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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

Developing lightweight, stiff and crash-resistant vehicle body structures requires a balance between part geometry and material properties. High strength materials suitable for crash resistance impose geometry limitations on depth of draw, radii and wall angles that reduce geometric efficiency. The introduction of 3rd generation Advanced High Strength Steels (AHSS) can potentially change the relationship between strength and geometry and enable simultaneous improvements in both. This paper will demonstrate applicability of 3rd generation AHSS with higher strength and ductility to replace the 780 MPa Dual Phase steel in a sill reinforcement on the current Jeep Cherokee. The focus will be on formability, beginning with virtual simulation and continuing through a demonstration run on the current production stamping tools and press.

Experimental procedures and results of a benchmark test for springback are reported and a complete suite of obtained data is provided for the validation of forming and springback simulation software. The test is usually referred as the Slit-Ring test where a cylindrical cup is first formed by deep drawing and then a ring is cut from the mid-section of the cup. The opening of the ring upon slitting releases the residual stresses in the formed cup and provides a valuable set of easy-to-measure, easy-to-characterize springback data. The test represents a realistic deep draw stamping operation with stretching and bending deformation, and is highly repeatable in a laboratory environment. In this study, six different automotive materials are evaluated.

Advanced high-strength steels (AHSS) are a class of steels that have a minimum tensile strength of 500 MPa. The advantages of AHSS include superior formability and better crash energy absorption compared with conventional low-strength steels having a minimum tensile strength of 270 MPa. Several steels with a minimum tensile strength of 590 MPa have already found use in current vehicles, and others with minimum tensile strength up to 980 MPa have been qualified for use in future vehicle models. Two 780 MPa steels of interest are 780 DP (Dual Phase) and 780 TRIP (TRansformation Induced Plasticity). In this study, an examination was undertaken to compare the resistance spot-welding behavior of commercially produced 1.6 mm-thick, hot-dipped galvannealed, 780 MPa DP and TRIP steel sheet. Included in the study were evaluations of the weld lobes, weld microhardness, and the shear- and cross-tension strengths of resistance spot welds for the two steels.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

Studies in an Angular Stretch Bend Test (ASBT) have demonstrated that the failure location moves from the side wall to punch nose area. This occurs as the R/T ratio decreases below a certain limit and applies to most low carbon steels with the exception of Dual Phase (DP) steels. Such behavior in DP steels indicates that bending effects have a severe impact on the formability of DP materials. Therefore, the traditional criterion using the forming limit curve (FLC) is not suitable to assess the formability at punch radius areas for DP steels due in part to its uniqueness of unconventional microstructures. In this paper, a new failure criterion, ‘Bending-modified’ FLC (BFLC), is proposed by extending the traditional FLC using the “Stretch Bendability Index” (SBI) concept for the stretch bendability assessment.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

The benefits of energy and operational cost savings from using copper rotors are well recognized. The main barrier to die casting copper rotors is short mold life. This paper introduces a new approach for manufacturing copper-bar rotors. Either copper, aluminum, or their alloys can be used for the end rings. Both solid-core and laminated-core rotors were built. High quality joints of aluminum to copper were produced and evaluated. This technology can also be used for manufacturing aluminum bar rotors with aluminum end rings. Further investigation is needed to study the lifetime reliability of the joint. The improvement of manufacturing fixture through prototype test is also required.

The crush performance of lightweight composite automotive structures varies significantly between static and dynamic test conditions. This paper discusses the development of a new dynamic testing facility that can be used to characterize crash performance at high loads and constant speed. Previous research results from the Energy Management Working Group (EMWG) of the Automotive Composites Consortium (ACC) showed that the static crush resistance of composite tubes can be significantly greater than dynamic crush results at speeds greater than 2 m/s. The new testing facility will provide the unique capability to crush structures at high loads in the intermediate velocity range. A novel machine control system was designed and projections of the machine performance indicate its compliance with the desired test tolerances. The test machine will be part of a national user facility at the Oak Ridge National Laboratory (ORNL) and will be available for use in the summer of 2002.

A simple strategy for building lightweight automobile body-in-whites (BIWs) is developed and discussed herein. Because cost is a critical factor, expensive advanced materials, such as carbon fiber composites and magnesium, must only be used where they will be most effective. Constitutive laws for mass savings under various loading conditions indicate that these materials afford greater opportunity for mass saving when used in bending, buckling or torsion than in tensile, shear or compression. Consequently, it is recommended that these advanced materials be used in BIW components subject to bending and torsion such as rails, sills, “A-B-C” pillars, etc. Furthermore, BIW components primarily subject to tension, compression, or shear, such as floor pans, roofs, shock towers, etc., should be made from lower cost steel. Recommendations for future research that are consistent with this strategy are included.

