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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

This paper discusses the contribution of instrument panel systems in a European side-impact event. Systems studied include a conventional steel cross-car beam system and a glass-mat thermoplastic (GMT) composite system, evaluated in a body-in-white structure. A thermoplastic composite instrument panel system offers mass, cost, and recycling benefits, but its performance vs. a conventional steel cross-car beam system merited an engineering investigation. The comparison methodology used included a nonlinear dynamic side impact study with a moving, deformable barrier developed according to European Economic Community (EEC) standards. A finite-element model used in this study simulated the body-in-white structure, barrier structure and instrument panel systems. The resulting data include velocity, displacement and energy absorption levels of various components of the respective instrument panel systems.

The preform annealing process is a two-stage stamping method for shaping non age-hardenable (i.e. 5000 series) aluminum sheet panels in which the panel is heat treated in between the two steps to improve overall formability of the material. The intermediate annealing heat treatment eliminates the cold work accumulated in the material during the first draw. The process enables the ability to form more complex parts than a conventional aluminum stamping process. A demonstration of local annealing for this process was conducted to form a one-piece aluminum liftgate inner panel for a large sport utility vehicle using the steel product geometry without design concessions. In prior work, this process was demonstrated by placing the entire panel in a convection oven for several minutes to completely anneal the cold work.

Studies in an Angular Stretch Bend Test (ASBT) have demonstrated that the failure location moves from the side wall to punch nose area. This occurs as the R/T ratio decreases below a certain limit and applies to most low carbon steels with the exception of Dual Phase (DP) steels. Such behavior in DP steels indicates that bending effects have a severe impact on the formability of DP materials. Therefore, the traditional criterion using the forming limit curve (FLC) is not suitable to assess the formability at punch radius areas for DP steels due in part to its uniqueness of unconventional microstructures. In this paper, a new failure criterion, ‘Bending-modified’ FLC (BFLC), is proposed by extending the traditional FLC using the “Stretch Bendability Index” (SBI) concept for the stretch bendability assessment.

Generally linear finite element analysis (FEA) is used to predict fatigue life of spot welded joints in a vehicle body structure. Therefore, the effect of plastic deformation at the vicinity of the spot welded joints is not included on fatigue prediction. This study introduces a simple technique to include the plastic deformation effect without performing elastic-plastic finite element analysis. The S-N curve obtained from fatigue test results is modified to consider this effect. Tensile strength test results of spot welded joint specimens were utilized to find the load range for FEA equivalent to the applied load range for fatigue tests. To demonstrate the proposed approach, fatigue test results of advanced high strength steels (AHSS) for lap-shear and coach peel specimens were used. Both the specimen types were tested at various constant amplitudes with the load ratios of R=0.1 and 0.3.

One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

The ability to make accurate decisions concerning early body-in-white architectures is critical to an automaker since these decisions often have long term cost and weight impacts. We address this need with a methodology which can be used to assist in body architecture decisions using process-based technical cost modeling (TCM) as a filter to evaluate alternate designs. Despite the data limitations of early design concepts, TCM can be used to identify key trends for cost-effectiveness between design variants. A compact body-in-white architecture will be used as a case study to illustrate this technique. The baseline steel structure will be compared to several alternate aluminum intensive structures in the context of production volume.

The benefits of energy and operational cost savings from using copper rotors are well recognized. The main barrier to die casting copper rotors is short mold life. This paper introduces a new approach for manufacturing copper-bar rotors. Either copper, aluminum, or their alloys can be used for the end rings. Both solid-core and laminated-core rotors were built. High quality joints of aluminum to copper were produced and evaluated. This technology can also be used for manufacturing aluminum bar rotors with aluminum end rings. Further investigation is needed to study the lifetime reliability of the joint. The improvement of manufacturing fixture through prototype test is also required.

