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The increased availability of natural gas (NG) in the U.S. has renewed interest in the application to heavy-duty (HD) diesel engines in order to realize fuel cost savings and reduce pollutant emissions, while increasing fuel economy. Reactivity controlled compression ignition (RCCI) combustion employs two fuels with a large difference in auto-ignition properties to generate a spatial gradient of fuel-air mixtures and reactivity. Typically, a high octane fuel is premixed by means of port-injection, followed by direct injection of a high cetane fuel late in the compression stroke. Previous work by the authors has shown that NG and diesel RCCI offers improved fuel efficiency and lower oxides of nitrogen (NOx) and soot emissions when compared to conventional diesel diffusion combustion. The work concluded that NG and diesel RCCI engines are load limited by high rates of pressure rise (RoPR) (>15 bar/deg) and high peak cylinder pressure (PCP) (>200 bar).

Reactivity controlled compression ignition (RCCI) combustion employs two fuels with a large difference in auto-ignition properties that are injected at different times to generate a spatial gradient of fuel-air mixtures and reactivity. Researchers have shown that RCCI offers improved fuel efficiency and lower NOx and Soot exhaust emissions when compared to conventional diesel diffusion combustion. The majority of previous research work has been focused on premixed gasoline or ethanol for the low reactivity fuel and diesel for the high reactivity fuel. The increased availability of natural gas (NG) in the U.S. has renewed interest in the application of compressed natural gas (CNG) to heavy-duty (HD) diesel engines in order to realize fuel cost savings and reduce pollutant emissions, while increasing fuel economy. Thus, RCCI using CNG and diesel fuel warrants consideration.

This paper presents a fundamental thermodynamic modeling approach to study internal combustion engines. The computations of the thermodynamic functions, especially availability, have been developed to seek better energy utilization, analyze engine performance and optimize design of spark ignition (SI) engines fueled with compressed natural gas (CNG), by using both the first and the second law analyses. A single-zone heat release model with constant thermodynamic properties is built into the air cycle simulation, while a more comprehensive two-zone combustion model with burning rate as a sinusoidal function of crank angle is built into the fuel/air thermodynamic engine cycle simulation. The computations mainly include pressure, unburned and burned zone temperature, indicated work, heat loss, mass blowby, availability destruction due to combustion, fuel chemical availability, availability transfer with heat, availability transfer with work and availability exhaust to the environment.

The fuel called E-85 can be burned effectively in engines similar to the engines currently mass-produced for use with gasoline. Since the ethanol component of this fuel is produced from crops such as corn and sugar cane, the fuel is almost fully renewable. The different physical and chemical properties of E-85, however, do require certain modifications to the common gasoline engine. The Windsor - St. Clair team has focused their attention to modifications that will improve fuel efficiency and reduce tailpipe emissions. Other modifications were also performed to ensure that the vehicle would still operate with the same power and driveability as its gasoline counterpart.