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Argon replacing Nitrogen has been examined as a novel engine cycle reaching higher efficiency. Experiments were carried out under Homogeneous Charge Compression Ignition (HCCI) conditions using a single cylinder variable compression ratio Cooperative Fuel Research (CFR) engine. Isooctane has been used as the fuel for this study. All the parameters were kept fixed but the compression ratio to make the combustion phasing constant. Typical engine outputs and emissions were compared to conventional cycles with both air and synthetic air. It has been found that the compression ratio of the engine must be significantly reduced while using Argon due to its higher specific heat ratio. The resulting in-cylinder pressure was lower but combustion remains aggressive. However, greater in-cylinder temperatures were reached. To an end, Argon allows gains in fuel efficiency, in unburned hydrocarbon and carbon monoxide, as well as in indicated efficiency.

Stringent emission regulations and the anticipated climate change call for a paradigm shift in the design of the conventional internal combustion engines. One way to combat this problem is oxy-fuel combustion in which the combustion products are mainly water vapor and carbon dioxide. Water vapor can be easily separated by condensation and carbon dioxide is then easily captured and stored. However, many technical challenges are associated with this mode of combustion. There are many challenges facing oxy-fuel combustion before it find its way to commercial production especially for internal combustion engines. One such challenge is the relatively high temperature of the oxy-fuel combustion. A solution to this problem is the recirculation of the generated CO2 to moderate the in-cylinder temperature. Therefore, careful study of the effect of recirculating the CO2 back to combustion chamber is needed before the implementation of such a concept.

A new approach for investigating combustion behavior of practical fuels under homogeneous charge compression ignition (HCCI) conditions was developed with the help of a cooperative fuel research (CFR) engine. The method uses a set of two pressure-temperature diagrams and two charts, each with an octane number scale based on primary reference fuels (PRF), created from experimental results by sweeping the intake temperature. The two pressure-temperature diagrams report conditions leading to the start of the low temperature combustion and the start of the main combustion, respectively. Additional two charts -- required compression ratio and fraction of low temperature heat release charts -- describe global combustion behavior and the importance of the low temperature combustion. Each diagram and chart, together with their respective octane number scale, allow to examine the combustion behavior of practical fuels by comparing their combustion behavior with those of the PRFs.

The improvement of the indicated thermal efficiency of an argon power cycle (replacing nitrogen with argon in the combustion reaction) is investigated in a CFR engine at high compression ratios in homogeneous charge compression ignition (HCCI) mode. The study combines the two effects that can increase the thermodynamic efficiency as predicted by the ideal Otto cycle: high specific heat ratio (provided by argon), and high compression ratios. However, since argon has relatively low heat capacity (at constant volume), it results in high in-cylinder temperatures, which in turn, leads to the occurrence of knock. Knock limits the feasible range of compression ratios and further increasing the compression ratio can cause serious damage to the engine due to the high pressure rise rate caused by advancing the combustion phasing.

Textbook engine thermodynamics predicts that SI (Spark Ignition) engine efficiency η is a function of both the compression ratio CR of the engine and the specific heat ratio γ of the working fluid. In practice the compression ratio of the SI engine is often limited due to “knock”. Knock is in large part the effect of end gases becoming too hot and auto-igniting. Knock results in increase in heat transfer to the walls which negatively affects efficiency. Not to mention damages to the piston. One way to lower the end-gas temperature is to cool the intake gas before inducting it into the combustion chamber. With colder intake gases, higher CR can be deployed, resulting in higher efficiencies. In this regard, we investigated the efficiency of a standard Waukesha CFR engine. The engine is operated in the SI engine mode, and was operated with two differing mixtures at different temperatures.