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Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.

To investigate the events that could arise when fighting fires in vehicles with carbon fiber reinforced plastic (CFRP) hydrogen storage cylinders, we conducted experiments to examine whether a hydrogen jet diffusion flame caused by activation of the pressure relief device (PRD) can be extinguished and how spraying water influences the cylinder and PRD. The experiments clarified that the hydrogen jet flame cannot be extinguished easily with water or dry powder extinguishers and that spraying water during activation of the PRD may result in closure of the PRD, but is useful for maintaining the strength of CFRP composite cylinders for vehicles.

A significant route for water ingress into passenger cars is through the Heating, Ventilating, and Air-Conditioning (HVAC) system. The penetration of rainwater through the HVAC unit and the subsequent rise in moisture levels within the passenger compartment directly affect the provision of thermal comfort to the cabin occupants. It is speculated that up to 80% of water ingress into the cowl or engine bay is from water film movement over the bonnet of the car, and only the remaining 20% is from direct rain impact from above. Using a full-scale Climatic Wind Tunnel (CWT) facility, which incorporates accurate rain distribution modeling, it has been possible to study the movement of rainwater film over the exterior surface of the vehicle to ascertain the flow distribution of the film moving into the engine bay, into the cowl, advancing up and over the windscreen and shed to the sides and front of the vehicle.

This paper presents a comparison of aqueous corrosion rates in 5% NaCl solution for eight experimental creep-resistant magnesium alloys considered for automotive powertrain applications, as well as three reference alloys (pure magnesium, AM50B and AZ91D). The corrosion rates were measured using the techniques of titration, weight loss, hydrogen evolution, and DC polarization. The corrosion rates measured by these techniques are compared with each other as well as with those obtained with salt-spray testing using ASTM B117. The advantages and disadvantages of the various corrosion measurement techniques are discussed.

Ford's Hydrogen Hybrid Research Vehicle (H2RV) is an industry first parallel hybrid vehicle utilizing a hydrogen internal combustion engine. The goal of this drivable concept vehicle is to marry Ford's extensive hybrid powertrain experience with its hydrogen internal combustion engine technology to produce a low emission, fuel-efficient vehicle. This vehicle is seen as a possible bridge from the petroleum fueled vehicles of today to the fuel cell vehicles envisioned for tomorrow. A multi-layered hydrogen management strategy was developed for the H2RV. All aspects of the vehicle including the design of the fuel and electrical systems, placement of high-voltage subsystems, and testing, service, and storage procedures were examined to ensure the safe operation of the vehicle. The results of these reviews led to the design of the hydrogen sensing and mitigation system for the H2RV vehicle.

The hydrogen consumption of fuel cell vehicles (FCV) can be measured by the gravimetric, pressure and flow methods within a ±1% error. These are the methods acknowledged by ISO and SAE [1, 2], but require the test vehicles to be modified in order to supply hydrogen from an external, rather than the onboard tank. Consequently, technical assistance of the vehicle manufacturer is necessary for this modification, while various components in the test vehicle must be readjusted. For these reasons, a measurement method free of vehicle modification is in great demand. The present study therefore developed an “oxygen balance method” which determines the amount of hydrogen that has reacted with oxygen in the fuel cell stack by measuring the oxygen concentration in exhaust gas.

The differences in hydrocarbons (HCs) emitted by gasoline (E0) and ethanol (EtOH) blend fuels from flex-fuel capable engines can lead to differences in the performance of aftertreatment devices. Vehicle emission results have shown either better performance on E0 compared to E85 or vice versa, dependent on the vehicle calibration. In order to separate the impact of the vehicle and the catalyst, a laboratory study was conducted to evaluate performance on a pulse-flame (pulsator) reactor and compare reactivity towards E0 and E85 (85% EtOH-15% E0) exhaust. The catalysts evaluated were substrate-only, washcoat-only and fully formulated catalysts that had been aged either on a pulsator reactor or dynamometer engine. Catalyst performance was evaluated with light-off tests utilizing both slow and fast temperature ramp rates.

