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An advanced catalytic exhaust after-treatment system addresses the problem of NOX emissions from heavy-duty diesel trucks, relying on real-time catalyst modelling. The system consists of de-NOX catalysts, a device for injection of a reducing agent (diesel fuel) upstream the catalysts, and computer programmes to control the injection of the reducing agent and to model the engine and catalysts in real time. Experiments with 5 different air-assisted injectors were performed to determine the effect of injector design on the distribution of the injected diesel in the exhaust gas stream. A two-injector set-up was investigated to determine whether system efficiency could be increased without increasing the amount of catalyst or the amount of reducing agent necessary for the desired outcome. The results were verified by performing European standard transient cycle tests as well as stationary tests.

Emissions and in-cylinder pressure traces are used to compare the relative importance of soot formation and soot oxidation in a heavy-duty diesel engine. The equivalence ratio at the lift-off length is estimated with an empirical correlation and an idealized model of diesel spray. No correlation is found between the equivalence ratio at lift-off and the soot emissions. This confirms that trends in soot emissions cannot be directly understood by the soot formation process. The coupling between soot emission levels and late heat release after end of injection is also studied. A regression model describing soot emissions as function of global engine parameters influencing soot oxidation is proposed. Overall, the results of this analysis indicate that soot emissions can be understood in terms of the efficiency of the oxidation process.

Increased research is being driven by the automotive industry facing challenges, requiring to comply with both current and future emissions legislation, and to lower the fuel consumption. The reason for this legislation is to restrict the harmful pollution which every year causes 3.3 million premature deaths worldwide [1]. One factor that causes this pollution is NOx emissions. NOx emission legislation has been reduced from 8 g/kWh (Euro I) down to 0.4 g/kWh (Euro VI) and recently new legislation for ammonia slip which increase the challenge of exhaust aftertreatment with a SCR system. In order to achieve a good NOx conversion together with a low slip of ammonia, small droplets of Urea solution needs to be injected which can be rapidly evaporated and mixed into the flow of exhaust gases.

In the automotive industry, the piezo-based in-cylinder pressure sensor is getting commercialized and used in production vehicles. For example, the pressure sensor offers the opportunity to design algorithms for estimation of engine emissions, such as soot and NO , during a combustion cycle. In this paper a zero-dimensional NO model for a diesel engine is implemented that will be used in real time. The model is based on the thermal NO formation and the Zeldovich mechanism using two non-geometrical zones: burned and unburned zone. The influence of EGR on combustion temperature was modeled using a well-known thermodynamic identity where specific heat at constant pressure is included. Specific heat will vary with temperature and the gas composition. The model was implemented in LabVIEW using tools specific for an FPGA (Field-Programmable Gate Array).

A quasi-dimensional multi-zone model for diesel spray combustion has been developed. The model contains most of the physical processes of diesel spray combustion, and is simplified and economical. The zone formation is based on the fuel injection parameters. For the wall jet penetration velocity, a new equation is used based on the effect of the impinging free jet on the wall jet. For the fuel evaporation, an approximate solution of the instantaneous variations of droplet diameter is given in the simple algebraic equations based on the individual effect of the evaporation and the heat transfer from ambient gas. The soot emission sub-model calculates the soot concentration. This model has been applied for a direct injection diesel engine. The calculated results have shown a reasonable agreement with the experimental results. A parametric study has been carried out.

In this paper, computation fluid dynamics (CFD) simulations are employed to describe the effect of flow parameters on the formation of soot and NOx in a heavy duty engine under low load and high load. The complexity of diesel combustion, specially when soot, NOx and other emissions are of interest, requires using a detailed chemical mechanism to have a correct estimation of temperature and species distribution. In this work, Multiple Representative Interactive Flamelets (MRIF) method is employed to describe the chemical reactions, ignition, flame propagation and emissions in the engine. A phenomenological model for soot formation, including soot nucleation, coagulation and oxidation with O2 and OH is incorporated into the flamelet combustion model. Different strategies for modelling NOx are chosen to take into account the longer time scale for NOx formation. The numerical results are compared with experimental data to show the validity of the model for the cases under study.

