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Advanced combustion engines, as power sources, dominate all aspects of the transportation sector. Stringent emission and fuel efficiency standards have promoted the research interest in advanced combustion strategies and alternative fuels. Owing to the comparable energy density to the existing fossil fuels and renewable production, alcohol and ether fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. Furthermore, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. However, lean-burn or EGR dilution can introduce combustion inefficiencies in the form of excessive hydrocarbon, carbonyl species and carbon monoxide emissions.

Acetone-Butanol-Ethanol (ABE), an intermediate product in the ABE fermentation process for producing bio-butanol, is considered a promising alternative fuel because it not only preserves the advantages of oxygenated fuel which typically emit less pollutants compared to conventional diesel, but also lowers the cost of fuel recovery for each individual component during the fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly. ABE fuels with different component ratio, (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %), were blended with diesel and tested in a constant volume chamber.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

This paper investigates Homogeneous Charge Compression Ignition (HCCI) combustion on an engine that is fuelled with ethanol, iso-octane, and ethanol/iso-octane. The engine is a four-stroke three cylinder indirect injection type diesel engine converted to a single cylinder HCCI operation. In order to clarify the effects of fuel chemistry on HCCI combustion, the trials were done at a constant engine speed, a fixed initial charge temperature and engine coolant temperature. The HCCI engine was fuelled with a lean mixture of air and fuel (ethanol, iso-octane or mixture of ethanol/iso-octane). The engine performance parameters studied here include indicated mean effective pressure (IMEP) and thermal efficiency. Heat-release rate (HRR) analysis was done to determine the effect of fuels on combustion on-set. The experimental results demonstrate that the addition of iso-octane to ethanol retards the on-set of combustion and subsequently leads to a reduction of the IMEP and thermal efficiency.

Extensive empirical work indicates that the exhaust emission and fuel efficiency of modern common-rail diesel engines characterise strong resilience to biodiesel fuels when the engines are operating in conventional high temperature combustion cycles. However, as the engine cycles approach the low temperature combustion (LTC) mode, which could be implemented by the heavy use of exhaust gas recirculation (EGR) or the homogeneous charge compression ignition (HCCI) type of combustion, the engine performance start to differ between the use of conventional and biodiesel fuels. Therefore, a set of fuel injection strategies were compared empirically under independently controlled EGR, intake boost, and exhaust backpressure in order to improve the neat biodiesel engine cycles.

Oxygenated, low energy-density fuels have the potential to decouple the NOx-soot emissions trade-off in compression-ignition engines. Additionally, synthetic fuels can provide a pathway to reach carbon-neutral utilization of hydrocarbon-based fuels in IC engines. Oxymethylene Dimethyl Ether (OME) is one such synthetic, low energy-density fuel, derived from sustainable sources that in combination with conventional fossil fuels with higher energy content, has the potential to reduce CO2 emissions below the US and EU VI legislative limits, while maintaining ultra-low soot emissions. The objective of this work is to investigate and compare the performance, emissions and efficiency of a modern multi-cylinder diesel engine under conventional high temperature combustion (HTC) with two different fuels; 1) OME310 - a blend of 10% OME3 by volume, with conventional Ultra-Low Sulphur Diesel (ULSD), and 2) D100 - conventional ULSD in North America.

The ever-stringent emission regulations are major challenges for the diesel fueled engines in automotive industry. The applications of advanced after-treatment technologies as well as alternative fuels [1] are considered as promising methodology to reduce exhaust emission from compression ignition (CI) engines. Using dimethyl ether (DME) as an alternative fuel has been extensively studied by many researchers and automotive manufactures since DME has demonstrated enormous potential in terms of emission reduction, such as low CO emission, and soot and sulfur free. However, the effect of employing DME in a lean NOX trap (LNT) based after-treatment system has not been fully addressed yet. In this work, investigations of the long breathing LNT system using DME as a reductant were performed on a heated after-treatment flow bench with simulated engine exhaust condition.

Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.

The heterogeneous nature of direct injection (DI) combustion yields high combustion efficiencies but harmful emissions through the formation of high nitrogen oxide (NOx) and smoke emissions. In response, extensive empirical and computational research has focused on balancing the NOx-smoke trade-off to limit diesel DI combustion emissions. Dimethyl ether (DME) fuel is applicable in DI compression ignition engines and its high fuel oxygen produces near-smoke-free emissions. Moreover, the addition of a premixed fuel can improve mixture homogeneity and minimize the DI fuel energy demands lessening injection durations. For this technique, a low reactivity fuel such as ethanol is essential to avoid early autoignition in high compression ratio engines. In this work, empirical experiments of dual fuel operation have been conducted using premixed ethanol with high-pressure direct injection DME.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

DME has been considered an alternative fuel to diesel fuel with promising benefits because of its high reactivity and volatility. Research shows that an engine fueled with DME will produce zero smoke emissions. However, the storage and the handling of the fuel are underlying difficulties owing to its high vapour pressure (530 kPa @ 20 °C). In lieu, OME1 fuel, a derivate of DME, offers advantages exhibited with DME fuel, all the while being a liquid fuel for engine application. In this work, engine tests are performed to realize the combustion behaviour of DME and OME1 fuel on a single-cylinder research engine with a compression ratio of 9.2:1. The dilution ratio of the mixture is progressively increased in two manners, allowing more air in the cylinder and applying exhaust gas recirculation (EGR). The high reactivity of DME suits the capability to be used in compression ignition combustion whereas OME1 must be supplied with a supplemental spark to initiate the combustion.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.

The correlations between the physical properties and autoignition parameters of several alternate fuels have been examined. The fuels are DF-2 and its blends with petroleum derived fuels, coal derived fuels, shale derived fuels, high aromatic naphtha sun-flower oils, methanol and ethanol. A total of eighteen existing correlations are discussed. An emphasis is made on the suitability of each of the correlations for the development of electronic controls for diesel engines when run on alternate fuels. A new correlation has been developed between the cetane number of the fuels and its kinematic viscosity and specific gravity.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

This paper examines the diesel-ethanol dual fuel combustion at medium engine loads on a single-cylinder research diesel engine with a compression ratio of 16.5:1. The effect of exhaust gas recirculation (EGR) and ethanol energy ratio was investigated for the dual fuel combustion to achieve simultaneously ultra-low NOx and soot emissions. A medium ethanol ratio of about 0.6 was found suitable to meet the requirements for mixing enhancement and ignition control, which resulted in the lowest NOx and soot emissions among the tested ethanol ratios. A double-pilot injection strategy was found competent to lower the pressure rise rate owing to the reduced fuel quantity in the close-to-TDC injection. The advancement of pilot injection timing tended to reduce the CO and THC emissions, which is deemed beneficial for high EGR operations. The reactivity mutual-modulation between the diesel pilot and the background ethanol mixture was identified.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.

The effects of different blends of Soybean Methyl Ester (biodiesel) and ultra low sulfur diesel (ULSD) fuel: B-00 (ULSD), B-20, B-40, B-60, B-80 and B-100 (biodiesel); on autoignition, combustion, performance, and engine out emissions of different species including particulate matter (PM) in the exhaust, were investigated in a single-cylinder, high speed direct injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated at 1500 rpm under simulated turbocharged conditions at 5 bar IMEP load with varied injection pressures at a medium swirl of 3.77 w ithout EGR. Analysis of test results was done to determine the role of biodiesel percentage in the fuel blend on the basic thermodynamic and combustion processes under fuel injection pressures ranging from 600 bar to 1200 bar.