Hydrogen concentration during combustion in a confined space with a ceiling was investigated. The results indicated that steady-state hydrogen concentration was highest at the ceiling surface for all hydrogen flow rates. When hydrogen concentration was 10-20%, weak flame propagation occurred at the ceiling surface, with the most easily burnable spots being dented areas such as seams, pores and creases on the ceiling surface. The unstable and limited nature of flame propagation at the ceiling surface was attributed to the relationship between temperature and hydrogen concentration in a confined space.

Ultrasonic fatigue tests (testing frequency around 20kHz) have been conducted on A356 aluminum alloys with different copper contents and AS7GU aluminum alloy. Tests were performed in dry air and submerged in water conditions. The effect of copper content was investigated and it was concluded that copper content plays an important role influencing the humidity effect on A356 aluminum alloy ultrasonic fatigue lives. Also, for the same copper content, copper in solute solution or in precipitate have different humidity sensitivities.

The penetration of rainwater through the heating ventilation and air conditioning system, HVAC, of a vehicle directly affects the provision of thermal comfort within the vehicle passenger compartment. The first element of a typical HVAC system, namely the cowl box is considered. The purpose of the airway from the cowl grille openings to the air filter, immediately before the blower, is to ensure proper water separation from the incoming air stream before entry onto the air filter and onwards into the rest of the HVAC system. This is achieved by ensuring standing water within the cowl is quickly drained and that water rain droplets or water flows from the windshield and body are separated from the air stream, hence minimising the effect on the total system volumetric flow rate. An experimental study is conducted to examine the effect of plane baffles on the airflow filed within a rectangular duct. A set of plane baffle plates is placed within the cowl duct.

As part of a continuous research and innovation effort, Ford Motor Company has been evaluating hydrogen as an alternative fuel option for vehicles with internal combustion engines since 1997. Ford has recently designed and built an Econoline (E-450) shuttle bus with a 6.8L Triton engine that uses gaseous hydrogen fuel. Safe practices in the production, storage, distribution, and use of hydrogen are essential for the widespread public and commercial acceptance of hydrogen vehicles. Hazards and risks inherent in the application of hydrogen fuel to internal combustion engine vehicles are explained. The development of a Hydrogen Management System (H2MS) to detect hydrogen leaks in the vehicle is discussed, including the evolution of the H2MS design from exploration and quantification of risks, to implementation and validation of a working system on a vehicle. System elements for detection, mitigation, and warning are examined.

The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 9 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable as a Recommended Practice for FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. SAE J2578 is currently being revised so that it will continue to be relevant as FCV development moves forward. For example, test methods were refined to verify the acceptability of hydrogen discharges when parking in residential garages and commercial structures and after crash tests prescribed by government regulation, and electrical requirements were updated to reflect the complexities of modern electrical circuits which interconnect both AC and DC circuits to improve efficiency and reduce cost.

The SAE FCV Safety Working Group has been addressing fuel cell vehicle (FCV) safety for over 8 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable to FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. J2578 is currently being updated to clarify and update requirements so that it will continue to be relevant and useful in the future. An update to SAE J1766 for post-crash electrical safety was also published to reflect unique aspects of FCVs and to harmonize electrical requirements with international standards. In addition to revising SAE J2578 and J1766, the Working Group is also developing a new Technical Information Report (TIR) for vehicular hydrogen systems (SAE J2579).

The SAE Fuel Cell Vehicle (FCV) Safety Working Group has published and is developing standards for FCVs and hydrogen vehicles. SAE J2578 was the first document published by the working group. The document is written from an overall vehicle perspective and deals with the integration of fuel cell and hydrogen systems in the vehicle and the management of risks associated with these systems. Since the publishing of SAE J2578, the working group has updated SAE J1766 regarding post-crash electrical safety and is developing SAE J2579 which deals with vehicular hydrogen systems.