This paper offers a two-zone NOx model suitable for vehicle on-board, on-line implementation. Similar NOx modeling attempts have previously been undertaken. The hereby suggested method does however offer clear and important benefits over the previously methods, utilizing a significantly different method to handle temperature calculations within the (two) different zones avoiding iterative computation. The new method significantly improves calculation speed and, most important of all, reduces implementation complexity while still maintaining reasonable accuracy and the physical interpretation of earlier suggested methods. The equations commonly used to compute NOx emissions is also rewritten in order to suit a two-zone NOx model. An algorithm which can be used to compute NOx emissions is presented and the intended contribution of the paper is a NOx model, implementation feasible for an embedded system, e.g. embedded processor or embedded electronic hardware (FPGA).

A previously presented robust and fast diagnostic NOx model was modified into a predictive model. This was done by using simple yet physically-based models for fuel injection, ignition delay, premixed heat release rate and diffusion combustion heat release rate. The model can be used both for traditional high temperature combustion and for high-EGR low temperature combustion. It was possible to maintain a high accuracy and calculation speed of the NOx model itself. The root mean square of the relative model error is 16 % and the calculation speed is around one second on a PC. Combustion characteristics such as ignition delay, CA50 and the general shape of the heat release rate are well predicted by the combustion model. The model is aimed at real time NOx calculation and optimization in a vehicle on the road.

Two competing in-cylinder processes, soot formation and soot oxidation, govern soot emissions from diesel engines. Previous studies have shown a lack of correlation between the soot formation rate and soot emissions. The current experiment focuses on the correlation between soot oxidation rates and soot emissions. Laser extinction is measured using a red (690nm) laser beam, which is sent vertically through the cylinder. This wavelength is long enough to minimize absorption interference from poly-aromatic hydrocarbons, while still in the visible regime. It is modulated at 72 kHz in order to produce 10 pulses per crank angle degree at an engine speed of 1200 rpm. The intake oxygen concentration is varied between 9% and 21%. The time resolved extinction measurements are used to estimate soot oxidation rates during expansion.

This paper presents a study of LPG lean burn in a motorcycle SI engine. The lean burn limits are compared by several ways. The relations of lean burn limit with the parameters, such as engine speed, compression ratio and advanced spark ignition etc. are tested. The experimental results show that larger throttle opening, lower engine speed, earlier spark ignition timing, larger electrode gap and higher compression ratio will extend the lean burn limit of LPG. The emission of a LPG engine, especially on NOx emission, can be significantly reduced by means of the lean burn technology.

Internal combustion engines, as the dominant power source in the transportation sector and the primary contributor to carbon emissions, face both significant challenges and opportunities in the context of achieving carbon neutral goal. Biofuels, such as biodiesel produced from biomass, and zero-carbon fuel ammonia, can serve as alternative fuels for achieving cleaner combustion in internal combustion engines. The dual-fuel combustion of ammonia-biodiesel not only effectively reduces carbon emissions but also exhibits promising combustion performance, offering a favorable avenue for future applications. However, challenges arise in the form of unburned ammonia (NH3) and N2O emissions. This study, based on a ammonia-biodiesel duel-fuel engine modified from a heavy-duty diesel engine, delves into the impact of adjustments in the two-stage injection strategy on the combustion and emission characteristics.

The emission control in heavy-duty vehicles today is based on predefined injection strategies and after-treatment systems such as SCR (selective catalytic reduction) and DPF (diesel particulate filter). State-of-the-art engine control is presently based on cycle-to-cycle resolution. The introduction of the crank angle resolved pressure measurement, from a piezo-based pressure sensor, enables the possibility to control the fuel injection based on combustion feedback while the combustion is occurring. In this paper a study is presented on the possibility to control NOx (nitrogen oxides) formation with a crank angle resolved NOx estimator as feedback. The estimator and the injection control are implemented on an FPGA (Field-Programmable Gate Array) to manage the inherent time constraints. The FPGA is integrated with the rest of the engine control system for injection control and measurement.

