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Reactivity controlled compression ignition (RCCI) is one of the most promising low temperature combustion (LTC) strategies to achieve higher thermal efficiencies along with ultra low oxides of nitrogen (NOx) and particulate matter emissions. Small single cylinder diesel engines of air-cooled type are finding increasing applications in the agriculture pump-set and small utility power generation owing to their lower cost and fuel economy advantages. In the present work, a small single cylinder diesel engine is initially operated under conventional combustion mode at rated speed, varying load conditions to establish the base line reference data. Then, the engine is modified to operate under RCCI combustion mode with a newly designed cylinder head to accommodate a high pressure, fully flexible electronically controlled direct diesel fuel injection system, a low pressure gasoline port fuel injection system and an intake air pre heater.

Advanced low temperature combustion (LTC) modes are most promising to reduce green house gas emissions owing to fuel economy benefits apart from simultaneously reducing oxides of nitrogen (NOx) and particulate matter (PM) emissions from diesel engines. Various LTC strategies have been proposed so far and each of these LTC strategies have their own advantages and limitations interms of precise ignition control, achievable load range and higher unburned emissions. In the present work, a small single cylinder diesel engine is initially operated under conventional combustion mode at rated speed, varying load conditions to establish the base line reference data. Then, the engine is modified to operate under different LTC strategies including Homogenous Charge Compression Ignition (HCCI), Premixed Charge Compression Ignition (PCCI) and Reactivity Controlled Compression Ignition (RCCI).

Biodiesel is a renewable, carbon neutral alternative fuel to diesel for compression ignition engine applications. Biodiesel could be produced from a large variety of feedstocks including vegetable oils, animal fats, algae, etc. and thus, vary significantly in their composition, fuel properties and thereby, engine characteristics. In the present work, the effects of biodiesel compositional variations on engine characteristics are captured using a multi-linear regression model incorporated with two new biodiesel composition based parameters, viz. straight chain saturation factor (SCSF) and modified degree of unsaturation (DUm). For this purpose, biodiesel produced from seven vegetable oils having significantly different compositions are tested in a single cylinder diesel engine at varying loads and injection timings. The regression model is formulated using 35 measured data points and is validated with 15 other data points which are not used for formulation.

The upcoming Bharat Stage VI (BS VI) emission legislation has put enormous pressure on the future of small diesel engines which are widely used in the Indian market. The present work investigates the emission reduction potential of a common rail direct injection single cylinder diesel engine by adopting a holistic approach of lowering the compression ratio, boosting the intake air and down-speeding the engine. Experimental investigations were conducted across the entire operating map of a mass-production, light-duty diesel engine to examine the benefits of the proposed approach and the results are quantified for the modified Indian drive cycle (MIDC). By reducing the compression ratio from 18:1 to 14:1, the oxides of nitrogen (NOx) and soot emissions are reduced by 40% and 75% respectively. However, a significant penalty in fuel economy, unburned hydrocarbon (HC) and carbon monoxide (CO) emissions are observed with the reduced compression ratio.

Biodiesel makes an attractive option to replace fossil diesel owing to its applicability in diesel engines without major modifications. An increase in NO emissions with biodiesel compared to diesel is a major concern for its wider use. Blending alcohols, such as methanol, with biodiesel is a potential remedy to mitigate NO formation, as suggested by experiments. However, computational investigations studying the effect of biodiesel-methanol blends on NO formation are scarce. A combined experimental and computational approach is adopted here to investigate the NO formation mechanism with neat biodiesel and biodiesel-methanol blend fueled light duty diesel engine. Firstly, a new compact kinetic model is utilized consisting of oxidation reactions for methyl butanoate and n-dodecane as a surrogate for biodiesel. A surrogate is defined to represent biodiesel based on a combined property and functional group based approach.

The ignition quality of a fuel is described by its cetane number. Experimental methods used to determine cetane number employ Co-operative fuel research (CFR) engine and Ignition quality tester (IQT) which are expensive, have less repeatability and require skilled operation, and hence least preferred. There are many prediction models reported, which involve number of double bonds and number of carbon atoms whose determination is not direct. Using models that relate biodiesel composition to its cetane number is limited by the range of esters involved. Hence, a model to predict cetane number of biodiesels that addresses the limitations of the existing models, without ignoring the influence of factors such as degree of unsaturation and number of carbon atoms, is needed. Fourier transform infrared spectroscopy (FTIR) could be one such method.