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A miniature quadrupole mass spectrometer array and gas chromatograph have been designed and built for NASA flight missions. Without the gas chromatograph the mass spectrometer is to be used for detection, by astronauts in EVA, of N2, O2, the hydrazines, and NH3 leaks in the hull of the International Space Station, and of adsorbed hydrazines on the astronauts’ suits. The fully-adapted astronaut system, with all software and visual readout, is called the Trace Gas Analyzer. When interfaced with the miniature gas chromatographic system, the mass spectrometer will be useful for a variety of NASA missions involving more complex gas mixtures. The missions include planetary exploration (to Venus, Europa, Titan, etc.), as well as cabin-air monitoring for long-duration human flight to the Moon, Mars, and beyond.

Bacillus sp. ATCC 29669 was isolated from microbial fallout in clean rooms during the assembly of the Viking Spacecraft missions to Mars, making it a potential contamination concern for outbound space missions. Spores from this bacterial strain were found to be thirty times more resistant to dry heat than B. atrophaeus. Spore inactivation rates under vacuum controlled humidity were faster than rates obtained under ambient humidity. Inactivation rates for these heat resistant spores are important considerations for planetary protection implementation where temperature, time and humidity conditions are used to estimate the effectiveness of dry heat microbial reduction (DHMR) procedures.

Various candidates for nonpetroleum electric and hybrid vehicle (EHV) subsystems have been evaluated as part of the Advanced Vehicle (AV) Assessment at the Jet Propulsion Laboratory. The subsystems include battery and power-peaking energy storage, heat engine and fuel cell energy conversion devices, motor/controller subsystems, transmissions, and vehicle subsystem (structure and body) technologies. The primary objective of this effort, was to project the mature capabilities of the various components in the 1990’s for application in the systems evaluations in the next phase of this activity. This paper presents the basic characteristics of the subsystems and compares their capabilities with projected AV subsystem requirements.

In support of the National Aeronautics and Space Administration(NASA), a laboratory has been established at the Jet Propulsion Laboratory (JPL) to evaluate the characteristics of chemical sensors which are candidates for use in a controlled chemical processing life support system. Such a facility is required for characterizing those sensors under development as well as those commercially available but whose functional properties are typically based upon operating in industrial environments that will not be completely synonomous with space operations. Space environments, such as an orbiting station or lunar base, will generally have different sensor requirements than terrestrial applications with respect to size, multifunctionality, sensitivity, reliability, temperature, ruggedness, mass, consumables, life, and power requirements. Both commercially available and developmental moisture sensors have been evaluated.

The Mars Exploration Rover (MER) flight system uses mechanical, paraffin-actuated heat switches as part of its secondary battery thermal control system. This paper describes the design, flight qualification, and performance of the heat switch. Although based on previous designs by Starsys Research Corporation1,2, the MER mission requirements have necessitated new design features and an extensive qualification program. The design utilizes the work created by the expansion of a paraffin wax by bringing into contact two aluminum surfaces, thereby forming a heat conduction path. As the paraffin freezes and contracts, compression springs separate the surfaces to remove the conduction path. The flight qualification program involved extensive thermal performance, structural, and life testing.

A paraffin-actuated heat switch has been developed for thermal control of the batteries used on the 2003 Mars Exploration Rovers. The heat switch is used to reject heat from the rover battery to a radiator. This paper describes the development test program designed, in part, to measure the thermal conductance of the heat switch in an 8 Torr CO2 environment over the expected operating temperature range of the battery. The switch has a closed conductance of about 0.6 W/°C and an open conductance of 0.019 W/°C. The test program also included measuring the battery temperature profile over a hot case and a cold case Mars diurnal cycle. The test results confirm that the battery will remain well within the upper and lower allowable flight temperatures in both cases.

The recent development of single-mode continuous wave distributed feedback mid-IR interband cascade lasers operating at thermoelectric cooler temperatures is presented. Also, latest progress of interband cascade lasers is reported.

