Extravehicular Activity (EVA) preparation.

The International Space Station (ISS) United States Orbital Segment (USOS) Oxygen Generation System (OGS) was originally intended to be installed in ISS Node 3. The OGS rack delivery was accelerated, and it was launched to ISS in July of 2006 and installed in the US Laboratory Module. Various modification kits were installed to provide its interfaces, and the OGS was first activated in July of 2007 for 15 hours. In October of 2007 it was again activated for 76 hours with varied production rates and day/night cycling. Operational time in each instance was limited by the quantity of feedwater in a Payload Water Reservoir (PWR) bag. Feedwater will be provided by PWR bag until the USOS Water Recovery System (WRS) is delivered to ISS in fall of 2008. This paper will discuss operating experience and characteristics of the OGS, as well as operational issues and their resolution.

The Major Constituent Analyzer (MCA) is a mass spectrometer system that measures the major constituents of the International Space Station (ISS) atmosphere. Experience has indicated that the operating life of the mass spectrometer is limited by the operating life of the ion pump, which maintains mass spectrometer vacuum. This paper summarizes the use of trend data from on orbit operations and ground testing to identify and understand the factors affecting ion pump life and to predict ion pump life on orbit. In addition, potential improvements currently under consideration to increase ion pump life, and therefore mass spectrometer life, are discussed.

The International Space Station Carbon Dioxide Removal Assembly (CDRA) uses regenerable adsorption technology to remove carbon dioxide (CO2) from cabin air. CO2 product water vapor measurements from a CDRA test bed unit at the NASA Marshall Space Flight Center were made using a tunable infrared diode laser differential absorption spectrometer (TILDAS) provided by NASA Glenn Research Center. The TILDAS instrument exceeded all the test specifications, including sensitivity, dynamic range, time response, and unattended operation. During the CO2 desorption phase, water vapor concentrations as low as 5 ppmv were observed near the peak of CO2 evolution, rising to levels of ∼40 ppmv at the end of a cycle. Periods of high water concentration (>100 ppmv) were detected and shown to be caused by an experimental artifact.

Following the Columbia accident, the EMUs (Extravehicular Mobility Units) onboard the ISS (International Space Station) went unused for an extended period of time. Upon startup, the units experienced a failure in the coolant systems. The failure resulted in a loss of EVA (Extravehicular Activity) capability from the US segment of the ISS. A failure investigation determined that chemical and biological contaminants and byproducts from the ISS Airlock Heat Exchanger, and the EMU itself, fouled the magnetically coupled pump in the EMU Transport Loop Fan/Pump Separator leading to a lack of coolant flow. Remediation hardware (the Airlock Coolant Loop Remediation water processing kit) and a process to periodically clean the EMU coolant loops on orbit were devised and implemented. The intent of this paper is to report on the successful implementation of the resultant hardware and process, and to highlight the go-forward plan.

An EMU water processing kit (Airlock Coolant Loop Recovery – A/L CLR) was developed as a corrective action to Extravehicular Mobility Unit (EMU) coolant flow disruptions experienced on the International Space Station (ISS) in May of 2004 and thereafter. Conservative schedules for A/L CLR use and component life were initially developed and implemented based on prior analysis results and analytical modeling. The examination of post-flight samples and EMU hardware in November of 2006 indicated that the A/L CLR kits were functioning well and had excess capacity that would allow a relaxation of the initially conservative schedules of use and component life. A relaxed use schedule and list of component lives were implemented thereafter. Since the adoption of the relaxed A/L CLR schedules of use and component lives, several A/L CLR kit items, transport loop water samples and sensitive EMU transport loop components have been examined to gage the impact of the relaxed requirements.

Future spacesuit systems for the exploration of Mars will need to be much lighter than current designs, while at the same time reducing the consumption of water for crew cooling. One of the technology paths NASA has identified to achieve these objectives is the replacement of current high pressure oxygen storage technology in extravehicular activity (EVA) systems with cryogenic technology that can simultaneously reduce the mass of tankage required for oxygen storage and enable the use of the stored oxygen as a means of cooling the EVA astronaut. During the past year NASA has funded production of a prototype system demonstrating this capability in a design that will allow the cryogenic oxygen to be used in any attitude and gravity environment. This paper describes the design and manufacture of the prototype system. The potential significance and application of the system is also discussed.