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Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

This paper presents a study of LPG lean burn in a motorcycle SI engine. The lean burn limits are compared by several ways. The relations of lean burn limit with the parameters, such as engine speed, compression ratio and advanced spark ignition etc. are tested. The experimental results show that larger throttle opening, lower engine speed, earlier spark ignition timing, larger electrode gap and higher compression ratio will extend the lean burn limit of LPG. The emission of a LPG engine, especially on NOx emission, can be significantly reduced by means of the lean burn technology.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

Internal combustion engines, as the dominant power source in the transportation sector and the primary contributor to carbon emissions, face both significant challenges and opportunities in the context of achieving carbon neutral goal. Biofuels, such as biodiesel produced from biomass, and zero-carbon fuel ammonia, can serve as alternative fuels for achieving cleaner combustion in internal combustion engines. The dual-fuel combustion of ammonia-biodiesel not only effectively reduces carbon emissions but also exhibits promising combustion performance, offering a favorable avenue for future applications. However, challenges arise in the form of unburned ammonia (NH3) and N2O emissions. This study, based on a ammonia-biodiesel duel-fuel engine modified from a heavy-duty diesel engine, delves into the impact of adjustments in the two-stage injection strategy on the combustion and emission characteristics.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

A test programme has been conducted to study any potential long term effects of gasoline sulphur on catalyst performance, using a newly developed transient engine-bed ageing cycle. The ageing cycle, which was based on repeated European Extra Urban Drive Cycles, was chosen to ensure that the catalyst experienced a realistically wide range of temperatures and space velocities, together with transients, idle and periods of overrun. Two nominally identical platinum/rhodium catalysts (manufactured from the same batch) with matched lambda sensors, were aged for a period of 80,000 km each, one being aged using a gasoline containing 50 mg/kg (ppm wt) sulphur, the other being aged on the same fuel doped to 450 ppm wt S. The emissions performance of both catalysts was measured after 6,000, 40,000 and 80,000 km ageing, by fitting the catalysts to a test vehicle, and performing emissions tests over the European test cycle at both sulphur levels.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

Advanced compression ignition combustion system which reduces simultaneously both nitride oxides (NOx) and particulate matter (PM) is a promising approach to meet future emission regulations. In order to achieve advanced compression ignition, flexible fuel injection is required for ultra-early and post-TDC injections, which conventional injector fails to accomplish due to wall-wetting effect. In this work, special injectors with the spray angle of 60 degree are applied on a 4 cylinder mass-production diesel engine without modification of the engine configuration. For application-oriented study, sweep experiments of injection timings and durations, fuel injection pressure and the boost pressure are carried out to investigate the relationships between the control parameters and the engine performance. Model based calibration and real application tests validate the maximum applicable operation range of maximum speed of 2200 RPM and IMEP of 8.0 bar.

This paper presents an experimental study of the emission characteristics of a small Spark-Ignited, LPG engine. A single cylinder, four-stroke, water-cooled, 125cc SI engine for motorcycle is modified for using LPG fuel. The power output of LPG is above 95% power output of gasoline. The emission characteristics of LPG are compared with the gasoline. The test result shows that LPG for small SI engine will help to reduce the emission level of motorcycles. The HC and CO emission level can be reduced greatly, but NOx emissions are increased. The emission of motorcycle using LPG shows the potential to meet the more strict regulation.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

The Center for Transportation Research (CTR) Vehicle Systems team modified a Nissan CK-2 Continuously Variable Transmission (CVT) for a diesel hybrid powertrain application. Mechanical and electrical modifications were made to the CVT, both internal and external to the transmission. The goal of this experiment was to investigate and demonstrate the potential of CVT for diesel engines hybrid electric vehicles (HEVs) in fuel economy and emissions. The test set-up consisted of a diesel engine coupled to an electric motor driving a Continuously Variable Transmission (CVT). This hybrid drive is connected to a dynamometer and a DC electrical power source creating a vehicle context by combining advanced computer models and emulation techniques. The experiment focuses on the impact particular transmission control strategies have on measured fuel economy and emissions specifically, nitrogen oxides (NOx) and particulate matter (PM).

