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Lean combustion has been well known to be an effective method to improve the thermal efficiency. However, leaner mixture is prone to cause the unstable combustion and poorer unburned hydrocarbon (UTHC) emissions. Pre-chamber turbulent jet combustion has been proved to enhance the combustion stability under ultra-lean conditions. However, more NOx is formed during the combustion, resulting in the fact that the tailpipe NOx emission is too high to be still not available for the real application. In this report, in order to achieve a higher air excess ratio while keeping lower UTHC emissions, and especially NOx emission, a new combustion technique which combined pre-chamber jet combustion with fuel reforming was proposed and experimentally demonstrated on a pre-chamber engine.

Ammonia-selective catalytic reduction (SCR) systems have been introduced commercially in diesel vehicles, however catalyst systems with higher conversion efficiency and better control characteristics are required to know the actual emissions during operation and the emissions in random test cycles. Computational fluid dynamics (CFD) is an effective approach when applied to SCR catalyst development, and many models have been proposed, but these models need experimental verification and are limited in the situations they apply to. Further, taking account of redox cycle is important to have better accuracy in transient operation, however there are few models considering the cycle. Model development considering the redox reactions in a zeolite catalyst, Cu-ZSM-5, is the object of the research here, and the effects of exhaust gas composition on the SCR reaction and NH3 oxidation at high temperatures are investigated.