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Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

To characterize emission performance and engine operating conditions during high-power cold starts (HPCS), a blended plug-in hybrid electric vehicle was tested over worldwide harmonized light-duty vehicle test cycle (WLTC), and a new cycle was developed to characterize HPCS. The results showed that the engine speed and load increased dramatically to high level during HPCS under the low temperature of coolant and catalysts. The higher concentration of particle number (PN) and NOx at higher speed and load, accounted for the higher emissions during HPCS. Besides, the cumulative PN emissions increased first and then decreased with the increasing coolant temperature.