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Ethanol is a promising alternative to fossil fuels because it can be made from biomass resources that are renewable. In the most cases, however, ethanol is blended with conventional fuels because of the limited amount of production. Ethanol-fuel blends are typically azeotropic and have a unique characteristic in vapor pressure and phase equilibrium, which is different from that of blends composed of simple aliphatic hydrocarbons. The current studies by the authors have developed a numerical vaporization model for ethanol-gasoline blends, which takes into account vapor-liquid equilibrium of azeotrope and high latent heat of vaporization of ethanol, in order to update the authors' multicomponent fuel spray model and to investigate effects of blending ethanol on droplet vaporization processes. In this paper, the developed vaporization model was validated through a comparison with experimentally-observed vaporization rate for single droplets of ethanol-n-heptane blends.