Japan Automobile Research Institute has devised and evaluated the various fuel consumption measurement methods for fuel cell vehicles (FCVs). The examination covers the methods based on measurement of electrical current, hydrogen pressure/temperature, weight and flow rate that are expected to be the same accuracy and convenience as conventional measurement methods such as carbon balance method or fuel flow measurement method. As a result of examining the measurement accuracy for each method with a sonic nozzle used as a standard, it is found that both the pressure method and the weight method fulfill the target accuracy of ±1% and that the flow method is able to improve the accuracy by means of calibration with hydrogen. Also, as a result of applying each method to the fuel consumption test of FCVs, the relative error between the pressure method and weight method is within ±1%.

hydrogen was leaked from the underfloor at a flow rate exceeding 131 NL/min (11.8 g/min), which is the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, and the resulting distribution of concentration in the engine compartment and the dispersion after stoppage of the leak were investigated. Furthermore, ignition tests were also conducted and the impact on the surroundings (mainly on human bodies) was investigated to verify the safety of the allowable leakage rate. The tests clarified that if hydrogen leaks from the underfloor at a flow rate of 1000 NL/min (89.9 g/min) and is ignited in the engine compartment, people around the vehicle will not be seriously injure. Therefore, it can be said that a flow rate of 131 NL/min (11.8 g/min), the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, assures a sufficient level of safety.

This paper describes a proton-exchange-membrane Fuel Cells (FC) system dynamic model oriented to automotive applications. The dynamic model allows analysis of FC system transient response and can be used for: a) performance assessment; b) humidification analysis; c) analysis of special modes of operation, e.g., extended idle or freeze start; d) model based FC control design and validation. The model implements a modular structure with first principle based components representation. Emphasis is placed on development of a 1-D membrane water transport model used to simulate gas to gas humidification and stack membrane water diffusion. The Simulink implementation of the model is discussed and results showing FC system transient behavior are presented.

Desiccant materials are commonly used in the automotive industry to reduce the level of moisture in vehicle air conditioning systems. The primary purpose for removing moisture from these systems is to avoid corrosion of metals, compatibility problems with polymeric materials, and possible freeze-up associated with free water. In nonpolar R-12/mineral oil systems with low solubility for water, moisture levels are usually controlled to 25 ppm or less. However, R-134a and PAG are highly polar and have good solubility for moisture, thus presenting reduced risk of free water in the air-conditioning systems. This paper addresses the questions of whether desiccants are required in air conditioning systems using R- 134a/PAG, and if required, what is the optimum quantity of desiccant for system stability and long-term system reliability Tests were conducted in the laboratory (accelerated sealed tube aging according to ASHRAE standard 97- 1989) as well as in the field (vehicle fleet tests).

In this paper, fatigue tests on a cast aluminum alloy (AS7GU-T64) were performed under different frequencies and humidity levels. Tests conducted under conventional frequency in laboratory air have been compared to tests conducted under ultrasonic frequency in dry air, saturated humidity and in distilled water. It was observed that the highest and lowest fatigue lives correspond to ultrasonic fatigue tests in dry air and in distilled water, respectively. Unlike specimens tested at conventional frequency, all of the specimens tested at ultrasonic frequency presented a large amount of slip facets on the fatigue crack propagation fracture surface.

As a part of a continuous research and innovation effort, Ford Motor Company has been evaluating hydrogen since 1997 as an alternative fuel option for vehicles with internal combustion engines. Hydrogen fuel is attractive in that it is the cleanest fuel. Hydrogen, when used in an internal combustion engine, produces an exhaust emission consisting mainly of water vapor, with no carbon dioxide and trace amounts of other regulated pollutants. Hydrogen can be produced from renewable sources which will help reduce the dependence on foreign oil. The implementation of the hydrogen powered IC engine is seen as a strategy to help transition from a petroleum economy to a hydrogen economy and drive development of hydrogen storage, fueling infrastructure and other hydrogen related technologies.