The Orbiting Carbon Observatory (OCO) will carry a single science instrument scheduled for launch on an Orbital Sciences Corporation LeoStar-2 architecture spacecraft bus in December 2008. The science objective of the OCO instrument is to collect spaced-based measurements of atmospheric CO2 with the precision, resolution, and coverage needed to identify CO2 sources and sinks and quantify their seasonal variability. The instrument will permit the collection of spatially resolved, high resolution spectroscopic observations of CO2 and O2 absorption in reflected sunlight over both continents and oceans. These measurements will improve our ability to forecast CO2 induced climate change. The instrument consists of three bore-sighted, high resolution grating spectrometers sharing a common telescope with similar optics and electronics.

An array-based sensing system based on 32 polymer/carbon composite conductometric sensors is under development at JPL. Until the present phase of development, the analyte set has focused on organic compounds (common solvents) and a few selected inorganic compounds, notably ammonia and hydrazine. The present phase of JPL ENose development has added two inorganics to the analyte set: mercury and sulfur dioxide. Through models of sensor-analyte response developed under this program coupled with a literature survey, approaches to including these analytes in the ENose target set have been determined.

An array-based sensing system based on polymer-carbon composite conductometric sensors is under development at JPL for use as an environmental monitor in the International Space Station. Sulfur dioxide has been added to the analyte set for this phase of development. Using molecular modeling techniques, the interaction energy between SO2 and polymer functional groups has been calculated, and polymers selected as potential SO2 sensors. Experiment has validated the model and two selected polymers have been shown to be promising materials for SO2 detection.

The development of tunable diode laser systems in the 2 - 5 μm spectral region will have numerous applications for trace gas detection. To date, the development of such systems has been hampered by the difficulties of epitaxial growth, and device processing in the case of the Sb-based materials system. One of the compounding factors in this materials system is the use of aluminum containing compounds in the laser diode cladding layers. This makes the regrowth steps used in traditional lasers very difficult. As an alternative approach we are developing laterally coupled antimonide based lasers structures that do not require the regrowth steps. In this paper, the materials growth, device processing and development of the necessary drive electronics for an antimony based tunable diode laser system are discussed.

Certain Eubacteria enter a viable but nonculturable (VBNC) state upon encountering unfavorable environmental conditions. VBNC cells do not divide on conventional media yet remain viable and in some cases retain virulence. Here, we describe the VBNC state of two opportunistic pathogens previously isolated from ISS potable waters, Burkholderia cepacia and Stenotrophomonas maltophilia. Artificially inoculated microcosms were exposed to the biocidal agents copper (CuSO4) and iodine (I2) in an attempt to induce nonculturablility. Viability was assessed via fluorescent microscopy (direct viable count assay coupled with BacLight™ staining) and metabolic activity was monitored by quantifying both intracellular ATP and transcribed rRNA (reverse transcriptase quantitative PCR). Culturablility was lost in both B. cepacia and S. maltophilia within two days of exposure to copper or high concentrations of iodine (6 or 8 ppm).

A technology demonstration propylene Loop Heat Pipe (LHP) has been tested extensively in support of the implementation of this two-phase thermal control technology on NASA’s Earth Observing System (EOS) Tropospheric Emission Spectrometer (TES) instrument. This cryogenic instrument is being developed at the Jet Propulsion Laboratory (JPL) for NASA. This paper reports on the transient characterization testing results showing low frequency temperature oscillations. Steady state performance and model correlation results can be found elsewhere. Results for transient startup and shutdown are also reported elsewhere. In space applications, when LHPs are used for thermal control, the power dissipation components are typically of large mass and may operate over a wide range of power dissipations; there is a concern that the LHP evaporator may see temperature oscillations at low powers and over some temperature range.

The lifetime of an AMTEC electrode is predicted from the rate of grain growth in the electrode. The rate of growth depends on several physical characteristics of each material, including the rate of diffusion of the material on itself. Grain growth rates for rhodium-tungsten and titanium nitride electrodes have been determined, and have been used to predict operating lifetimes of AMTEC electrodes. For lifetimes of 10 years or more, RhxW electrodes may be used at any operating temperature supportable by the electrolyte. TiN electrodes may be used in AMTEC cells only at operating temperatures under 1150 K.