Low carbon steels are being replaced by advanced high strength steels (AHSS) due to high demand of the future lighter weight vehicle, while still maintaining good or even better crash performance. However, sidewall curl and springback (section opening) have been found to increase as the strength of the sheet metal increases. Experiments have been conducted on the bending under tension (BUT) test to seek an effective control methodology regarding the applications of the advanced high strength steels (AHSS) in this study. Steels that were studied included a low carbon steel (DQSK), two dual phase steels (DP) and a transformation induced plasticity (TRIP) steel. Two different gauges of each AHSS were also included for a gauge sensitivity study. Different processing variables (four different diameter pins combining with five different back tension forces) were applied to the tests, and the springback angle and sidewall curl were measured for bend and bend-unbend areas of the specimen.

A novel performance classification system has been developed for advanced high-strength steel (AHSS). This system considers intrinsic global and local formability parameters derived from standard uniaxial tension tests and is applicable to all current and future AHSS materials. The overall AHSS performance index (P.I.) is defined herein as the product of the ultimate tensile strength (UTS) and the formability index (F.I.), where F.I. is an intermediate strain value between the true uniform strain and the true fracture strain (TFS). Target P.I. values are defined for First Generation AHSS (GEN1), Improved First Generation AHSS (GEN1+), Third Generation AHSS (GEN3), and AHSS Future. Performance is further distinguished by local, balanced, and global formability characteristics and by relative yield strength (yield-to-tensile ratio). Additionally, the influence of tension test specimen geometry and fracture area measurement method on the TFS value was explored.

The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.

This paper describes static and fatigue behavior of resistance spot welds with the stack-up of conventional mild and advanced high strength steels, with and without adhesive, based on a set of lap shear and coach peel coupon tests. The coupons were fabricated following specified spot welding and adhesive schedules. The effects of similar and dissimilar steel grade sheet combinations in the joint configuration have been taken into account. Tensile strength of the steels used for the coupons, both as-received and after baked, and cross-section microstructure photographs are included. The spot weld SN relations between this study and the study by Auto/Steel Partnership are compared and discussed.

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

Traditional autonomous vehicle perception subsystems that use onboard sensors have the drawbacks of high computational load and data duplication. Infrastructure-based sensors, which can provide high quality information without the computational burden and data duplication, are an alternative to traditional autonomous vehicle perception subsystems. However, these technologies are still in the early stages of development and have not been extensively evaluated for lane detection system performance. Therefore, there is a lack of quantitative data on their performance relative to traditional perception methods, especially during hazardous scenarios, such as lane line occlusion, sensor failure, and environmental obstructions.

A typical forming operation of chassis components (control arms, cross members, etc.) often involves edge stretching and/or hole expansion. As a result, the edge split is a common forming failure mode. To overcome this problem, Japanese and European automakers use stretch flange high strength (SFHS) steel due to its high strength and excellent edge stretch capability. Recently, SFHS steel has gained greater attention in North America and is currently being used for upper and lower control arm applications. This paper includes a discussion on general edge stretch issues in forming operations, including material data that demonstrate the higher stretch limit of SFHS steel as compared to other high strength steels. In a case study, SFHS steel is applied to a control arm and finite element analysis (FEA) is conducted to evaluate forming and structural performance.

Axial drop tower crash tests were carried out on a variety of 70-mm outer-diameter continuous-welded cylindrical steel tubes with several thicknesses (t). Ultimate tensile strength (UTS) ranged from less than 300 MPa for a fully stabilized steel to greater than 800 MPa for the advanced high strength steels (AHSS). In the tests, a 520-kg weight is dropped from a height of 3.3 meters to achieve impact velocities of 6.1 to 6.7 m/s (14 to 15 mph). Load and acceleration data are recorded as a function of time as the tube is crushed axially. The results show that, for a given impact condition, the peak and average crush loads of a steel tube is directly proportional to UTS × t2, while axial crush distance is inversely proportional to UTS × t2. As such, crash deformation can be reduced by substituting higher strength steels of the same thickness, or existing crash deformation can be maintained and weight reduction achieved by substituting higher strength steels with reduced thickness.

To evaluate vehicle crash performance in the early design stages, a reliable fracture model is needed in crash simulations to predict material fracture initiation and propagation. In this paper, a generalized incremental stress state dependent damage model (GISSMO) in LS-DYNA® was calibrated and validated for a 780-MPa third generation advanced high strength steels (AHSS), namely 780 XG3TM steel that combines high strength and ductility. The fracture locus of the 780 XG3TM steel was experimentally characterized under various stress states including uniaxial tension, shear, plane strain and equi-biaxial stretch conditions. A process to calibrate the parameters in the GISSMO model was developed and successfully applied to the 780 XG3TM steel using the fracture test data for these stress states.

The development of new catalytic materials is still dominated by trial and error methods, even though the experimental and theoretical bases for their characterization have improved dramatically in recent years. Although it has been successful, the empirical development of catalytic materials is time consuming and expensive with no guarantee of success. We have been exploring computationally complex but experimentally simple systems to establish a “catalysis by design” protocol that combines the power of theory and experiment. We hope to translate the fundamental insights directly into a complete catalyst system that is technologically relevant. The essential component of this approach is that the catalysts are iteratively examined by both theoretical and experimental methods.