The objective of this work is to develop a strategy to reduce the penalties in the diesel engine performance, fuel economy and HC and CO emissions, associated with the operation in the low temperature combustion regime. Experiments were conducted on a research high speed, single cylinder, 4-valve, small-bore direct injection diesel engine equipped with a common rail injection system under simulated turbocharged conditions, at IMEP = 3 bar and engine speed = 1500 rpm. EGR rates were varied over a wide range to cover engine operation from the conventional to the LTC regime, up to the misfiring point. The injection pressure was varied from 600 bar to 1200 bar. Injection timing was adjusted to cover three different LPPCs (Location of the Peak rate of heat release due to the Premixed Combustion fraction) at 10.5° aTDC, 5 aTDC and 2 aTDC. The swirl ratio was varied from 1.44 to 7.12. Four steps are taken to move from LTC to ALTC.

A Scania 13 1 engine modified for single cylinder operations was run using nine fuels in the boiling point range of gasoline, but very different octane number, together with PRF20 and MK1-diesel. The eleven fuels were tested in a load sweep between 5 and 26 bar gross IMEP at 1250 rpm and also at idle (2.5 bar IMEP, 600 rpm). The boost level was proportional to the load while the inlet temperature was held constant at 303 K. For each fuel the load sweep was terminated if the ignitibility limit was reached. A lower load limit of 15 and 10 bar gross IMEP was found with fuels having an octane number range of 93-100 and 80-89 respectively, while fuels with an octane number below 70 were able to run through the whole load range including idle. A careful selection of boost pressure and EGR in the previously specified load range allowed achieving a gross indicated efficiency between 52 and 55% while NOx ranged between 0.1 and 0.5 g/kWh.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

A better understanding is needed of the electrostatic rotating bell (ESRB) application of metallic basecoat paint to automobile exteriors in order to exploit their high transfer efficiency without compromising the coating quality. This paper presents the initial results from experimental investigation of sprays from an ESRB which is designed to apply water-borne paint. Water was used as paint surrogate for simplicity. The atomization and transport regions of the spray were investigated using laser light sheet visualizations and phase Doppler particle analyzer (PDPA). The experiments were conducted at varying levels of the three important operating parameters: liquid flow rate, shaping-air flow rate, and bellcup rotational speed. The results show that bellcup speed dominates atomization, but liquid and shaping-air flow rate settings significantly influence the spray structure. The visualization images showed that the atomization occurs in ligament breakup regime.

Acetone-Butanol-Ethanol (ABE), an intermediate product in the ABE fermentation process for producing bio-butanol, is considered a promising alternative fuel because it not only preserves the advantages of oxygenated fuel which typically emit less pollutants compared to conventional diesel, but also lowers the cost of fuel recovery for each individual component during the fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly. ABE fuels with different component ratio, (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %), were blended with diesel and tested in a constant volume chamber.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Stoichiometric dual-fuel compression ignition (SDCI) combustion has superior potential in both emission control and thermal efficiency. Split injection of diesel reportedly shows superiority in optimizing combustion phase control and increasing flexibility in fuel selection. This study focuses on split injection strategies in SDCI mode. The effects of main injection timing and pilot-to-total ratio are examined. Combustion phasing is found to be retarded in split injection when overmixing occurs as a result of early main injection timing. Furthermore, an optimised split injection timing can avoid extremely high pressure rise rate without great loss in indicated thermal efficiency while maintaining soot emission at an acceptable level. A higher pilot-to-total ratio always results in lower soot emission, higher combustion efficiency, and relatively superior ITE, but improvements are not significant with increased pilot-to-total ratio up to approximately 0.65.