A method for determining margins in conceptual-level design via probabilistic methods is described. The goal of this research is to develop a rigorous foundation for determining design margins in complex multidisciplinary systems. As an example application, the investigated method is applied to conceptual-level design of the Mars Exploration Rover (MER) cruise stage thermal control system. The method begins with identifying a set of tradable system-level parameters. Models that determine each of these tradable parameters are then created. The variables of the design are classified and assigned appropriate probability density functions. To characterize the resulting system, a Monte Carlo simulation is used. Probabilistic methods can then be used to represent uncertainties in the relevant models. Lastly, results of this simulation are combined with the risk tolerance of thermal engineers to guide in the determination of margin levels.

The Jet Propulsion Laboratory Mars Exploration Program Office is currently planning a series of exciting missions to the Red Planet. During each launch opportunity, the missions to Mars will include a Rover mission. During the earlier Rover missions to Mars such as the Mars Pathfinder mission carrying the Sojourner Rover in 1997, the main rover power source was a solar array. The power subsystem of the Sojourner Rover included a solar panel for power during the day, a non-rechargeable lithium battery for power during the night, and a power electronics board for power conditioning and distribution. Starting with the year 2003 the rover missions to Mars will incorporate a rechargeable energy storage device rather than a non-rechargeable power source. Included in the power electronics board, will be a battery controller/charger. The battery controller/charger will be able to monitor and control three parallel 4-cell battery strings.

The Mars Science Laboratory (MSL1) mission to land a large rover on Mars is being planned for Launch in 2009. As currently conceived, the rover would use a Multi-mission Radioisotope Thermoelectric Generator (MMRTG) to generate about 110 W of electrical power for use in the rover and the science payload. Usage of an MMRTG allows for a large amount of nearly constant electrical power to be generated day and night for all seasons (year around) and latitudes. This offers a large advantage over solar arrays. The MMRTG by its nature dissipates about 2000 W of waste heat. The basic architecture of the thermal system utilizes this waste heat on the surface of Mars to maintain the rover's temperatures within their limits under all conditions. In addition, during cruise, this waste heat needs to be dissipated safely to protect sensitive components in the spacecraft and the rover.

Future planetary science missions planned for Mars are expected to be more complex and thermally challenging than any of the previous missions. For future rovers, the operational parameters such as landing site latitudes, mission life, distance traversed, and rover thermal energy to be managed will be significantly higher (two to five times) than the previous missions. It is a very challenging problem to provide an effective thermal control for the future rovers using traditional passive thermal control technologies. Recent investigations at the Jet Propulsion Laboratory (JPL) have shown that mechanical pump based fluid loops provide a robust and effective thermal control system needed for these future rovers. Mechanical pump based fluid loop (MPFL) technologies are currently being developed at JPL for use on such rovers. These fluid loops are planned for use during spacecraft cruise from earth to Mars and also on the Martian surface operations.

The development of mid-IR semiconductor diode lasers based on type-II interband cascade structures is presented. How these diode lasers can be developed to meet the requirements in chemical sensing applications is discussed.

The power produced by an AMTEC is dependent on the porosity of the electrode layers deposited on the surface of the BASE tubes. The elevated temperatures at which these power generators operate result in a slow growth or coalescence of the grains that comprise the electrode layers thereby reducing porosity and effective surface area. The lifetime of AMTEC electrodes is therefore related to the rate of grain growth of the electrode material. A preliminary model has been developed to determine the rate of grain growth over the operational lifetime of an AMTEC. This model examines the conditions for continuous growth as a function of the relative sizes, boundary and activation energies and mobilities of the grains. An assumption of strain-free growth has been made in determining the factors for normal growth. Experimental measurements for titanium nitride alloy electrodes are compared with this model. Predictions are made for performance lifetimes out to 10 years.