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Isobaric combustion has demonstrated a great potential to reach high thermodynamic efficiency in the advanced Double Compression Expansion Engine (DCEE) concept. It appears as one of few viable choices for applications with high-pressure combustion. At these conditions, releasing heat at a constant pressure minimizes the peak in-cylinder pressure and, hence, mitigates excessive mechanical stress on the engine. This study focuses on the effect of fuels on the multiple-injection isobaric combustion. A single-cylinder heavy-duty engine was utilized to test and compare the isobaric combustion with pure isooctane and n-heptane fuels. The engine was equipped with an optical piston to allow a bottom-view of the combustion chamber. The interactions of multiple injections and the combustion behavior were studied using high-speed acquisition of chemiluminescence. The examined isobaric cases have a peak pressure of 70 bar.