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

This paper presents the development of an electronic control LPG gas injection system and its application in a small SI engine. The tests results show that the developed LPG gas injection system can meet the needs for the goal of high engine power output and low exhaust emissions based on the engine bench tests. With the LPG electronic gas injection system, the air-fuel ratio can be optimized based on the requirements and CO and NOx emission levels are decreased significantly compared with the LPG mechanical mixer fuel supply system, based on the same HC emission levels. With the new gas phase LPG electronic control injection system, the HC emission level is controlled below the 300 ppm under most engine conditions and under 200 ppm when the engine speed is over 3000 r/min. The NOx emission level is under 2600 ppm in the whole range of engine operation conditions and is decreased by 2000 ppm compared with the LPG mechanical mixer system.

The objective of this paper is to present the results of diesel exhaust aftertreatment testing and analysis done under the FreedomCAR program. Nitrogen Oxides (NOx) adsorber technology was selected based on a previous investigation of various NOx aftertreatment technologies including non-thermal plasma, NOx adsorber and active lean NOx. Particulate Matter (PM) emissions were addressed by developing a catalyzed particulate filter. After various iterations of the catalyst formulation, the aftertreatment components were integrated and optimized for a light duty vehicle application. This compact exhaust aftertreatment system is dual leg and consists of a sulfur trap, NOx adsorbers, and catalyzed particulate filters (CPF). During regeneration, supplementary ARCO ECD low-sulfur diesel fuel is injected upstream of the adsorber and CPF in the exhaust. Steady state and transient emission test results with and without the exhaust aftertreatment system (EAS) are presented.

The molecular filtration of sulfur components in ultra low sulfur diesel (ULSD) fuel is described. A comprehensive screening of potential sulfur removal chemistries has yielded a sorbent which has the capability to efficiently remove organo-sulfur components in ULSD fuel. This sorbent has been used to treat ULSD fuel on a heavy duty engine equipped with NOx adsorber after-treatment technology and has been shown to lengthen the time between desulfation steps for the NOx adsorber. The fuel properties, cetane number and aromatics content, etc., have not been changed by the removal of the sulfur in the fuel with the exception of the lubricity which is reduced.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

Gasoline direct injection (GDI) engines have been developed rapidly in recent years, driven by stringent legislative requirements on vehicle fuel efficiency and emissions. However, one challenge facing GDI is the formation of particulate emissions, particularly with the presence of injector tip deposits. The Chinese market features some gasoline fuels that contain no detergent additives and are prone to deposit formation, which can affect engine performance and emissions. The use of detergent additives to mitigate the formation of injector deposits in a GDI engine was investigated in this study by testing a 1.5L turbocharged GDI engine available in the Chinese market. The engine was operated both on base gasoline and on gasoline dosed with detergent additives to evaluate the effect on injector deposit formation and engine performance and emissions.

The purpose of this study was to determine the effect of injector nozzle hole size, shape, and finish on performance and emissions in a light-duty diesel engine. Two sets of six-hole valve covered orifice (VCO) nozzles were tested with nearly identical volumetric flow rates but varying geometry and finish. The 17% hydro-erosion (HE) nozzles had a 22% larger discharge coefficient (CD), compared to the 7% HE nozzles. In order to maintain similar volumetric flow rates, the orifice diameter of the 17% HE nozzles were reduced by almost 10%.The nozzles were tested in a 1.7L, four-cylinder, common rail diesel engine, operating on conventional D2 diesel fuel. The 17% HE, conical-shaped nozzles reduced fuel specific particulate matter (PM) and increased fuel specific oxides of nitrogen (NOx) emissions, over the 7% HE, straight-shaped nozzle.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.