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Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).

With accelerating exhaust gas regulations in recent years, not only CO / HC / NOx but also PN regulation represented by Euro 6 d, China 6 are getting stricter. PN reduction by engine combustion technology development also progresses, but considering RDE, PN reduction by after treatment technology is also indispensable. To reduce PN exhausted from the gasoline engine, it is effective to equip GPF with a filter structure. Considering the installation of GPF in limited space, we developed a system that so far replaces the second TWC with GPF for the TWC 2 bed system. In order to replace the second TWC with GPF, we chose the coated GPF with filtering and TWC functions. Since the initial pressure drop and the catalyst amount (purification performance) of coated GPF have a conflicting relationship, we developed the coated GPF that can achieve both the low initial pressure drop and high purification performance.

The PVC(poly-vinyl chloride) underbody coating was specifically designed for the automotive underfloor area in order to prevent chipping damage as well as the onset of rust propagation from a scratched point. This superior anti-chipping performance can also be achieved without increasing film thickness of the PVC by balancing film strength and adhesion strength. Also, by incorporating plastic balloons in the PVC formulation, a dried film specific gravity of less than 1.0 is achieved, and consequently a 2 kg weight reduction becomes possible when compared to conventional materials used for underbody coating.

Gas shielded metal arc welding is generally applied to automobile chassis parts. However, the weld parts with the E-coat show poor corrosion resistance. Therefore, the corrosion mechanism of the weld parts was investigated. The results found two reasons why the weld parts corroded faster than the non weld parts:(1)inadequate phosphating (2)defects in the E-coat. After detailed investigation, it was clarified that the major cause of poor corrosion resistance was the defects in the E-coat caused by slags formed on the surface of the weld bead. Therefore the amount of slag has to be decreased to improve the corrosion resistance. The effect of shielding gas composition on the amount of slag was then investigated. In the case of Ar and oxidizing gas mixture, the corrosion resistance improved as the oxidizing gas content decreased. This was due to the reduction of slags.

Into the early-part of the next century, automotive emission standards are becoming stricter around the world. The electrically-heated catalyst (EHC) is well known as an effective technology for the reduction of cold-start hydrocarbon emissions without a significant increase in back pressure. Our extruded, alternator powered EHC (APEHC) manufactured with a unique canning method and equipped with a reliable, water proof electrode has demonstrated excellent durability and reliability, as stated in our previous SAE paper (#960340). The APEHC system discussed in this paper has achieved the Ultra-Low-Emission Vehicle (ULEV) standards, after 100,000 miles of fleet testing, without any failure. This is the final milestone in addressing the EHC as a realistic-production technology for ULEV. With the ability to meet ULEV/Stage III emission targets without a significant increase in back pressure, the EHC will be applied to an especially high performance vehicle with a large displacement engine.

Amidst of the recent concerns on depletion of natural resources, a new heat resistant titanium alloy has been developed using the minimum amount of rare metals. Using Ti-811 as a basis and modifying the alloy composition to Ti-7Al-2Mo-0.2Si-0.15C-0.2Nb, the mechanical property, the creep resistance and the oxidation resistance at high temperatures are improved. At the same time, with the β transformation point shifted to a higher temperature, the hot formability is also improved. The newly developed alloy has made it possible to expand the application of titanium material to exhaust valves in reciprocating engines.

The environmental performance of automobiles and automobile engines in particular is the foremost issue in the automotive industry today. In addition, engine durability performance is an essential aspect of engine oil performance. Four-cycle motorcycle engine oils formulated with dialkyl phosphate, a sulfur-free additive developed as an alternative to ZDDP, provide excellent environmental and durability performance in terms of longer drain intervals, cleanliness and low corrosion properties.

The reduction of NOx in exhaust gas has been a major challenge in diesel engine development. For the NOx reduction issues, a new Lean NOx Catalyst (LNC) aftertreatment system has been developed by Honda. A feature of the LNC system is the method that is used to reduce NOx through an NH₃-Selective Catalytic Reduction (NH₃-SCR). In an LNC system NOx is adsorbed at lean conditions, then converted to NH₃ at rich conditions and subsequently reduced in the next lean phase. In recent years, as the efficiency of the diesel engine has improved, the exhaust gas temperatures have been reduced gradually. Therefore, the aftertreatment system needs to be able to purify NOx at lower temperatures. The development of a new LNC which has a high activity at low temperature has been carried out. For the improvement of the LNC three material improvements were developed. The first of these was the development of a NOx adsorbent which is matching the targeted exhaust gas temperatures.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.

Aiming for higher output power, greater fuel economy and reduced exhaust emissions, a new V-6 3.5-liter i-VTEC Variable Cylinder Management (VCM) engine has been developed. This engine uses a cylinder-deactivation mechanism with VTEC technology that allows the number of cylinders to be controlled in three modes (three, four or all six cylinders), according to the operating conditions. This adds a four-cylinder mode to the conventional cylinder- deactivation engine. In addition to increasing the number of cylinder- deactivation modes, the new hydraulic circuits, a hydraulic pressure switching mechanism and a switchover control were also developed. These make it possible to instantaneously switch the active cylinders without impairing drivability, in the same manner as a conventional engine.

