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This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.

The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.

With the adoption of the California Low-Emission Vehicle Regulations and the associated lower emission standards such as LEV (Low-Emission Vehicle in 1990), ULEV (Ultra-Low-Emission Vehicle), and LEV II (1998 with SULEV-Super Ultra Low Emission Vehicle), concerns were raised by emissions researchers over the accuracy and reliability of collecting and analyzing emissions measurements at such low levels. The primary concerns were water condensation, optimizing dilution ratios, and elimination of background contamination. These concerns prompted a multi-year research program looking at several new sampling techniques. This paper will describe the cooperative research conducted into one of these new technologies, namely the Bag Mini-Diluter (BMD) and Direct Vehicle Exhaust (DVE) Volume system.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

As SULEV emission regulations approach, the bag mini-diluter (BMD) technology is gaining acceptance as a replacement for the existing constant volume sampler (CVS) for SULEV exhaust emission measurement and certification. The heart of the BMD system is the direct vehicle exhaust (DVE) flow measurement system. Due to the transient nature of vehicle exhaust during a standard FTP emission test cycle, the DVE must be capable of rapid and accurate response in order to track these varying exhaust flow rates. The DVE must also be robust enough to accurately measure flow rate despite variations in exhaust gas composition, pulsation effects, and rapid changes in both exhaust temperature and pressure. One of the primary DVE systems used on BMDs is the E-Flow, an ultrasonic flow meter manufactured by Flow Technologies, Inc.

In order to fulfill future emissions standards, there is a need for new exhaust-gas aftertreatment concepts, with NOx-emissions reduction in passenger car diesel engines being of particular importance. The NOx storage catalyst is one of the technologies currently under discussion with high NOx conversion potential, and which is under development at DaimlerChrysler for EURO IV standards. With this system, the nitrogen oxides contained in the diesel exhaust gas are stored under lean exhaust-gas conditions and are reduced in the catalyst through an enriched air-fuel ratio of the exhaust-gas and favorable thermal conditions. Hydrocarbons, carbon monoxide and hydrogen are used as reducing agents. DaimlerChrysler has analyzed the effect of sulphur contained in the fuel on the operation of various catalysts during laboratory and engine testing. The sulphur dioxide in the exhaust gas generates sulfates, which remain on the catalyst when nitrate compounds are regenerated briefly.

In view of tight emission standards, injection strategies to reduce raw HC-emissions during the cold starting of port fuel injected engines are evaluated in this study. The relevance of spray targeting and atomization is outlined in the first part of this paper. The foundation and performance of different injector concepts with respect to spray characteristics are discussed. Laboratory experiments demonstrate that concepts relying on auxiliary energy, such as air-assistance, fuel heating and injection at elevated system pressures, are capable of producing spray droplet sizes in the SMD-range of 25μm. For future injection strategies aimed at the compliance of SULEV emission levels, this target value is considered to be essential. In the second part of this paper, emission tests of selected injector concepts are carried out using a V6-3.2I ULEV engine operated both in a vehicle and on a test bench.

For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

It is becoming increasingly difficult to obtain good repeatability from running lab vehicle correlation testing, since vehicle variability is so significant at the Low ULEV and SULEV emissions levels. These new emission standards are becoming so stringent that it makes it very difficult to distinguish whether a problem is a result of vehicle variability, test cell sampling or the analytical system. A vehicle exhaust emission simulator (VEES) developed by Horiba, can simulate emissions from low emitting gasoline vehicles by producing tailpipe flow rates containing emissions constituents ( HC, CH4, CO, NOx, CO2 ) injected at the tailpipe flow stream via mass flow controllers.

This paper describes the results of a joint development program focussing on the introduction of the new generation of Pt/Rh-technology for current and future emission standards as a cost effective alternative to the in serial Pd/Rh based exhaust gas concepts. In the initial phase of the program combinations of Pd- and Pt-based three-way catalyst technologies were evaluated on vehicles equipped with a 8 cylinder engine. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and the new Pt/Rh technology in the underfloor position at lower precious metal loading. A combination of a close-coupled Pd/Rh technology and the new Pt/Rh in the underfloor position was able to meet the emission targets at significant lower costs of the system after a catalyst aging that resembles more than 100.000 km of vehicle German highway driving.

The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).

Due to ever soaring fuel costs and even more stringent emission regulations which require more elaborate technical efforts and unfortunately lead to a negative trend on fuel economy as well, todays and future trucking business is extremely challenged. These facts create an urgent requirement for the engine manufacturer to offer an engine with an optimized cost-benefit-ratio for the trucking business. Mercedes-Benz, as the leader in the European commercial vehicle market - of which e. g. high fuel costs, long maintenance intervals and high engine power-to-weight ratios have always been key characteristics - has developed a new class 8 engine for the US market. The MBE 4000 is a 6 cylinder inline engine in the compact size and low weight category, but due to its displacement of 12,8 liters it offers high performance characteristics like heavier big block engines.