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In the last decades, worldwide automotive regulations induced the industry to dramatically increase the application of electronics in the control of the engine and of the pollutant emissions reduction systems. Besides the need of engine control, suitable fault diagnosis tools had also to be developed, in order to fulfil OBD-II and E-OBD requirements. At present, one of the problems in the development of Diesel engines is represented by the achievement of an ever more sharp control on the systems used for the pollutant emission reduction. In particular, as far as NOx gas is concerned, EGR systems are mature and widely used, but an ever higher efficiency in terms of emissions abatement, requires to determine as better as possible the actual oxygen content in the charge at the engine intake manifold, also in dynamic conditions, i.e. in transient engine operation.