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Ammonia has attracted the attention of a growing number of researchers in recent years. However, some properties of ammonia (e.g., low laminar burning velocity, high ignition energy, etc.) inhibit its direct application in engines. Several routes have been proposed to overcome these problems, such as oxygen enrichment, partial fuel cracking strategy and co-combustion with more reactive fuels. Improving the reactivity of ammonia from the oxidizer side is also practical. Ozone is a highly reactive oxidizer which can be easily and rapidly generated through electrical plasma and is an effective promoter applicable for a variety of fuels. The dissociation reaction of ozone increases the concentration of reactive radicals and promotes chain-propagating reactions. Thus, obtaining accurate rate constants of reactions related to ozone is necessary, especially at elevated to high pressure range which is closer to engine-relevant conditions.

Euro VI emission standards have set a very strict limitation on particulate matter emissions of Gasoline Direct Injection (GDI) engine. It is difficult for GDI engine to meet the Euro VI PN regulation (6×1011#/km) without a series of complicated after-treatment devices such as Gasoline Particulate Filter (GPF). Previous research shows that GDI vehicles under cold start condition account for more than 50% of both particle number and mass emissions during the entire NEDC driving cycle. Dual Injection Gasoline engine is based on the GDI engine by adding a set of port fuel injection system. The good mixing characteristics of the port fuel injection system can help to reduce the particulate matter emissions of the GDI engine during the cold start condition.

In the present study a novel surrogate model for biodiesel including methyl decanoate (MD) and methyl crotonate (MC) was proposed and validated. In the binary mixture of surrogate fuel, MD was chosen to represent saturated methyl esters, which exhibited great low-temperature reactivity with typical negative temperature-coefficient (NTC) behavior and MC represented unsaturated components in real biodiesel, which was mainly responsible for soot formation and evolution. The proportion of MD and MC was determined by matching the characteristics such as derived cetane number (DCN), molecular weight (MW), atom number, H/C ratio and unsaturated degree. All of the criterions were calculated by the least square principles and the calculated surrogate of biodiesel was comprised of 92% MD and 8% MC in mole fraction. Furthermore, detailed kinetic model of the surrogate fuel was constructed and developed with modifications, which was composed of 2918 species and 9164 reactions.

Gasoline direct injection (GDI) has been a mainstream technology due to its higher thermal efficiency and better power output. However, with increasingly stringent emission regulations introduced (EURO VI PN limits: 6 x l011#/km), high particulate matter (PM) emission of GDI engine has been a serious problem that limits its further development. Previous studies have found that cold-start and warm-up operation conditions play the dominant role in engine-out particulate emissions. In this paper, emission characteristics during the cold-start were first studied by controlling the coolant temperature. A Cambustion DMS500 fast particle spectrometer was employed to analyze the PM emissions. In order to reduce the engine-out emissions of cold-start, a dual injection system which combines port-fuel-injection (PFI) and direct-injection (DI) was applied in a four-cylinder gasoline engine.

The aim of this study is to evaluate the land requirement, energy consumption and GHG (greenhouse gases) emissions of microalgal biodiesel (M-BD) and Jatropha curcas seeds (J-BD) based biodiesel from the perspective of life cycle assessment (LCA). Mass and energy balance was used through the whole LCA calculation for each process. Two types of biodiesel (100% biodiesel: BD100, and 20% blends of biodiesel: BD20) were assumed to be combusted in the suitable diesel engine. Displacement method was adopted to measure the co-products credits. The results showed that the land requirement of producing 1 kg biodiesel from microalgae was about 1/31 of that from Jatropha curcas seeds. The well to pump (WTP) stage for microalgal biodiesel had higher fossil energy requirement but lower petroleum energy consumption and GHG emissions compared to Jatropha curcas and conventional diesel (CD). The WTP energy efficiency for J-BD100 and M-BD 100 were 26% and 17.4%, respectively.

Recently, the shortage of fossil resources contributes to strict regulations of environmental protection. The research on the high efficiency and low emission of engines becomes an important direction all over the world. Technologies like high injection pressure, high levels of supercharging and higher levels of back pressure have come into application. Increasing the injection pressure and average cylinder pressure results in that parts of the spray can experience transcritical and supercritical regimes. In this paper, we established a surrogate fuel composed of n-Hexadecane, HMN and 1-Metylnaphthalene, to analyze the injection and atomization of diesel surrogate fuel with large eddy simulation (LES) in a cubic calculation region with high temperature and high pressure environment. The injection pressure was fixed to 150MPa, and the 900-K temperature and the 6-MPa pressure represented the ambient condition in constant volume vessel which is supercritical with respect to No.2 diesel.

Biodiesel is a potential alternative fuel which can meet the growing need for sustainable energy. Partially premixed compression ignition (PPCI) is an important low-temperature combustion strategy to reduce NOx and soot emission of diesel engines. To investigate partial premixing impact on particle formation in flames of biodiesel or biodiesel surrogates, an experimental study was performed to compare the soot morphology and nanostructure evolution in laminar co-flow methyl decanoate non-premixed flame (NPF) and partially premixed flame (PPF). The thermophoretic sampling technique was used to capture particles along flame centerlines. Soot morphology information and volume fraction were obtained from TEM analysis and nanostructure features were evaluated by HR-TEM. With primary equivalence ratio of 19, gas temperature of PPF is higher along flame centerline compared with NPF. The results show an initially stronger sooting tendency in PPF at lower positions.

European standards have set stringent PN (particle number) regulation (6×1011 #/km) for gasoline direct injection (GDI) engine, posing a great challenge for the particulate emission control of GDI engines. Dual-injection, which combines direct-injection (DI) with port-fuel-injection (PFI), is an effective approach to reduce particle emissions of GDI engine while maintaining good efficiency and power output. In order to investigate the PN emission characteristics under different dual-injection strategies, a DMS500 fast particle spectrometer was employed to characterize the effects of injection strategies on particulates emissions from a dual-injection gasoline engine. In this study, the injection strategies include injection timing, injection ratio and injection pressure of direct-injection.