Technical Paper
A 3WCC Global Kinetic Model: A Calibration Method Using Laboratory Scale and Engine Test Bench Experiments
2008-04-14
2008-01-0453
A 3 way catalytic converter (3WCC) model based on a global kinetic model was developed and validated against laboratory scale and engine test bench experiments. Various equivalence ratios and temperatures were tested. A methodology was finalized and applied to calibrate the kinetic constants. Laboratory scale experiments were first used to characterize the reaction mechanism during light-off, including the way reduction and oxidation reactions begin and compete with each other when temperature increases. The numerical results are in good agreement with the laboratory scale light-off results. Also, when adapted to simulate the engine test bench experiments, the model is able to correctly reproduce both the light-off tests and the 3WCC conversion efficiency evolution versus equivalence ratio. A calibration method in two steps was thus established and successfully used. The combination of modeling with experimental work appeared to be a powerful tool to determine the reaction mechanism.