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The work analyses, from both an experimental and a numerical point of view, the impingement of a spray generated from a GDI injector on a hot solid wall. The temperature of the surface is identified as an important parameter affecting the outcome after impact. A gasoline spray issuing from a customized single-hole injector is characterized in a quiescent optically-accessible vessel as it impacts on an aluminum plate placed at 22.5 mm from the injector tip. Optical investigations are carried out at atmospheric back-pressure by a direct schlieren optical set-up using a LED as light source. A synchronized C-Mos high-speed camera captures cycle-resolved images of the evolving impact. The spatial and temporal evolution of the liquid and vapor phases are derived. They serve to define a data base to be used for the validation of a properly formulated 3D CFD model suitable to describe the impact of the fuel on the piston head in a real engine.