A simple strategy for building lightweight automobile body-in-whites (BIWs) is developed and discussed herein. Because cost is a critical factor, expensive advanced materials, such as carbon fiber composites and magnesium, must only be used where they will be most effective. Constitutive laws for mass savings under various loading conditions indicate that these materials afford greater opportunity for mass saving when used in bending, buckling or torsion than in tensile, shear or compression. Consequently, it is recommended that these advanced materials be used in BIW components subject to bending and torsion such as rails, sills, “A-B-C” pillars, etc. Furthermore, BIW components primarily subject to tension, compression, or shear, such as floor pans, roofs, shock towers, etc., should be made from lower cost steel. Recommendations for future research that are consistent with this strategy are included.

Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.

The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.

This paper clarifies aggressivity reduction approach for MPV, Multi-Purpose Vehicles, derived from large passenger vehicles toward small passenger vehicles. The effects of aggressivity-reducing approach were measured through full-frontal rigid barrier crash simulations with TRL aluminum honeycomb by Finite Element Method. The front-end structures of large vehicles studied in this paper based on this aggressivity reduction approach show good front-end homogeneity and low average height of force. The structures were also found to effectively reduce aggressivity toward small vehicles by car-to-car simulation. However, there are some cases where the effect was influenced by overlap ratios. From this result, overlap ratio is considered to be one of the important factors to improve compatibility performance.

An extruded Mg-Al-Mn (AM30) magnesium alloy was subjected to uniaxial compression along the extrusion direction (ED) and the extrusion radial direction (RaD) at 450 °C and different strain rates. The microstructure and texture of the AM30 alloy under different deformation conditions were examined. Texture evolution was characterized by electron backscatter diffraction (EBSD). The activity of different deformation modes including twinning were simulated using the visco-plastic self-consistent (VPSC) and the simplistic Sachs polycrystal plasticity models. The results show that the microstructure and the mechanical property of the Mg alloy strongly depend on the strain rate, with twinning activated at strain rates >0.5 s−1. Dynamic recrystallization and twinning interacted with each other and affected the final microstructure and mechanical property of the magnesium alloy.

Compressed natural gas (CNG) currently is used as an alternative fuel for internal combustion engines in motor vehicles. This paper presents results of an analysis of leaks from a model isolated section of CNG fuel system. Discharge of CNG was modeled as vent flow of a real gas hydrocarbon mixture through an orifice from a reservoir with finite volume. Pressures typically used in CNG fuel systems result in choked flow for gas venting directly to atmosphere, producing an under-expanded, momentum-dominated, turbulent free jet with well defined velocity and concentration fields. This paper presents results of analyses of reservoir pressure decay, and vent flow and concentrations fields for CNG venting from a pressurized reservoir into the atmosphere. A combination of empirically-derived analytical relationships and detailed two-dimensional high resolution computational fluid dynamic modeling was used to determine the velocity and concentrations fields of the resulting CNG jet.

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

Interest in operational cost reduction is driving engine manufacturers to consider low-cost fuel substitution in heavy-duty diesel engines. These dual-fuel (DF) engines could be operated either in diesel-only mode or operated with premixed natural gas (NG) ignited by a pilot flame of compression-ignited direct-injected diesel fuel. Under certain conditions, dual-fuel operation can result in increased cycle-to-cycle variability (CCV) during combustion. CFD can greatly help in understanding and identifying critical parameters influencing CCV. Innovative modelling techniques and large computing resources are needed to investigate the factors affecting CCV in dual-fuel engines. This paper discusses the use of the High Performance Computing resource Titan, at Oak Ridge National Laboratory, to investigate CCV of a dual-fuel engine.

Biodiesel, a fuel comprised of mono-alkyl esters of long-chain fatty acids also known as Fatty Acid Methyl Esters(FAME), derived from vegetable oils or animal fats, has become an important commercial marketplace automotive fuel in the United States (US) and around the world over last few years. FAME biodiesels have many chemical and physical property differences compared to conventional petroleum based diesel fuels. Also, the properties of biodiesel vary based on the feedstock chosen for biodiesel production. One of the key differences between petroleum diesel fuels and biodiesel is the energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects the vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb calorimeter, this analytical laboratory testing is time consuming and expensive.