The development of the lightweight and compact EU1000i generator with a maximum output of 1kVA is presented. The technology applied to achieve the required levels of exhaust emission, fuel consumption and noise, and to provide a stable electrical power supply with low waveform distortion is described. The technology comprises of four elements: a high-speed, multi-pole, external rotor type alternator, a microcomputer-controlled sine wave inverter, a compact high-speed 4-stroke engine with electronic speed governing, and a lightweight frame with a two-level noise-damping system. Combination of these four elements of technology has achieved 50% less weight, 25-30% lower fuel consumption, and 7-9dB(A) less noise than the previous model. The emission levels of CO and of NOx + HC are also 30% and 65% lower than the 2000 CARB regulations.

This paper presents a new substrate for Lean NOx Traps (LNT) which enables high NOx conversion efficiency, even after long-term aging, when using alkali metals as the NOx adsorber. When a conventional metal honeycomb is used as the LNT substrate, the chromium in the metal substrate migrates into the washcoat and reacts with the alkali metals after thermal aging. In order to help prevent this migration, we have developed a new substrate where a fine -alumina barrier is precipitated to the surface of the metal substrate. The new substrate is highly capable of preventing migration of chromium into the washcoat and greatly enhances the NOx conversion. The durability of the new substrate and emission test using a test vehicle are also examined.

In order to contribute to the resolution of global environmental problems and to respond to the issue of diminishing resources, the Civic Hybrid, a hybrid passenger automobile has been developed to achieve both low emissions and low fuel consumption. The hybrid system takes the conventional Honda IMA (Integrated Motor Assist) system as its foundation. 4-cylinder, 1.3L SOHC, 2-plug engine i-DSI (DSI: Dual and Sequential Ignition) has been selected and modified for lean burn combustion. In addition, a cylinder idling system to increase the amount of electrical energy regenerated during deceleration has been adopted, among other technology. The ultra-thin DC brushless motor has been modified with its magnetic circuit to improve maximum regenerative torque by approximately 30%. Thanks to a new power train that improves CVT transfer efficiency, low fuel consumption of 48mpg in the city and 47mpg on the highway (the 5MT vehicle is 46mpg in the city and 51mpg on the highway) is achieved.

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.

Recently, automotive emission regulations are being further tightened, such as the Tier III/LEV III in the U.S. As a result, reducing cost of after-treatment systems to meet these strict regulations has become an urgent issue, and then the demand for high-precision air-fuel ratio (A/F) control which can achieve this cost reduction is high [1]. On the other hand, in order to meet rapidly changing market needs, it is becoming difficult to keep enough development periods that enable sufficient calibration by trial-and-error, such as feedback-gain calibration. This leads to an increase in three-way catalytic converter costs in some cases. For these reasons, it is necessary to construct control system that can make full use of hardware capabilities, can shorten development periods regardless of the skill level of engineers.

Measuring the real-world performance of emission control technologies is an important aspect in the development of advanced low-emission vehicles. In addition, data acquired from such measurements can be used to improve the accuracy of air quality predictive models. Honda has developed an on-board sampling/analysis system capable of measuring on-road emissions at ULEV levels and below. Ambient air can be analyzed simultaneously. This FTIR-based system can measure several species; this paper will focus on NMHC, NOX, and CO. Techniques were developed to address the challenges associated with acquiring accurate real-time data at concentrations below 1 ppm in an on-road vehicle. Validation studies performed with reference gases and vehicle exhaust indicate a very good correlation between the on-road analyzer system and classic bench methods for all target compounds. Dynamic studies performed by the University of California, Riverside, also show good correlation.

The two liter DOHC-VTEC engine developed for the Honda S2000 produces 179kW (240HP, which is 120HP per liter). It is the highest output power among all naturally aspirated two liter engines ever mass-produced. It also achieves an exhaust emission level within National LEV standards. The new engine utilizes a redesigned VTEC cylinder head, in which MIM (metal injection molding) rocker arms are used. The new cylinder block with a ladder frame structure for its lower part, a newly developed camshaft drive chain and gear system and a metal honeycomb catalyst with an air pump start-up system are also utilized.

With the total amount of air pollution caused by vehicle emissions on the increase, the problem has now became a global concern, and various regulatory measures have been put into effect in each region of the world. This is especially true in California, U.S.A, where countermeasures have been adopted early. There, the ULEV (Ultra Low Emission Vehicle) standard, which was ones deemed impossible for gasoline engines to meet, is now in effect. In response to these developments, Honda announced the ULEV system for a 2.2 liter gasoline engine with a closed-coupled catalytic converter (CC) and an under-floor catalytic converter (UF) at the beginning of 1995, and reported on the system's emission characteristics. 1) A new ULEV system has been developed based on the previous system but using only UF, aiming for marketable improvements in product characteristics such as higher output. The new system features the ultra low heat capacity and high heat insulating (ULOC) exhaust manifold.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.

In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.